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Danalyzers Specification
How Does Danalyzer Operate?
Analysis Result from Danalyzer
Manual Calculation Refers to Old
GPA and Latest GPA Standard
Calculations Comparisons
Conclusion and Recommendation
Chromatogram
C1
C3
iC4
C6+
nC4
iC5
CO2
N2
nC5
C2
Analysis Result
No.
Component Name
Mole
Gallons/
BTU Gross
Relative
Percent
1000 scf
(BTU/scf)
Density
C6+
0.0676
0.0301
3.5700
0.0022
Propane
0.4723
0.1302
11.9100
0.0072
i-Butane
0.0909
0.0297
2.9600
0.0018
n-Butane
0.1073
0.0338
3.5100
0.0022
NeoPentane
0.0000
0.0000
0.0000
0.0000
i-Pentane
0.0408
0.0149
1.6400
0.0010
n-Pentane
0.0284
0.0103
1.1400
0.0007
Nitrogen
0.5077
0.0556
0.0000
0.0049
Methane
96.8801
16.4212
980.7200
0.5366
10
Carbon Dioxide
0.6614
0.1127
0.0000
0.0101
11
Ethane
1.1437
0.3059
20.2800
0.0119
100.0000
0.5550
1025.7300
0.5786
Total
Standard Gas
No.
Component
Calibration
Concentration (%)
Peak Area
Response
Factor
C6+
0.03
74174.10
2.47E+06
Propane
0.999
1509688.80
1.51E+06
i-Butane
0.3
522534.00
1.74E+06
n-Butane
0.3
531852.00
1.77E+06
NeoPentane
0.0999
200255.54
2.00E+06
i-Pentane
0.0999
194827.98
1.95E+06
n-Pentane
0.0999
200231.57
2.00E+06
Nitrogen
2.496
2449150.08
9.81E+05
Methane
89.576
66309977.64
7.40E+05
10
Carbon Dioxide
1084720.00
1.08E+06
11
Ethane
4.999
4556838.45
9.12E+05
Composition Calculation
No.
Component
Name
Peak Area
Response
%Mol
%Mol
Factor
Unnormalized
Normalized
C6+
174040.00
2.47E+06
0.070391147
0.070611
Propane
712900.00
1.51E+06
0.471744309
0.473215
i-Butane
157208.00
1.74E+06
0.090257093
0.090539
n-Butane
188848.00
1.77E+06
0.106522867
0.106855
NeoPentane
0,00
2.00E+06
i-Pentane
77928.00
1.95E+06
0.039958364
0.040083
n-Pentane
55296.00
2.00E+06
0.027588409
0.027674
Nitrogen
473277.00
9.81E+05
0.48233034
0.483834
Methane
71603800.00
7.40E+05
96.72725308
97.02886
10
Carbon Dioxide
720112.00
1.08E+06
0.663869017
0.665939
11
Ethane
919976.00
9.12E+05
1.009243596
1.012391
99.68915822
100
Total
Component Name
Xi
Gi
Xi.Gi
Hvi
Xi.Hvi
C6+
0.000706
3.2544
Propane
0.004732
1.5226
i-Butane
0.000905
2.0068
n-Butane
0.001069
2.0068
NeoPentane
2.4912
i-Pentane
0.000401
2.4912
n-Pentane
0.000277
2.4912
Nitrogen
0.004838
0.96723
0.00468
Methane
0.970289
0.55392
10
Carbon Dioxide
0.006659
1.5196
0.01012
11
Ethane
0.010124
1.0382
Total
0.577925
3994.22
1025.044
Standard Gas
No.
Componen
Calibration
Concentration
Peak Area
Response Factor
C6+
0.03
74174.10
4.04E-07
Propane
0.999
1509688.80
6.62E-07
i-Butane
0.3
522534.00
5.74E-07
n-Butane
0.3
531852.00
5.64E-07
NeoPentane
0.0999
200255.54
0.00E+00
i-Pentane
0.0999
194827.98
5.13E-07
n-Pentane
0.0999
200231.57
4.99E-07
Nitrogen
2.496
2449150.08
1.02E-06
Methane
89.576
66309977.64
1.35E-06
10
Carbon Dioxide
1084720.00
9.22E-07
11
Ethane
4.999
4556838.45
1.10E-06
Total
100
Composition Calculation
No.
