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Introduction
Introduction
First development ( Goodyear and Hancock) Rubber compound is a mixture of a number of different ingredients Raw gum elastomer as adhesive Significant swelling capacity of raw gum.
Raw Materials
Sulfur
Widely use cross-linking agent. Results: 1) More dimensional stable 2) Less heat-sensitivity 3) Less swelling 4) Less sticking Cheap, rubber-makers sulfur (particle size variation), oil coated.
Sulfur
Rubber-makers sulfur
suitable for vulcanizing rubber It has a low ash content Low acidity Sufficiently fine for adequate dispersion and reaction
Sulfur
Highly amorphous form of sulfur, known as insoluble sulfur, is available to reduce this problem. Dispersion in the compound can be more difficult NO affect on products performance Aesthetically displeasing
In the uncured compound, bloom can reduce tack needed in building operations such as
plying up uncured sheets of rubber to obtain thicker sheets
Together with sulfur & accelerator, constitute the cure system for the formulation and speed up the rate at which sulfur vulcanization occurs With this curing system, it can be reduced time from several hours to few minutes
Accelerators
speeds up the rate of vulcanization Grouped into several chemical classes
delayed action accelerator (sulfenamides) short induction accelerator (dithiocarbamate) o slow cure accelerator (guanidines) o Fast cure accelerator (thiurams and dithiocarbamate) sulfur donor accelerator (TMTD, DTDM)
Peroxides
suitable for curing rubber they do not need unsaturated bonds Not as popular as sulfur In the basic rubber compound formulation, the zinc oxide, stearic acid, sulfur and accelerator can all be replaced by a single material, the peroxide Contact with oxygen (air) should be avoided during vulcanization These compounds can interact with the peroxide in peroxide cure systems and thus interfere with cure
Peroxides
Advantages
improvement in heat aging resistance of vulcanizate thus lifetime can be extended upper processing temperature limits can be pushed up a little
Disadvantages
Reduced mechanical properties Post curing is sometimes undertaken for peroxide cured vulcanizates, to complete the cure and remove unwanted byproducts
Peroxides
Coagents cross-link density of a peroxide cured compound can be increased by addition of chemicals called coagents
e.g., methacrylates
This results in a higher state of cure with improvements in properties such as compression set
Antidegradant
An antidegradant is a compounding material used to retard deterioration caused by oxidation, ozone, light or combinations of these