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A
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=
RT
a
E
R
#
S
B
e e
h
T k
e k
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A
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=
R
#
S
B
e
h
T k
e A
A linear expression of Eyring equation;
Slope of the graph =
Intercept =
RT
E
h
k
ln
R
S
1
T
k
ln
a B
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+
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+ =
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A
R
E
a
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+
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+
h
k
ln
R
S
1
B
#
A
For an ideal gas in transition state,
An
#
= -1 = 1 molecule (hasil AB
#
) 2 molecule (A and
B)
Then : E
a
= AH
#
+ 2RT
Eyring equation becomes;
Linear expression;
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A
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=
RT
a
E
R
#
S
B 2
e e
h
T k
e k
RT
E
h
k
ln
R
S
2
T
k
ln
a B
#
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+
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+ =
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A
Slope of the graph =
Intercept =
Small values of Ea and AH
#
- fast rate
large values of Ea and AH
#
- slow rate
ln A small, corresponding to very negative values of AS
#
-
slow rate
ln A large, corresponding to relatively positive values of
AS
#
- fast rate
R
E
a
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+
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+
h
k
ln
R
S
2
B
#
A