Component
Name
Peak Area
Response
% Mol
% Mol
Factor
Unnormalized
Normalized
C6+
174040.00
4.04E-07
0.070391147
0.070611
Propane
712900.00
6.62E-07
0.471744309
0.473215
i-Butane
157208.00
5.74E-07
0.090257093
0.090539
n-Butane
188848.00
5.64E-07
0.106522867
0.106855
NeoPentane
0.00
0.00E+00
i-Pentane
77928.00
5.13E-07
0.039958364
0.040083
n-Pentane
55296.00
4.99E-07
0.027588409
0.027674
Nitrogen
473277.00
1.02E-06
0.48233034
0.483834
Methane
71603800.00
1.35E-06
96.72725308
97.02886
10 Carbon Dioxide
720112.00
9.22E-07
0.663869017
0.665939
11 Ethane
919976.00
1.10E-06
1.009243596
1.012391
99.68915822
100
Total
Component Name
Xi
Gi
Xi.Gi
Hvi
Xi.Hvi
C6+
0.000706
3.2544
0.002298
5281.065
3.728994
Propane
0.004732
1.5225
0.007205
2521.921
11.93412
i-Butane
0.000905
2.0068
0.001817
3259.423
2.951034
n-Butane
0.001069
2.0068
0.002144
3269.848
3.493996
NeoPentane
2.4911
3993.718
i-Pentane
0.000401
2.4911
0.000999
4010.156
1.607389
n-Pentane
0.000277
2.4911
0.000689
4017.974
1.111952
Nitrogen
0.004838
0.9672
0.00468
Methane
0.970289
0.5539
0.537443
1012.337
982.2587
10
Carbon Dioxide
0.006659
1.5195
0.010119
11
Ethane
0.010124
1.0382
0.010511
1773.794
17.95773
Total
0.577904
1025.044
Analysis by
Danalyzer
to Old Standard
%Mol Unnormalized
99.705
99.68915822
-0,01588865 %
Relative Density
0.5786
0.577924717
-0,116709899 %
Heating Value
1025.73
1025.044004
-0,066878805 %
Parameter
Deviation
Parameter
Analysis by
Danalyzer
Manual Analysis
Refers to Latest
Deviation
Standard
%Mol Unnormalized
99.705
99.68915822
-0.01588865 %
Relative Density
0.5786
0.577903959
-0.120297495 %
Heating Value
1025.73
1025.043949
-0.066884214 %
Manual Analysis
Refers to Old
Refers to Latest
Standard
Standard
%Mol Unnormalized
99.68915822
99.68915822
0%
Relative Density
0.577924717
0.577903959
-0.003591789 %
Heating Value
1025.044004
1025.043949
-0.00000541215 %
Parameter
Deviation
Conclusion
Analysis of the composition and physical
properties of natural gas in PT PGN (Persero)
Tbk. using Danalyzer Gas Chromatograph
Model 2350 System Controller with the
reference calculations are still using GPA
Standard 2261-89, GPA 2172-86, and GPA 214589 or standards that have not been revised.
Based on Danalyzers analysis on Thursday,
February 11, 2010 at 11:01 o'clock at the offtake
stations Gresik, the natural gas flow has
methane content of 96.88%, with relative
density of 0.5786 and GHV amounted to 1025.73
BTU / scf.
Recommendation
The routine maintenance of Danalyzer Gas
Chromatograph with Model 2350 Controller System
in off-take station in accordance with the Standard
Operation Procedure should be further enhanced.
Although there are only small deviations between
the calculation by old references and new
references, but PGN should be able to respond this
differences because the results of this analysis
affects the custody transfer between PGN and
suppliers, and distributed gas quality assurance.
Revisions or updates should be performed against
the reference standard used by Danalyzer.
Response factor
Peak area of standard component
Mol Percent of standard component
G XiGi
i 1
Where :
G = Relative density
Xi = Mol fraction of sample component
Gi = Relative density of sample component
Hv X i Hv i
i 1
Where :
Hv = Heating value
Xi = Mol fraction of sample component
Hvi = Heating value of sample component