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Ionisation Energy
Evidence for how the electrons are arranged in atoms comes from ionisation energies. 1st Ionisation Energy The energy required to remove one mole of electrons (to infinity) from one mole of isolated, gaseous atoms to form one mole of gaseous positive ions. e.g. 1st IE of Na: Na(g) Na+(g) + e 2st Ionisation Energy The energy required to remove one mole of electrons (to infinity) from one mole of gaseous unipositive ions to form one mole of gaseous dipositive ions. 2nd IE of Na: Na+ (g) Na2+(g) + e
E = hL = h
n=1
n=2
n=3
n=4
e.c. = 2, 8, 8, 1
Potassium is in group 1
Notice the jump in energy needed to remove the 2nd electron
n=2
Group 4
Notice the jump in energy needed to remove the 5th electron
Valence electrons
Group 2
Notice the jump in energy needed to remove the 3rd electron
Group 3
Notice the jump in energy needed to remove the 4th electron
Group 5
Notice the jump in energy needed to remove the 6th electron
Valence electron
Group 1
Notice the jump in energy needed to remove the 2nd electron