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c
32
2
A
=
f
o i
P
P P
P
+
= A
2
Pore flow model
m
v
R
P
J
A
= Resistance model
Osmotic pressure
model
cp m
v
R R
P
J
+
A A
=
t
g cp m
v
R R R
P
J
+ +
A A
=
t
Ultrafiltration models
Transmembrane pressure
P
e
r
m
e
a
t
e
f
l
u
x
Pressure
dependent
Pressure
independent
?
Limiting f lux
Concentration
polarization model
|
|
.
|
\
|
=
p b
p w
v
C C
C C
k J ln
Gel polarization model
|
|
.
|
\
|
=
|
|
.
|
\
|
=
b
g
b
s
C
C
k
C
C
k J ln ln
lim
Membrane
Bulk feed
o
b
= Thickness of concentration polarization layer
C
b
C
w
C
p
Permeate
Mass transfer coefficient
k (= mass transfer coefficient) = D / ob
33 . 0
33 . 0 33 . 0
Re 62 . 1
|
|
.
|
\
|
=
t
l
d
Sc Sh
33 . 0 8 . 0
Re 023 . 0 Sc Sh =
For fully developed laminar
flow: Graetz-Leveque
correlation
For turbulent flow (Re > 2000):
the Dittus-Boelter correlation
Dimensionless correlations are used for determining mass
transfer coefficient
Correlations are based on heat-mass transfer analogy
General form is: Sh = a Re
b
Sc
c
Solute transmission through membranes
i
w
p
i
S
C
C
R = = 1 1
a
b
p
a
S
C
C
R = = 1 1
( ) ( )
2
2 =
a
R
< 1
1 =
a
R
> 1
Intrinsic rejection and sieving
coefficient
Apparent rejection and sieving
coefficient
Classical theory of rejection
Solute transmission through membranes
|
.
|
\
|
+
|
|
.
|
\
|
=
|
|
.
|
\
|
k
J
S
S
S
S
v
i
i
a
a
1
ln
1
ln
Modern theory of solute transmission:
S
S
S J
D
S
S J
D
i
v m
eff
v m
eff
=
|
\
|
.
|
|
+
|
\
|
.
|
|
exp
exp
o
o
1
( )
S
S
S J
D
J
k
S
S J
D
S
S J
D
J
k
a
v m
eff
v
v m
eff
v m
eff
v
=
+
|
\
|
.
|
|
|
\
|
.
|
|
(
(
+ +
|
\
|
.
|
|
exp
exp exp
o
o o
1 1
Permeate flux (log scale)
I
n
t
r
i
n
s
i
c
s
i
e
v
i
n
g
c
o
e
f
f
i
c
i
e
n
t
Asymptotic
intrinsic sieving
coefficient
Solute fractionation
Solute fractionation refers to separation of one solute from
another
For fractionation of a binary mixture of solutes, it is desirable
to achieve maximum transmission of the solute desirable in
the permeate and minimum transmission of the solute
desirable in the retentate
Efficiency of solute fractionation for a binary mixture is
expressed in terms of the selectivity ():
( )
( )
2
1
2
1
1
1
a
a
a
a
R
R
S
S
= =