Professional Documents
Culture Documents
15-Feb-14
AIM
To apprise the audience about various GRP materials, methods for the production of hand laid-up GRP moulding, common defects and quality control of GRP layup
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SCHEME OF LESSON
Introduction to GRP Materials Moulds and Mould Preparation
Day 1 & 2
Day 3
Day 4
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SCHEME OF LESSON
Sandwich Structures Handling/Transportation of finished Mouldings
Day 5
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REFERENCES
Defence Standard 02-701 (NES 701) Part 1 Defence Standard 02-701 (NES 701) Part 2 Fiberglass Boat Design and Construction by Robert J Scott Open Sources (Internet web sites)
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INTRODUCTION TO GRP
Glass Reinforced Plastic (GRP) or Fiberglass Reinforced Plastic(FRP) is a two component structural matrix consisting of:
Fiberglass or glass material Thermosetting Liquid resin
GRP is a truly synergetic material in which combination of two materials has superior characteristics than either material individually Resin with relatively poor physical properties and would not perform well as structural material The glass portion though composed of strong glass filaments, is utilized as fabric and has no structural capabilities except in tension
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INTRODUCTION TO GRP
Matrix of glass and resin is similar in principle to reinforced concrete where
Like steel reinforcing bars, glass reinforcement are main load carrying members The resin performs a function similar to concrete in supporting and positioning the reinforcement so that it can perform effectively
Glass material provides the major strength whereas resin binds the glass reinforcement together and distributes applied loads uniformly between the individual glass fibres
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INTRODUCTION TO GRP
Advantages of GRP Resistance to marine environment (Anti fouling paint however required) Light Weight (One half the weight of equivalent steel or wood structures and almost equal in weight to Aluminum) High strength to weight ratio. Long exposure to marine environment has little effects on its properties Seamless Construction Chemically inert (No threat of galvanic corrosion)
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INTRODUCTION TO GRP
Advantages of GRP Ability to orient fiber strength Ability to mold complex shapes Good against impact loads (such as slamming) Competitive Cost (In case of serial production) Ability to mold in colours Easy Repair Low maintenance Durability (Prolonged Hull life)
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INTRODUCTION TO GRP
Disadvantages of GRP Stiffness
Modulus of elasticity 2 x 106 PSI as compared to steel with 30 x 106 PSI and Al with 10 x 106 PSI . Modulus of elasticity can go up to 4-6 x 106 PSI in case of unidirectional laminates or high strength glass/carbon composites GRP in disadvantage in deflection critical application
Relatively lower fatigue strength. Notch toughness to be evaluated to determine stress concentration problems at hatch corners, ending of stiffeners, decks etc
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INTRODUCTION TO GRP
Disadvantages of GRP Low buckling strength Creep
GRP has tendency to creep if subjected to long term loading, though this not a problem with normal boat structures
Vibration Low abrasion resistance than metals but better than wood, thus necessitates use of bumpers or chafing plates in areas where abrasive loads might occur
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INTRODUCTION TO GRP
Disadvantages of GRP Vulnerability to Fire
Flame spread rate of conventional GRP and Plywood is same
Fire Retardant resins available though they give out toxic flames and properties of laminate decrease with heat
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SCHEME OF LESSON
MATERIALS
MATERIALS
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MATERIALS
GRP consists of:
Layup Resins Glass material
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LAY UP RESINS
The resins used for hand lay-up GRP fabrication are all liquids, that can be cured to form tough solids by the addition of suitable curing agents Various types of resins are:
Polyester Resins
Epoxide Resins Phenolic Resins
Gelcoat Resins
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LAY UP RESINS
POLYESTER RESINS Polyester resins are normally used as these are usually:
The most economical
The curing of polyester resins is brought about by the addition of two materials i.e. a curing agent (catalystnormally a peroxide) and an accelerator (normally a cobalt soap)
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LAY UP RESINS
POLYESTER RESINS The catalyst promotes a chemical reaction causing cross-linking of molecules in the resin The accelerator controls the rate of cure of the resin and, in particular, the usable pot life (gel-time) The amount of catalyst & accelerator used with a given resin should always be that recommended by the resin manufacturers The accelerators and curing agents for Polyester resins MUST NEVER BE MIXED TOGETHER. Each material is to be mixed separately with the resin, first the accelerator, second the catalyst. Neglect of this precaution can lead to a fire or an explosive reaction
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LAY UP RESINS
EPOXIDE RESINS Epoxide resins are used on high strength structures, some specialized applications and as adhesives (polyester resins are not suitable for the latter) Epoxide resins possess
