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References :
Basic Principles and Calculations in Chemical Engineering, 7 edition, David. M. Himmerblau and James B. Riggs.
1, . . , , . ,
Lecture 1. Introduction
Derived Dimensions
Dimensions that can be developed in terms of the fundamental dimensions. Velocity, Acceleration, Force, Pressure, Density, Heat Capacity, Energy, Power, etc. Important Note!
Fundamental or Derived depending also on dimension/unit systems. ( 1.1, AH)
Units
Units : means of expressing dimensions
Length; feet, meters Time; hours, seconds
Systems of Units
SI : Le Systeme Internationale dUnites (International System) AE : American Engineering USCS : U.S. Conventional System Metric systems : CGS (centimeters, grams, seconds) English system ( 1.2, 1.3 1, AH)
SI Prefixes (Remember!)
G, giga, 109 M, mega, 106 k, kilo, 103 h, hecto, 102 da, deka, 101 d, deci, 10-1 c, centi, 10-2 m, milli, 10-3 , micro, 10-6 n, nano, 10-9
Caution!
camels hair brush : camels hair brush or camels hair brush? Written with confusion
ms milliseconds or meter seconds? cm2 square centimeters or centi square meters?
2.
3.
Nonlinear Operations
Caution!
There are several miles, pounds, gallon, oz, and barrel.
U.S. frequent-flier mile (nautical mile) -> 1.85 km U.S. mile -> 1.61 km Ancient Italian mile -> 37 modern U.S. miles
F = ma or F = Cma
F = force C = constant or conversion factor, whose numerical value and units depend on those selected for F, m and a m = mass a = acceleration
d 2 ax 2 2 1+ (x / a ) = dx 1 + ( x 2 / a2 )
- This cannot be correct. - The lefthand side has units of 1/x, but the righthand side has units of x2 (the product of ax).
u=c
where u P c
DP
= fluid velocity = pressure drop (force per unit area) = density of the flowing fluid = constant
Ans. c is dimensionless.
Significant Figures
1.43
1.43 0.005, between 1.425 and 1.435 1.43 0.01, between 1.44 and 1.42
Engineering Calculation
Cost of inaccuracy is high, knowledge of the uncertainty is vital, and vice versa.
Absolute Error
Numbers with a decimal point
the last significant figure in a number represents the associated uncertainty. 100.3 -> 4 significant figures 100.300 -> normally 6 significant figures since there usually was a reason for displaying the trailing zeros e.g. rounding 100.2997 to 100.300 100. ? -> 3 significant figures
Absolute Error
Numbers without a decimal point
assume that the trailing zeros do not imply any additional accuracy 458,300 -> 4 significant figures 0.23 or 0.230 or 0.2300 -> 2 significant figures
Absolute Error
Multiplying or Dividing
the lowest number of significant figures retained. (1.47)(3.0926) -> 4.54612 -> 4.55
Adding or Subtracting
final significant figures determined by the error interval of the largest number 110.3 + 0.038 -> 110.338 -> 110.3
Relative Error
1.01/1.09 -> 0.9266 -> 0.927 (absolute error)
Uncertainty by absolute error
(0.001/0.927)100 -> 0.1%
Should the answer be truncated to 0.93, rather than 0.927? -> The decision is yours.
Statistical Analysis
more rigorous and complicated concept of confidence limits
2/3 can be treated as 0.6667 in relation to the accuracy of other values in the samples or problems.
If 20,100 kg is subtracted from 22,400 kg, is the answer of 2,300 kg good to 4 significant figures?
If a decimal point point were placed in each number thus 22,400. and 20,100.,
22,400. -> 5 significant figures 20,100. -> 5 significant figures
-> 3 significant figures (by relative error) -> 0.230 x 104 ? No. -> 230. x 10
Problems : Chapter 1
P1.4* P1.11** P1.12** P1.20** P1.21*** P1.30* P1.33*