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Multi-component distillation
F zF,1 zF,2
We can specify two fractional recoveries: FR1 = (DxD,1)/(FzF,1) = 0.95 FR2 = (BxB,2)/(FzF,2) = 0.98 If the feed contains more than two volatile components, we cannot specify the recoveries of the additional components. However, we can add more distillation columns.
B, xB,1
Alternative? 1
1, 2
II
2,3,4
F zF,1 zF,2 zF,3 zF,4
3,4
I
2
4
3
3, 4
Key components
Each column is designed to separate two components of adjacent relative volatility. These components are the keys. All other components are non-keys.
component
1 design for separation 2 3 4 5
a
1.5 1.4 1.3 1.2 1.0
designation
Light non-key (LNK) Light key (LK) Heavy key (HK) Heavy non-key (HNK) Heavy non-key (HNK) assume exclusively in distillate specify recovery in distillate specify recovery in bottoms assume exclusively in bottoms
Distributions in the distillate and bottoms streams are specified for the two key components. If we assume that the non-keys do not distribute, the overall mass balance is easily solved.
Define fi, di, and bi as molar flow rates of component i in feed, distillate and bottoms, respectively.
Ex.: 100 mol/h of an equimolar mixture of four components. Assume 80 % recovery of LK in D, and 80 % recovery of HK in B. component i zF,i fi = F zF,i di xD,i = di/D bi LNK LK HK HNK 0.25 0.25 0.25 0.25 25 25 25 25 25 20 5 0 di = D = 50 0.50 0.40 0.10 0 xD,i = 1 0 5 20 25 bi = B = 50
Stage-by-stage calculations
For a specified external reflux ratio R = L0/D and feed quality q, and assuming constant molal overflow (CMO), first perform the overall column balance to obtain D. Then, L = (L0/D) D V=L+D
L/V
L = L + q F V = V + (1 q) F
Algebraic solution, starting at top of column: 1. yi,1 = xi,D 2. xi,1 = yi,1 / Ki,1 3. yi,2 = (L/V) xi,1 + (1 L/V) xD section)
L/V
Repeat steps (2) and (3) down to feed stage. Then, change mass balance equation to yi,k+1 = (L/V ) xi,k + (1 L/V ) xB We just need to find Ki for each stage.
a AB
K A y A / xA = = K B y B / xB
y A, j K A, j = y A, j
a BB = 1
xA, j + xB, j + xC , j =
a CB =
y A, j +
KC KB
y B, j + y C, j
xA, j =
a ABK B, j
y B, j yC, j
a ABK B, j
a BBK B, j
y A, j
a CBK B, j
=1
K B, j =
y A, j
a AB
a BB
a CB
y i,j = a iB i
xA, j =
y i,j a iB i
a AB
IF relative volatility is not constant, use geometric average, (a1aN). Or, find Tj from dewpoint calculation (starting with xD,i), then find Ki(Tj) using VLE.
Trial-and-error solution
Perform stage-by-stage analysis, from top to bottom of column. xHK,N+1 xHK,B xLK,N+1 xLK,B
if not true, choose different starting concentrations at the top of the column, and repeat cannot assume xD,HNK = 0, but no way to guess works best if there are no HNKs. If there is no LNK, can start at bottom of column and work to the top
designate the keys A and B, and assume constant aAB according to the definition of equilibrium:
yA xA = a AB y B N +1 xB N +1
N
xi,N N+1
Estimating Nmin
at the top of the column
xA y A Nmin xA = = a AB xB 0 y B 1 xB N +1
x xA A ln xB 0 xB N +1 = lna AB
Fenske equation
Nmin
Nmin
FRC,distillate =
NF ,min
x zA A ln z x B 0 B F = lna AB
xD
zF
xB
xB condensor
near the pinch point, composition changes little from stage to stage - passing streams are very close to equilibrium - no change in temperature between stages
Consider LK
LK is the most volatile component in the system on every stage there is almost no LK at the reboiler stage xi
Consider HNK
HNK is the least volatile component in the system on every stage almost all HNK is found at the reboiler stage finite HNK at feed stage, drops off rapidly above 0 C F stage number R
Behavior of HK
1 Ternary composition profile LK-HK-HNK pinch point ~binary
Consider HK:
HK behavior is most complex above feed stage, distillation is almost binary
near reboiler, distillation is almost binary (HNK-HK), but HK is the more volatile component HNK goes through a maximum in the stripping section, creating a pinch point there 0 C
F stage number
~binary
pinch
pinch
LK-HK-HNK system
has a pinch point in the stripping section
xi , j = xi , j +1 y i , j +1 = K i xi , j +1
a i = K i Kref
y i , j +1 = a i Kref xi , j +1
Lmin Vmin y i , j +1 1= Dxi ,D a iVminK ref
define: f =
a i Dxi ,D
Lmin ai VminK ref
f =f
DVfeed a i Dxi ,D a i Bxi ,B = Vmin - Vmin = + a f a f i i i a i Fzi ,F = i ai -f
DVfeed
DVfeed = F (1- q)
searching for: with C components, the 1st Underwood equation has C roots, one between each adjacent pair of a-values, and one between 0 and the smallest a-value. We need the root aHK < < aLK binary system: use quadratic equation to solve for trial-and-error: use (aHK + aLK) as initial guess
Estimating Rmin
Onceis known, obtain Vmin using the 2nd Underwood equation.
Gilliland correlation
We have Nmin (Fenske) and Rmin (Underwood). R is often specified as a multiple of Rmin, e.g., R = 1.5 Rmin
y=
y = 1- e
x=
Figure 7-3 Gilliland correlation as modified by Liddle (1968);
Reprinted with permission from Chemical Engineering, 75(23), 137 (1968), copyright 1968, McGraw-Hill.
From Separation Process Engineering, Third Edition by Phillip C. Wankat (ISBN: 0131382276) Copyright 2012 Pearson Education, Inc. All rights reserved.
Assume relative position of the feed stage is the same as it was at total reflux:
D
F NF,min F NF
NF ,min Nmin
NF N
Remember! Nmin and N include partial reboiler (and partial condensor). Works well for symmetrical columns (feed stage close to middle).
B B
Kirkbride equation
Better feed stage estimation for unsymmetrical columns:
F
0.206
Nrectifying Nstripping
z x 2 B = HK LK ,B zLK xHK ,D D F
N = Nrect + Nstrip + 1
Sandwich components
At the beginning of this section, we specified that the key components should have adjacent relative volatilities. What if there is a non-key with intermediate volatility (i.e., between the two key components)? This component is called a sandwich component.
component 1 2 3 4 5 a 1.5 1.4 1.3 1.2 1.0 designation Light non-key (LNK) Light key (LK) Sandwich non-key Heavy key (HK) Heavy non-key (HNK) F S D
Sandwich components tend to concentrate in the middle of the column, and can cause flooding even when present at trace concentrations. If unavoidable, use side-streams to withdraw them.