Superior abrasion resistance Less water absorption Greater bonding strength
The curing of epoxide resins is brought about by the addition of a curing agent (catalyst/hardener) only. The amount of hardener used is fixed by manufacturers and must not be varied in an effort to alter the gel-time of the system as such a variation will lead to an improperly cured resin with poor mechanical properties
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LAY UP RESINS
PHENOLIC RESINS Phenolic resins have excellent inherent resistance to fire combined with very low smoke and toxic evolution The curing of phenolic resins is brought about by the addition of a catalyst. The amount and type of catalyst used is fixed by manufacturers Gel-coat phenolic resin pastes have been developed to give phenolic laminates smooth pin-hole free surface finishes Phenolic resins should not be used for GRP mouldings that are likely to come into contact with foodstuffs, directly or indirectly
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LAY UP RESINS
GEL COAT A resin applied to the surface of a mould and gelled before lay-up. The gel-coat becomes an integral part of the finished moulding, and is usually used to improve surface finish
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LAY UP RESINS
It is important to note that all the resins (polyester, epoxide, phenolic) do not develop their full mechanical properties as soon as they have hardened. All types require a period of several days at room temperature for a reasonably full cure, but the rate of cure can be accelerated by the application of heat. Again the resin manufacturers recommendations should be followed
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GLASS REINFORCEMENTS
Glass reinforcements are available in five forms
Chopped Strand Mat (CSM) Woven Rovings (WR) Woven Fibre Cloths Combination Cloths Double-bias Cloth
The composition of the glass should be that known as E-glass High strength reinforcements also exist and are discussed in later part
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GLASS REINFORCEMENTS
Chopped Strand Mat (CSM) CSM, consisting of randomly dispersed glass fibres about 50mm long held together with a suitable binder
Cheapest and most widely used reinforcement Moderate strength Homogeneous material with equal physical properties in all directions Easy to wet Builds up laminate thickness at rate of 20 piles/inch (If mat weighs 1 ounces per sq foot)
When working with mats, it is important to use the minimum amount of resin consistent with good wetting of the glass. CSM should comply with BS 3496 for use with polyester resins
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GLASS REINFORCEMENTS
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GLASS REINFORCEMENTS
Woven Roving (WR) WR consist of glass rovings (bundles of glass fibres) woven into either a plain-weave cloth, for general use, or as a predominantly unidirectional cloth for structures requiring maximum strength in one direction
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Higher strength than mat Good drapeability and handling characteristics Builds up laminate thickness rapidly (25 piles/inch) Good resistance to impact because of continuous and untwisted strands
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GLASS REINFORCEMENTS
Woven Roving (WR) Woven rovings for use with polyester resins are to comply with BS 3749 or NES 166
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GLASS REINFORCEMENTS
Woven Fibre Cloth Woven fibre cloths are manufactured from spun yarns and are available in a range of weights and weaves. Because of their high cost, cloths are normally used for structures in which a high strength to weight ratio or where close control of resin to glass ratio is required The choice of weave is generally dictated by the stresses which the structure will have to withstand when in use
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GLASS REINFORCEMENTS
For maximum impact strength
Cloth having a large amount of crimp in the fibres is required; this is achieved by using a square-weave cloth woven from heavy yarns
Woven fabrics are to comply with BS 3396; Parts 13 and be made from E-glass
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GLASS REINFORCEMENTS
Combination Cloth Combination cloth is a mixture of CSM and WR and is used to improve cost efficiency. However care must be taken to ensure that the weave of the woven roving is in the correct direction for the design requirement and that the inner layers of glass are completely wetted by the resin
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GLASS REINFORCEMENTS
Double Bias Cloth Double-bias cloth has the fibres at angles and is used to lay down reinforcement at various angles in large mouldings where it would be uneconomical or impractical to lay the normal 0/90 cloth at an angle when strength in all directions is required
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GLASS REINFORCEMENTS
Surfacing Tissue Surfacing tissues are very thin (0.25mm0.44mm) reinforcing fabrics used to strengthen the gel-coat of a GRP structure to prevent crazing of the resin and to minimize impact damage. Very thin glass mats are sometimes used but non-woven synthetic fabrics are generally preferred. Only a single layer of surfacing tissue is use
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GLASS REINFORCEMENTS
