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Chapter 17
Temperature, Thermal
Expansion, and the Ideal Gas
Law
2
Topics
3
Definitions
5
17-1 Atomic Theory of Matter
6
Unified Mass Unit (u)
7
Carbon
A
Z X
Where A = total number of nucleons (protons +
neutrons); Z is the atomic number = number of
protons (and electrons in a neutral atom); N = A – Z is
the number of neutrons.
12
6
C
For carbon 12, 1 u = 12.000 exactly, by definition.
The weighted average for all carbon isotopes is u =
12.0107.
8
Carbon
mp = 1.6726 x 10-27 kg
mn = 1.6749 x 10-27 kg
me = 9.1094 x 10-30 kg
6 x mp = 1.6726 x 10-27 kg = 1.00356 x 10-26 kg
6 x mn = 1.6749 x 10-27 kg = 1.00494 x 10-26 kg
6 x me = 9.1094 x 10-30 kg = 5.46564 x 10-30 kg
2.00855 x 10-26 kg
12 x 1 u = 12 x 1.6605 x 10-27 kg
= 1.9926 x 10-26 kg; ∆ = .01595 x 10-26 kg which is the
binding energy (B) of the nucleus.
9
Binding Energy
11
12
Albert Einstein
• His 1905 paper put Brownian motion on sound
theoretical grounds based on the assumption that
atoms really exist.
• Until that time many considered atoms merely a
convenient model for calculation with no basis in
reality.
• Einstein calculated the approximate size and mass of
atoms and molecules based on experimental data.
o
• Size 10 m. (1 Angstrom (A) = 10-10 m)
-10
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Three Phases of Matter
• Solid
• Liquid
• Gas
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Molecular Bonding
• Molecular bonding causes molecules and solids to
bond together.
• Bonding forces are electrical (governed by the
electrons surrounding the nucleus of each atom.
• When atoms get too close to each other, the repulsive
electrical forces take over.
• Principal types of bonds:
Ionic
Covalent
Metallic
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Solid
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Characteristics of Solids
• Any Solid
Maintains a fixed shape and fixed size even if a
large force is applied
Attractive forces so strong that atoms stay in more
or less fixed positions—they vibrate about these
fixed positions. As heat is added, they vibrate
more.
• Crystal
Regular periodic array of atoms (crystal lattice)
Long-range order
• Amorphous
No regular periodic array of atoms
No long-range order
17
Basic Crystal Lattice Structures
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19
Liquid
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Characteristics of Liquids
• Short-range order
• No long-range order
• Well defined boundary
• Incompressible
• Atoms in solid have begun to vibrate so much that
long-range order is lost. This happens when heat
causes the atoms in a solid to vibrate about their fixed
positions so much that the long-range order is lost.
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Gas
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Characteristics of Gases
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Vapors
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17-2 Temperature
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Temperature Scales
• Celsius (C)
• Fahrenheit (F)
• Kelvin (absolute)
• Science uses either Celsius or Kelvin.
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Example 17-2
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17-3 Thermal Equilibrium and the Zeroth
Law of Thermodynamics
• If two objects at different temperatures are placed in
thermal contact with each other (thermal contact
means thermal energy can pass from one object to the
other), the two objects will eventually reach the same
temperature.
• They are then said to be in thermal equilibrium.
• The zeroth law of thermodynamics:
If two objects are in thermal equilibrium with a
third object, then they are in thermal equilibrium
with each other.
30
17-4 Thermal Expansion
Linear Expansion
∆L = αLo∆T
where α is the coefficient of linear expansion.
Its units are (Co)-1.
This equation is empirical.
31
32
Example 17-3
Bridge expansion.
The steel bed of an expansion bridge is 200 m
long at 20o C. If the extremes of temperature to
which it might be exposed are – 30o to + 40o C,
how much will it contract and expand?
33
Conceptual Example 17-4
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35
Example 17-5
Ring on a rod.
An iron ring is fit snugly on a cylindrical iron rod. At
20o C, the diameter of the rod is 6.445 cm and the
inside diameter of the ring is 6.420 cm. To slip over
the rod, the ring must be slightly larger than the rod
diameter by about 0.008 cm. To what temperature
must the ring be brought if its hole is to be large
enough so it will slip over the rod?
36
Thermal Expansion
Volume Expansion
∆V = βVo∆T
where β is the coefficient of volume expansion.
Note: β 3α.
The units of β are (Co)-1.
37
Example 17-6
38
17-5 Anomalous Behavior of Water
Below 4oC
• Most substances expand more or less uniformly with
an increase in temperature (as long as no phase
change occurs).
• Water, however, does not follow the usual pattern.
• If water at 0o C is heated, it actually decreases in
volume until it reaches 4o C.
• Above 4o C water behaves normally.
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40
17-6 The Gas Laws and Absolute
Temperature
• Equation of state of a gas is the relationship between
pressure, volume, and temperature.
• Will consider only equilibrium states of a system.
That is, the state variables are constant in time
throughout the system.
• Why?
• The field is called non-equilibrium
thermodynamics. It was developed in the mid-20th
century by Ilya Prigogene.
41
Boyle’s Law
V 1
P
or PV = constant
42
Charles’s Law
VT
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Gay-Lussac’s Law
P T
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The Three Laws
• The laws due to Boyle, Charles, and Gay-Lussac are
not really laws in the sense that we use this term
today.
• That is, precise, deep, and of wide-ranging validity.
• They are really only approximations that are accurate
for real gases only as long as the pressure and density
of the gas are not too high, and the gas is not too
close to condensation.
• The term law applied to these three relationships has
become traditional however.
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17-3 The Ideal Gas Law
PV T.
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The Ideal Gas Law
PV = nRT
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The Ideal Gas Law
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Since zero volume is
impossible, one can
never reach absolute
zero.
52
Mole
53
Mole
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Example 17-8
Volume of one mol at STP.
Determine the volume of 1.00 mol of any gas,
assuming it behaves like an ideal gas, (a) at STP, (b)
20oC.
56
Example 17-9
57
Example 17-10
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17-9 Ideal gas Law in Terms of
Molecules: Avogadro’s Number
• Amedeo Avogadro (1776 – 1856)
• Avogadro’s hypothesis states: equal volumes of gas
at the same pressure and temperature contain equal
numbers of molecules.
• Avogadro’s number:
NA = 6.02 x 1023 molecules/mole.
• That is, Avogadro was the first to clearly realize that
the volume of a gas depends on the number of
molecules it contains.
• Or, 1 mole of any substance contains NA numbers of
molecules (or atoms as the case may be). 59
In Other Words
60
Calculation of Avogadro’s Number
12 x 10-3 kg/mol
= 6.0214 x 1023
molecules/mol
1.9926 x 10 kg/molecule
-26
61
Boltzmann’s Constant
The total number of molecules, N, in a gas is equal to
the number of mols times the number of
molecules/mole:
N = nNA
N NA
PV = nRT = RT
PV = NkT
where: k = R/NA
62
-23
Example 17-11
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Homework Problem 1
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Homework Problem 2
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Homework Problem 13
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Homework Problem 15
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Homework Problem 32
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Homework Problem 36
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Homework Problem 46
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