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UE 5501
E.C.E. 7TH SEMESTER
U.I.E.T., PANJAB UNIVERSITY
CONTENTS
• Nanoparticle
• Quantum Dots
– Quantum Dot
– Degrees of freedom
– Structure and Formation
– How Quantum dots work
– Quantum Dot features
• Solar Cells
– Working
– Construction
• Need for Quantum dots in Solar cells
continued…
• References
NANOPARTICLE
• In nanotechnology, a particle is
defined as a small object that
behaves as a whole unit in terms of
its transport and properties
• According to size:
– fine particles cover a range between 100
and 2500 nm
– ultrafine particles are sized between 1
and 100 nm
• Nanoparticles may or may not exhibit
size-related intensive properties
QUANTUM DOTS
• Non-traditional semiconductor
• 0 degrees of freedom
Quantum Dot
Quantum Dot Layer
Quantum Dot Layer
DEGREES OF FREEDOM
Bulk Crystal (3D) Quantum Well (2D)
3 Degrees of Freedom (x-, y-, and z-axis) 2 Degrees of Freedom (x-, and y-axis)
• Quantum confinement
– Exciton Bohr Radius
– Discrete energy levels
• The shape of the dot also changes the band gap energy level
QUANTUM DOT FEATURES
• Molecular Coupling
– QDs can be attached to a variety of molecules via metal coordinating
functional groups. For eg: thiol, amine, nitrile, phosphine, phosphine
oxide
– by bonding appropriate molecules to the surface, the quantum dots
can be dispersed or dissolved in nearly any solvent or incorporated
into a variety of inorganic and organic films
– the surface chemistry can be used to effectively alter the properties of
the quantum dot, including brightness and electronic lifetime
continued...
• Quantum Yield
– The percentage of absorbed photons that result in an emitted photon
is called Quantum Yield (QY)
– controlled by the existence of nonradiative transition of electrons and
holes between energy levels
– greatly influenced by the surface chemistry
• PV Construction Technologies:
– Single Crystalline
– Polycrystalline or Multicrystalline
– Amorphous or Thin-film
NEED FOR QUANTUM DOTS IN SOLAR CELLS
• Reduction in cost:
– of each kilowatt of electricity produced
– of raw materials
– of processes used to convert the raw materials into functional cells
• Nanoparticles of titanium
dioxide are used in these cells
– Its band gap is too wide to
absorb much sunlight
• Working:
– TiO2 particles are coated with a
metal organic ruthenium-based
dye, the dye absorbs light,
becomes oxidized (loses
electrons), and injects these
electrons into the TiO2
continued…
p n
LUMINESCENT CONCENTRATOR CELLS
Light
• Spectrum of the incoming light is
converted such that it has a better
1
match with the absorption spectrum
of the solar cell 2
a
• Can reduce spectral losses, 2
especially in the case of a small
1
absorption band, such as for dye
sensitized solar cells and polymer QD
solar cells Solar Cell
Transparent Matrix
Schematic 3D view of a luminescent concentrator. AM Light is incident from the top. The light is absorbed by a
luminescent particle. The luminescence from the particle is randomly emitted. Part of the emission falls within
the escape cone (determined by the angel (a)) and is leaving the luminescent concentrator at the side (1). The
other part of the luminescence is guided to the Si cell by total internal reflection (2).
continued...
• The LC consists of a transparent matrix material, usually a flat
plate, with solar cells connected to one or more sides
• The transparent matrix contains luminescent particles such as,
e.g., organic dyes or quantum dots that absorb part of the
spectrum
• Part of the light emitted by the luminescent particles is guided
towards the solar cells by total internal reflection
• Both direct and diffuse sunlight is collected, making solar tracking
unnecessary
• Ideally, the luminescence spectrum of the luminescent particles
matches the spectral response of the solar cell.This can be done by:
– combining two infrared photons to get one photon in the visible
(upconversion), or by splitting one ultraviolet photon into two visible photons
(downconversion)
– using different dyes which cover different parts of the spectrum
REFERENCES
• http://www.evidenttech.com/
• http://en.wikipedia.org/wiki/Solar_cell
• http://en.wikipedia.org/wiki/Quantum_dot
• http://softpedia.com/
• http://www.sciencedaily.com/articles/
• http://www.i-sis.org.uk/index.php/
• White Papers:
– Brad Gussin, John Romankiewicz
– Peter Green
– L.H. Slooff, R. Kinderman, A. R. Burgers, J.A.M. van Roosmalen
– UC-Davis Physics,CM Journal Club