High Strength Reinforcements Number of high strength reinforcements available but use limited due high cost Most commonly used such reinforcement is S Glass, KEVLAR and carbon fiber, woven in bi-directional or uni-directional fabric with minimum number of fill or cross fiber Carbon fiber generally laid up with epoxy resin Besides being expensive, consideration of high strength laminate is complicated by relative performance. E.g
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STORAGE OF MATERIALS
Glass Reinforcements Rolls of glass reinforcements to be stored in clean dry room with humidity less than 70% Rolls individually wrapped in moisture-proof wraping Rolls of material should not be stood on end; suitable racks or shelving should be provided NOTE: Dampness of glass reinforcements causes an irreversible loss of reinforcing strength
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STORAGE OF MATERIALS
CORRECT WAY
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WRONG WAY
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STORAGE OF MATERIALS
GRP Chemicals Polyester resins and accelerators, epoxide resins, and phenolic resins should be stored in a cool dry place, at a temperature no higher than 20C
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SCHEME OF LESSON
MATERIALS
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MOULDS
A variety of materials is suitable for the construction of moulds for hand-laid GRP Sheet Metal Moulds
Made from aluminum alloy or mild steel sheet
Sheet metal moulds are suitable for small mouldings and short production runs
Metal moulds for use with phenolic resins should be either stainless steel or plated to avoid acid attack
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MOULDS
Sheet Metal Moulds
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MOULDS
Timber Moulds
Moulding surface of the mould is sealed to prevent the absorption of parting agent and resin into the timber. This can be achieved, together with a good surface finish, by applying several coats of furan varnish to the mould Timber moulds are only used for short production runs (about 50 per mould) For the production of large numbers of small items densified wood is preferred to the more usual timbers Timber moulds should not be used for the production of phenolic resin mouldings
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MOULDS
GRP Moulds
GRP moulds are made from a master pattern, or when available, an existing item Polyester moulds should be well cured to ensure that no free styrene is present that could result in release problems
Plaster and Concrete Moulds Wax Moulds Flexible Moulds Moulds with Undercuts
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SCHEME OF LESSON
MATERIALS
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Containers for resin mixtures. These should be constructed from tinplate, porcelain, glass, stainless steel or polythene
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Timber inserts should be clean. Any contamination should be removed with glass paper. Some timber preservatives may inhibit the cure of the resin. Zinc naphthenate is acceptable as a timber preservative
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SCHEME OF LESSON
MATERIALS
MOULDING OPERATION
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MOULDING OPERATION
Moulding Shop The shop used for the actual moulding operation should preferably be used for this purpose alone. No other form of operation should be allowed in the moulding area (except for cloth cutting, resin mixing if extremely essential) The shop is to be heated such that the room temperature never falls below 15C during lamination and 10C during curing Condensation should be kept to minimum. Draught free ventilation to remove vapours
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MOULDING OPERATION
Moulding Shop Air flow velocity over the face of uncured laminates must not exceed 1metre/sec; greater air-flow velocity would remove styrene too rapidly and prohibit satisfactory cure
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MOULDING OPERATION
Moulding Tools Tools are required to ensure thorough impregnation of the glass and that all air bubbles are worked out The usual tools are paint brushes, metal, polythene, nylon and lambswool rollers, flat squeegees
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MOULDING OPERATION
Moulding Tools Paint brushes used for hand lay-up should have unvarnished handles and bristles (hair, coat). The varnishes used in brush manufacture and rubber compounds used for setting some brush bristles are resin solvent and inhibit resin cure
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MOULDING OPERATION
Laminating Temperatures Polyester Resin
Laminating should not to be undertaken when the ambient temperature is below 15C or above 30C
Epoxide Resins
Manufacturers advice should be sought regarding laminating temperatures for epoxide systems
Phenolic Resins
Laminating should be carried out at a minimum temperature of 15C
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MOULDING OPERATION
Application of Gel Coat The first step in fabricating a GRP moulding by hand lay-up is to apply a gel-coat. The gel-coat may be applied either by hand or by spray gun
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MOULDING OPERATION
Application of Gel Coat If applied by spray gun
The resin will have to be diluted with styrene (if a polyester) to allow for styrene loss by evaporation The dilution rate recommended by the resin manufacturer is not to be exceeded
To achieve even coverage, it may be necessary to use a thixotropic additive or a formulated gel-coat resin. The gel-coat should be lightly pigmented, to the colour scheme of the finished moulding, to assist complete coverage of the mould
