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Chapter Objectives:
• To learn the differences between the solid, liquid, and gas state,
and how the polarity of molecules influences those states.
• To learn the different types of intermolecular forces between
different molecules.
Kinetic Molecular Theory of Liquids
and Solids
• Liquids and solids have significant interactions.
• Liquids and solids have well-defined volume.
• Liquid molecules “flow,” while solids are held “rigid.”
Since CH3Cl has a tetrahedral shape, with one polar bond and three nonpolar
bonds, there is an overall dipole moment pointing towards the Cl end of the
molecule.
Depending on the number and orientation of the bond dipoles, the molecule may
Structures and dipole moments for ammonia and water are shown
Structures and dipole moments are shown for carbon dioxide and
tetrachloromethane. Although each molecule has bond dipoles,
they do not have molecular dipoles
Intramolecular &
• Intermolecular Forces
Intramolecular forces operate within each molecule,
influencing the chemical properties of the substance
(i.e., covalent bonds).
These are the forces that hold the atoms in a molecule together.
They are very strong forces which result from large charges (on
protons and electrons)interacting over very short distances.
These are the forces that hold liquids and solids together, and
influence their melting and boiling points. They are weaker forces,
because they result from smaller charges, or partial charges,
interacting over much larger distances.
Intramolecular &
Intermolecular Forces
To break an O—H bond in water, the water must be
heated to thousands of degrees C; to completely
overcome the intermolecular forces, all you have to do is
boil it — 100ºC.
Intramolecular &
Intermolecular Forces
(a) In an individual N2 molecule,
atoms are held together by strong
intramolecular force(covalent bond).
Different N2 molecules are weakly
attracted to one another at low
temperature by intermolecular forces,
causing nitrogen to become liquid.
• Dipole - induced dipole forces are the attractive forces that exist
between polar molecules and nonpolar molecules. Being next to a
polar molecule “induces” a dipole in a nonpolar molecule.
Atoms on the surface are less stable because they have fewer neighbors
and feel fewer attractive forces than atoms in the interior, so the liquid acts
to minimize their number by minimizing the area of the surface.
Intermolecular Force
Effects
More surface tension examples…
Intermolecular Force
Effects
2. Viscosity
Changes from a less random phase to a more random one have positive
values of ΔH and Δ S. Changes from a more random phase to a less
random one have negative values of Δ H and Δ S.
Phase Changes
• Sublimation: The process in which molecules go
directly from the solid into the vapor phase.
A heating curve for H2O, showing the temperature changes and phase
transitions that occur when heat is added. The plateau at 0°C represents
the melting of solid ice, and the plateau at 100°C represents the boiling
of liquid water.
A phase diagram for H2O, showing a negative slope for the solid/liquid
boundary.
Phase diagram for
carbon dioxide
Here we can see the separate phases of carbon dioxide. The meniscus
is easily observed.
Once the critical temperature and pressure have been reached the
two distinct phases of liquid and gas are no longer visible. The
meniscus can no longer be seen. One homogenous phase called
the "supercritical fluid" phase occurs which shows properties of
both liquids and gases.