Subject: Chemistry

u e st io n (Write this number B on your Answer o Sheet) o kl (Write et this Q No. Question Booklet

11 11 11

MHT-CET

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Answer Sheet No r. Day and

Duration : 6.00 pm to 06.45pm

Total Marks: 50 This is to certify that, the entries of MHT-CET-11 No. & Answer Sheet No. have been correctly written & verified

Candidate's Signature Invigilators Signature Instructions to Candidates 1. This question booklet contains 50 Objective Type Questions in the subjects of Chemistry (50). The question paper and OMR (Optical Mark

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Recognition) Answer Sheet is issued separately at the start of the examination. Choice and sequence for attempting questions will be as per the convenience of the candidate. Candidate should carefully read the instructions printed on the Question Booklet and Answer Sheet and make the correct entries on the Answer Sheet. As Answer Sheets are designed to suit the OPTICAL MARK RECOGNITION (OMR) SYSTEM, special care should be taken to mark the entries correctly. Special care should be taken to Fill QUESTION BOOKLET VERSION, SERIAL No. and MHTCET-11 Roll No. accurately. The correctness of entries has to be cross-checked by the invigilators. The candidate must sign on the Answer Sheet and Question Booklet. Read each question carefully. Determine the correct answer from out of the four available options given for each question. Fill the appropriate circle completely like this , for answering a particular question. Mark with Black ink ball point pen only. Each answer with correct response shall be awarded One (1) mark. There is

No Negative Marking. No mark shall be awarded for marking two or more answers of same question, scratching or overwriting. 9. Use of whitener or any other material to erase/hide the circle once Filled is not permitted. 10. Avoid overwriting and/or striking of answers once marked. 11. Rough work should not be done on the Answer Sheet. 12. Immediately after the prescribed examination time is over, the Question Booklet and Answer Sheet is to be returned to the invigilator. Confirm that both the candidate and invigilator have signed on Question Booklet and Answer Sheet. 13. No candidate is allowed to leave the examination hall till the paper gets over.

1. The pH of 10 -8 M NaOH will be A. 6.96 B. 7.04 C. 12.0 D. 8 2. Among the following reactions, the fastest one is A. precipitation

of silver chloride by mixing silver nitrate and sodium chloride solutions B. burning of coal C. rusting of iron in moist air D. conversion

of monoclinic sulphur to rhombic sulphur 3. The unit of electrochemi cal equivalent is A. coulomb/gra m B. gmampere C. gm./coulomb D. gmampere-1 4. The number of hours required for a current of 3.0 A to decompose electrically 18 g of water is A. 12 hours B. 24 hours C. 6 hours D. 18 hours 5. Number of nucleons in D2 molecule is A. 4 B. 1 C. 2 D. 3 6. The compound having blue colour is A. HgSO4 B. PbSO4 C. CuSO4.5H2O D. CuSO4 7. The reagent

which forms crystalline osazone derivative when reacted with glucose is A. Hydroxylami ne B. Benedict solution C. Fehling solution D. Phenylhydra zine 8. Which of the following alcohol on dehydration with conc. H2SO4 will yield 2butene? A. 2-methyl2-propanol B. 2-methyl2-butanol C. 2propanol D. Sec. Butyl alcohol 9. A compound A has a molecular formula C2Cl3OH. It reduces Fehling solution and an oxidation gives a monocarbox ylic acid B. It can be obtained by

the action of chlorine on ethyl alcohol. A is A. Chloral B. Chloroform C. Methyl chloride D. Monochloro acetic acid 10. Isopropyl alcohol is heated on a water bath with the suspension of bleaching powder. Which of the following products will be formed? A. Propene B. Ethanol C. Isopropyl chloride D. Trichloromet hane 11. Which of the following compounds is least basic? A. C6H5NH2 B. C2H5NH2 C. CH3NH2 D. NH3 12. The metals occurring in the form of their

compound in the earth's crust are called A. matters B. minerals C. alloys D. gangue 13. The reaction of aliphatic primary amine with nitrous acid in cold produces A. nitrile B. alcohol C. diazonium salt D. secondary amine 14. The aldol condensation of acetaldehyde results in the formation of
A. CH3COCHOH CH3 B.CH3CHOHC H2CHO C. CH3CH2CHO HCHO D.CH3CH2OH + CH3COOH

14. Which compound reacts fastest with Lucas reagent at room temperature?

A. Butan-l-ol B. Butan-2-ol C. 2-Methyl propan-l-ol D. 2-Methyl propan-2-ol 15. The reaction with alcoholic potash, lchlorobutane gives A. 1-Butene B. 1Butanol C. 2-Butene D. 2Butanol 16. The active nitrating agent during nitration of benzene is A. NO3 - B. HNO2 - C. NO2- D. HNO3 17. The number of sigma and pi bonds in 1buten-3-yne are A. 5 sigma and 5 pi B. 7 sigma and 3 pi C. 8 sigma and 2 pi D. 6 sigma and 4 pi