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MOULDING OPERATION
Application of Gel Coat The gel-coat should be inspected as per Part 2 of NES 701 prior layup After the gel-coat has been applied to the mould, the surfacing tissue should be laid in the mould and be gently rolled into the gel-coat The gel-coat should then be allowed to gel (gel time as specified by manufacturer), before proceeding with the build up of the laminate. Lay-up of the laminate should then follow within 12 hours of the gel-coat setting
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MOULDING OPERATION
Lay-up of Laminates The tailored section of reinforcement should be weighed and to ensure complete wetting out of the reinforcement, a slightly greater weight of mixed resin than is required to give the specified resin glass ratio should be taken Apply resin using paint brush on first layer of laminate Using a roller or squeegee, the resin should be worked through the reinforcement until the latter is thoroughly wetted and visible air bubbles minimized
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MOULDING OPERATION
Lay-up of Laminates A second application of resin should now be made followed by a second layer of reinforcement and so on until the finished thickness of the laminate has been reached Less and less resin may be required for successive layers of reinforcement Over-rolling must be avoided. This is particularly important when using glass mats as the binder dissolves in the resin and if the laminate is over-rolled the glass fibres are distributed by the roller so that glass-rich and resin-rich areas are formed in the laminate
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MOULDING OPERATION
Lay-up of Laminates It is essential that the quantities of resin and reinforcement are continuously monitored and recorded throughout fabrication since The resin glass ratio and uniformity of impregnation will influence the physical properties of the finished laminate
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MOULDING OPERATION
Lay-up of Laminates Edges of adjacent pieces should be butted or overlapped depending on the application and thickness tolerance Overlaps should be 5075mm in the case of CSM For WR the weft selvedge tails should overlap the outer warp roving of the adjacent cloth by their own length (20mm) Overlaps should when possible be staggered to aid production of a smooth surface
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MOULDING OPERATION
Lay-up of Laminates Butts in the reinforcement should be staggered 150mm relative to butts in the underlying ply and superimposed butts must be separated by at least six passing plies Corners and re-entrant angles in a moulding should be thoroughly wetted
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MOULDING OPERATION
Lay-up of Laminates Mouldings over 9mm in thickness must be laid up in several stages to avoid excessive exothermic heat during the initial cure of the resin Practical maximum layup limit, at compartment temperatures of 20C, is approximately four plies of 600g/m2 CSM or ten plies of 830g/m2 WR; if this limit is reached, a period of 12 hours is to elapse before any further plies are laid When the compartment temperature is higher, the number of plies laid must be reduced
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MOULDING OPERATION
Lay-up of Laminates When unbalanced weave-materials are being used, eg unidirectional cloths, care must be taken to ensure that the cloth warp is laid in the direction of maximum stress Inspection is essential during each stage of fabrication For large mouldings, pre-impregnated cloth should be used. The glass cloth is passed to a resin dispenser into which resin and catalyst are fed at a controlled rate to give the required resin:glass ratio. The dispensing equipment is mounted on a gantry and traversed across the mould laying down the impregnated cloth which is then consolidated using rollers or squeeges
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MOULDING OPERATION
Lay-up of Laminates If completion of a lamination is delayed for an extended period a peel-ply, usually of terylene, should be lightly rolled into the surface. This can be peeled-off when laminating recommences. If a peel-ply cannot be laid down then, if the elapse period extends for more than seven days, the surface of the laminate should be wiped with styrene and left 15 minutes or abraded (care being taken to avoid cutting plies of reinforcement) before additional plies are laid. Lay-up delays of up to seven days are acceptable without surface preparation of use of peel-ply
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MOULDING OPERATION
Lay-up of Laminates Phenolic-based adhesives are widely used in woodworking, consequently no woodworking operations using phenolic-based adhesive should be allowed in the moulding shop
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SCHEME OF LESSON
MATERIALS
CURE OF MOULDS
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CURE OF MOULDS
Cure Time in Moulds After completion of the lay-up, the assembly must be left until the resin has hardened sufficiently The cure period varies with the resin used and the design specification and/or the resin manufacturers recommendations In cases of difficulty in the removal of mouldings, the application of compressed air between the moulding and the mould is usually an effective aid Phenolic resin mouldings may be heated to 4070C whilst still in the mould.