18. The most stable carbonium ion among the cations is A. sec-butyl B. ter-butyl C. n-butyl D. none of these 19. How many optically active stereoisomers are possible for butane-2, 3diol? A. 1 B. 2 C. 3 D. 4 20. Which of the following is a weak acid? A. HCl B. HBr C. HF D. HI 21. The chemical name of phosgene is A. Phosphene B. Carbonyl chloride C. Phosphorous oxychloride D. Phosphorous trichloride 22. Which one of the following is

strongest Lewis acid? A. BF3 B. BCl3 C. BBr3 D. BI3 23. Rocky impurities present in a mineral are called A. flux B. gangue C. matte D. slag 24. On passing 0.3 faraday of electricity through aluminium chloride, the amount of aluminium metal deposited on cathode is (Al = 27) A. 0.27 g B. 0.3 g C. 2.7 g D. 0.9 g 25. The halflife of a first order reaction is 69.35. The value of rate constant of the reaction is A. 1.05-1 B. 0.15-1 C. 0.015-1 D. 0.0015-1 26. In exothermic reactions,

A. HR =HP B. HR >HP C. HR < HP D. None of the above 27. Which is a buffer solution? A. CH3COOH + CH3COONa B. CH3COOH + CH3COONH
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C. CH3COOH + NH4Cl D. NaOH + NaCl 28. The pH of 0.01 M solution of HCl is A. 1.0 B. 2.0 C. 10.0 D. 11.0 29. The value of R in calorie/degre e/mole is A. 0.0831 B. 8.31 C. 8.31 x 107 D. 1.987 30. NH3 and BF3 form an adduct readily because they form A. a coordinate bond B. a

covalent bond C. an ionic bond D. a hydrogen bond 31. Loss of a -particle is equivalent to A. loss of two neutrons only B. loss of two protons only C. loss of two neutrons and loss of two protons D. none of the above 32. The reaction of CH3OC2H5 with HI gives A. CH3I B. C2H5OH C. CH3I + C2H5OH D. C2H5I + CH3OH 33. A compound 'X' with molecular formula C3H8O can be oxidised to a compound' Y' with the molecular formula C3H6O2, 'X'

is most likely to be (A) Primary alcohol (B) Secondary alcohol (C) Aldehyde (D) Ketone 34. Acetophenon e can be obtained by the distillation of (A) (C6H5COO)2 Ca (B) (CH3COO)2 Ca (C) (C6H5COO)2 Ca and (CH3COO)2 Ca (D) (C6H5COO)2 Ca and (HCOO)2Ca 35. Acetone can be converted into pinacol by: (A)Mg/Hg/H (B) 2O Zn/Hg/HCl (C) Na/Hg/ H2SO4 (D) All of these 36. Cannizzaro reaction is example of:

(A) Redox reaction (B) Disproportio nation (C) Both (A) and (B) (D) Only oxidation 37. The smallest ketone and its next homologue are reacted with NH2OH to form oximes. (A) Two different oximes are formed (B) Three different oximes are formed (C) Two oximes are optically active (D) All oximes are optically active 38. Which of the following compounds gives carbon dioxide with NaHC03? (A) Acetic acid (B) Hexanol (C) Phenol (D) Acetylene

39. Which amine will not react with nitrous acid: (A) Methyl amine (B) Ethyl amine (C) Dimethyl amine (D) N, N Dimethyl ethane amine 40. Intramolecul ar hydrogen bonding is found in: (A) Salicylaldeh yde (B) Water (C) Acetaldehyd e (D) Phenol 41. In dry ice there are: (A) Ionic bond (B) Covalent bond (C) Hydrogen bond (D) None of these 42. Loss ofap-particle is equivalent to (A) Increase of one proton only (B) Decrease of one neutron only

(C) Both (A) and (B) (D) None of these. 43. pH of an aqeous solution of NaCl at 8 5 C should be (A) 7 (B)> 7 (C) < 7 (D) 0 44. The pH of an aqueous solution of 1.0 M solution of a weak monoprotic acid which is 1 % ionised is (A) 1 (B) 2 (C) 3 (D) 11 45. Elevation of boiling point of 1 molar aqueous glucose solution (density =1.2 g/ml) is (A)Kb (B) 1.20 Kb (C) 1.02 Kb (D) 0.98Kb 46. The radioactive element which was discovered by Madam Curie and the name of which is based on her country is

(A) Uranium (B) radium (C) polonium (D) neptunium 47. The ratio of CT to n bonds in mesitylene is (A) 3 (B)7 (C) 5 (D)6 48. Mixture of 1, 2 and 3 amines can be separated by: (A) Hinsberg's method (B) Hofinann's isocyanide test (C) Fractional distillation (D) NaNO2 + HCl 49. Acetic acid can be used for the preparation of: (A) Ethane (B) Methane (C) Acetone (D) ethanol 50. Which of the following gives silver mirror test? (A) HCOOH (B) CH3COCHO HCH3

(C) Tartaric acid (D) Glucose