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CURE OF MOULDS
Post cure Although amoulding is usually strong enough to be handled some twelve hours after the completion of the lay-up, the resin will not have hardened sufficiently for the maximum mechanical properties of the laminate to have developed; therefore, a postcure must be applied to the moulding before finishing operations can be carried out Post cure may include leaving mould at room temp for specified time or in a heated room for specified time
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CURE OF MOULDS
Post cure
Temperature 20C 30 C 40 C Post-cure time 30 days 14 days 3 days 80 C 120 C 7 hours 2 hours
A period of at least 24 hours at room temperature must be allowed to elapse before any post-cure is applied The lower the post-curing temperature, the less chance of distortion in the moulding
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CURE OF MOULDS
Post cure With epoxide resin systems the post-cure manufacturers curing schedules must be followed For phenolic laminates the amount of post-cure given is governed by the use to which the moulding is to be put, i.e by the performance specification, and the resin manufacturers advice should be sought. Typical post-cure times are in the range 48 hours at 5060C.
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SCHEME OF LESSON
MATERIALS
FINISHING OPERATIONS
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FINISHING OPERATIONS
The finishing operations carried out on GRP mouldings, are much the same as those used for other materials, e.g sawing, drilling of holes, riveting, painting, etc
In all cases, deviations from normal wood or metal working practice are necessary if the best product is to be made
Mouldings are to be fully cured before finishing operations are begun
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FINISHING OPERATIONS
Sawing and Trimming Because of the very abrasive nature of glass the best saws are those with an electrometallic bonded diamond cutting edge
Tungsten carbide and high speed steel tipped saws can be used but have a much shorter life than the diamond tools Band-saws with a tooth pitch in the range 8 to 18 teeth per 25mm should be used with cutting speeds up to 300m/min
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FINISHING OPERATIONS
Sawing and Trimming The direction of cut must always be such as to start at the gel-coat and then proceed into the body of the moulding. This prevents chipping and crazing of the gel-coat Saw blades must always be sharp and correctly set After sawing, the cut edge of the moulding should be smoothed with fine emery cloth applied along the length of the cut edge and never at right angles to it as this latter action causes local delamination and chipping of the gel-coat
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FINISHING OPERATIONS
Sawing and Trimming After smoothing, the cut edge of the laminate should be sealed with a room-temperature curing epoxide resin or in the case of polyester laminates with polyester resin Ensure health safety
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FINISHING OPERATIONS
Drilling All holes drilled in GRP should be drilled from the gel-coat side Holes more than 6mm diameter require the use of rigidly supported back-up pieces of hardwood or plastic to prevent chipping of the back face Holes in excess of 40mm diameter and non-circular holes should be cut either by sawing or using an electrometallic diamond edge routing tool
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FINISHING OPERATIONS
Drilling If a hand held jig saw of the pattern which cuts as the saw is drawn into the body of the tool is used, sawing must be carried out from the back of the laminate to avoid gel-coat damage The cut edges of all holes should be sealed with a coat of room temperature curing epoxide resin or polyester resin Safety precautions in drilling of GRP are the same as for sawing (will be discussed in health and safety)
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FINISHING OPERATIONS
Water-Jet Cutting Water-jet cutting is relatively new and offers fast, low temperature, distortion-free, accurate and clean cutting Abrasive water-jet cutting, in which abrasives are introduced into the water jet, is especially suited to nonhomogeneous materials, such as GRP, that are abrasive in nature and damaging to more conventional cutting tools The equipment can have simple XY movement or have intricate shape cutting capabilities by the use of computer controlled articulated robots with multiple axes cutting ability
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FINISHING OPERATIONS
Water-Jet Cutting A hydraulically driven intensifier unit pumps filtered and conditioned water, at pressures up to 410 MPa and rates of 4 to 8 L/min The high pressure fluid is expelled through an orifice to form a jet of water, propelled at speeds up to 850m/s For abrasive water-jet cutting an abrasive material, eg garnet grit, is introduced into the water stream after the primary jet is formed. A fine grit may be used to produce a smooth surface finish
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FINISHING OPERATIONS
Water-Jet Cutting Because composite materials may delaminate in the area surrounding the initial penetration, the water-jet is usually activated away from the work piece and then guided into the desired edge The technique produces very low dust-level, so reducing the risk to health and fire hazard. However, because of the air coupling into a large high-velocity volume of air/water, noise levels are high and appropriate ear protection is required
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FINISHING OPERATIONS
Laser Cutting Focused CO2 laser beams are now being used to cut a wide range of composites and complex cutting can be achieved by manipulating the beam by a five-axes robot In order to cut, a laser must be integrated with the means to deliver the beam, handle the workpiece and be in an enclosure that ensures the safety of personnel from the beam and any irritating and/or toxic gases released by the thermal degradation of the resin
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FINISHING OPERATIONS
Laser Cutting When cutting GRP thermal damage to the matrix may result due to heat conduction along the fibres. Also when cutting laminates over 10mm thick charring may be a problem Charring is a chemical process of incomplete combustion of certain solids when subjected to high heat. The resulting residue matter is called Char.
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FINISHING OPERATIONS
Bolting of Laminates Fasteners must never be pulled up directly on to the laminate surfaces but should have large diameter washers or a drilled clamping plate of the fastening material under both the bolt head and the nut Where the use of nuts and bolts is not possible and recourse has to be made to the use of bolts screwed into tapped holes, a metal insert should be included in the moulding. The fastening holes can then be drilled and tapped in the insert A wire thread insert (Helicoil or Crosswire) in a hole tapped in the GRP is only suitable for lightly loaded structures
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FINISHING OPERATIONS
Bolting of Laminates Bolt hole spacing should be:
not less than 3 bolt diameters from the edge of the laminate;
from 3.5 to 4.5 bolt diameters apart for structural and watertight joints;
from 5 to 8 bolt diameters apart for non-structural applications.
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FINISHING OPERATIONS
Riveting of Laminates Riveting of laminates should be avoided whenever possible. However, when used, rivets should be of soft aluminium and be driven with a washer of the same material under both head and point. Rivets greater than 5mmshould be avoided whenever possible Spacing of rivets should be:
not less than 3 rivet diameters from the edge of the laminate from 3.5 to 4.5 rivet diameters apart
During all riveting operations, GRP mouldings must be very soundly supported
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FINISHING OPERATIONS
Riveting of Laminates Explosives and similar riveting systems must not be used. The proprietary Advel fastener is recommended as an alternative to riveting for sizes above 5mm
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SCHEME OF LESSON
MATERIALS
SANDWICH STRUCTURES
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SANDWICH STRUCTURES
Sandwich structures consist of lightweight core material with a skin of GRP on either side The purpose of sandwich construction is to increase rigidity of panel by increasing its thickness with relatively little increase in weight The core materials commonly used are:
Wood Foamed Plastics
Honeycomb
Microballons Buoyancy Foam
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SANDWICH STRUCTURES
Alternative core materials, i.e polyetherimide (PEI) and phenolic foams, possessing superior fire characteristics to those listed above are being evaluated and may eventually be considered
The basic lay-up technique is used when making sandwich structures, with some detail modifications in both mould design and lay-up procedure. NES 752 may be considered as guideline
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CORE MATERIALS
WOOD Plywood, Soft Woods and Balsa are typically used woods as core material Plywood
Good strength, rigidity and ability to withstand local loads
Commonly used for bulkheads and deep girders Relatively heavy and should be of exterior grade only
Hard woods are not used since they have tendency to swell and crack the covering laminate and do not bond well with GRP
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CORE MATERIALS
WOOD Soft Woods
Soft woods such as pine used for framing and similar application Can cause swelling problems, however, bond well with GRP
Balsa
Balsa wood, weighing b/w 6 to 9 pounds per cubic foot, is commonly used as light weight core material for small boat construction
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CORE MATERIALS
WOOD Balsa
In end grain configuration, with the grain perpendicular to laminate, the bond strength is relatively high, upto 1000 PSI due the resin wicking into elongated cells of balsa Bond strength can further be increased by use of vacuum injection, which provides added benefit of filling the gaps between individual balsa blocks to prevent water migration through core
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CORE MATERIALS
WOOD Due possible rotting, swelling and degradation, the use of wood cores in areas below the waterline, or adjacent to tanks is not recommended unless special precautions are taken In case of balsa, there has been a controversy over its use below waterline. Some research however shows penetration of the end grain balsa of less than 1/8 inch after 1000 hours exposure to sea water
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CORE MATERIALS
FOAMED PLASTIC Foamed plastics such as polystyrene, polyurethane and ployvinyl chloride (PVC) offer advantages of light weight and resistance to water, fungi and decay
Low shear and compressive strength, especially of very light foams, make them susceptible to delamination and damage from local loads To avoid excessive core thickness on highly loaded panels, FRP shear webs between faces of sandwich panels may be used
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CORE MATERIALS
FOAMED PLASTIC Polystyrene
Not generally recommended since it is attacked by polyester resin
Polyurethane
A rigid material which will generally not conform to surface curvature, however, used in boat building
CORE MATERIALS
FOAMED PLASTIC Polyvinyl Chloride (PVC)
Tendency to soften when heated can however cause problems if ambient temp is too high. Hence use of PVC on surfaces exposed directly to intense sunlight like deck or in engine room compartment is not recommended A cross linked foam containing both PVC and polyurethane is available which reduces above mentioned problem, but has somewhat reduced properties PVC core material is also softened by polyester resin and must be either treated with a sealant or used in conjunction with resin having a styrene content below 30% and gel time of less than 30 min for the first layer of re-inforcement
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CORE MATERIALS
FOAMED PLASTIC Structural grade foams usually have 96 to 128 Kg per cubic meter density. Lighter foams may be used, however physical properties diminish rapidly with decreasing density
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CORE MATERIALS
HONEYCOMB Honeycomb cores of aluminium, fibergalss laminate, phenolic, waterproof paper and nylon are available in various sizes and weights
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CORE MATERIALS
HONEYCOMB They have light weight, good rigidity and poor resistance to concentrated loads Highly developed fabrication techniques required to produce good bonding b/w core and facing. Imperfect bonding will result in water travel throughout core in case of a leak In marine construction, honeycomb cores limited to interior decks, flats and bulkheads where light weight is essential
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CORE MATERIALS
HONEYCOMB Honeycomb cores configurations available in various
Hexagon and square recommended for use on flat panels and applications as radomes For conforming to shaped surfaces, knifed and flex- core honeycombs are available
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CORE MATERIALS
MICROBALLONS Light weight hollow glass or gas-filled phenolic spheres and polystyrene beads embedded in resin are example of high density, trowelled-in-place core material presently being used in some boat hulls and deep-submergence vehicles Use is limited due high cost, used only where high core strength is required Alternate may be a core insert of vermiculite and resin (80% resin by weight)
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CORE MATERIALS
BUOYANCY FOAM Polyurethane or polystyrene foams of about 32 Kg per cubic meter used for flotation in small boats Foams may be installed as pre-cured blocks or in case of polyurethane foamed in place
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SCHEME OF LESSON
MATERIALS
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Chain or wire rope is permitted if adequate arrangement to prevent local loads and abrasion is made When lifting, care should be taken not to apply shock loads to the lugs or moulding
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SCHEME OF LESSON
MATERIALS
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In the event of a serious spillage which enters public drains or waterways, the Local Water Authority must be informed immediately (CANT SAY ABOUT PAKISTAN)
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SCHEME OF LESSON
MATERIALS
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Tap Tests
Radiographic Inspection
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freedom from air voids entrapped in the laminate. (The use of unpigmented resin makes visual inspection much easier) dimensions
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0 compression waves should be used with frequencies in the range 0.5 to 5MHz. Guidance on the selection and use of ultrasonic equipment is given in NES 729 Part 5
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GEL-COAT DEFECTS
Surface Fibre Pattern Star Cracking Crazing Pin Holes on Gel-Coat Cratering and Blistering Wrinkling of Surface Poor Adhesion Fish Eyes Internal Dry Patches Leaching Distortion or Warping
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GEL-COAT DEFECTS
SURFACE FIBRE PATTERN If the gelcoat is thin or the reinforcement is applied before the gelcoat is sufficiently cured the roving pattern may print through and be visible in the gelcoat when the hull is released
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GEL-COAT DEFECTS
Fault Cause Gel-coat not cured sufficiently before commencing lay-up Gel-coat too thin Remedy Ensure adequate cure of gel-coat
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GEL-COAT DEFECTS
STAR CRACKING Due to an over thick gelcoat but this time it must have received an impact from the inside
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GEL-COAT DEFECTS
Fault Star Cracking Cause Remedy no
Result of an over thick Ensure gel-coat gel-coatoccurs when thicker laminate has received a than 0.5mm reverse impact
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GEL-COAT DEFECTS
CRAZING Crazing usually indicates a gelcoat which is too thick and has crazed during flexing of the hull
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GEL-COAT DEFECTS
Fault Cause Gel-coat too thick Use a brittle resin or resin containing excess monomer Excessive accelerator in formulation or curing temperature too high. (Sometimes gives orange peel effect) Remedy Use even thickness gelcoat Use properly formulated gel-coat resin Check resin formulation Use experimentally verified mix Avoid high temperatures
Crazing
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GEL-COAT DEFECTS
PIN HOLES IN GEL-COAT Small air bubbles trapped during the cure show up on release
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GEL-COAT DEFECTS
GEL-COAT
Fault Cause Remedy
Use non-silicone wax on Gel-coat not wetting mould surface followed by release agent on mould a PVA release agent Minute air bubbles in the surface of the laminate. Caused by poor mixing of filler into thixotropic gelcoat and/or overbrushing of gel-coat when applied to mould Occluded air in the filler used in resin formulation Mix resin by mechanical means. Apply resin carefully using minimum brushwork consistent with uniform resin coverage Use only fillers which have been treated for use with polyester or epoxy resin as appropriate
Pinholes in Gel-coat
Mould under clean conditions. Ensure that dust cannot fall on mould before Introduction to GRP and Hand Laid-up application of gel-coat
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GEL-COAT DEFECTS
CRATERING AND BLISTERING An indication of delamnation between layers on older vessels. It is potentially the most serious of problems
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GEL-COAT DEFECTS
Fault Cause Usually caused by air or solvent trapped between gel-coat and laminate proper. If reinforcement is carefully rolled down this defect should not occur Remedy
Check resin:glass ratio; a deficiency of resin often causes air ubbles. Check the grade of any glass mat used. If the binder is insoluble in the resin the fibre will not If parting agent not bed down. Ensure that agent is thoroughly dry, volatiles parting will cause lifting of gel- thoroughly dry before applying gel-coat coat
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GEL-COAT DEFECTS
WRINKLING OF SURFACE This is caused by the heat released by the following laminate immediately attacking an under cured thin gelcoat
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GEL-COAT DEFECTS
Fault Cause Remedy
Wrinkling of Surface
Prevent drainage of gelToo thin a gel-coat coat by ensuring which is under cured. adequate amount of Often on vertical thixotropic agent in surfaces formulation Under cure as a result of Ensure that there are no styrene (or other draughts in vicinity of monomer) evaporation the moulding
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GEL-COAT DEFECTS
POOR ADHESION It occurs when a gelcoat is left unreinforced for too long. A weekend is long enough
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GEL-COAT DEFECTS
FISH EYES Fish Eyes are caused by the gelcoat de-wetting from the polished mould surface in spots. Occurs mainly when silicone based waxes are used. These, in particular car waxes, should be avoided
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GEL-COAT DEFECTS
INTERNAL DRY PATCHES Areas where resin has not penetrated
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GEL-COAT DEFECTS
LEACHING Leaching a serious fault. Severe weathering can remove a poor resin from surface of a laminate
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GEL-COAT DEFECTS
DISTORTION OR WARPING Causes
Differential shrinkage between unreinforced gel-coat and reinforced laminate
Remedy
Use a reinforced gel-coat Use thin gel-coat Use a specially formulated gel-coat resin
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ACCEPTANCE CRITERIA
GEL-COAT Small areas up to 1200mm2 exhibiting defects shown on previous slides are acceptable except in case of radomes and sonar domes
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LAMINATE DEFECTS
Bubbles in Body of Laminate Resin-rich and Glass-rich Areas Delaminated Areas within Body of Laminate Crazed Areas Tacky Laminate Surface Internal Dry Patches
Undercure
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LAMINATE DEFECTS
BUBBLES IN BODY OF LAMINATE Air trapped in a laminate is undesirable because its presence lowers the strength of the part, reduces radar and acoustic transparency, and in extreme cases, results in a porous laminate
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LAMINATE DEFECTS
Fault Cause Remedy
Check resin glass:ratio Insufficient resin and/or being worked. Ensure mat incorrect binder on glass binder is soluble in resin in mat use. Check operator is fully trained Bubbles in Body of Laminate
Damp reinforcement
Check reinforcement storage conditions. If recently delivered, reinforcement may require drying in a warm room
Excessively short gel-time Check resin formulation. Do or too thick a lay-up leading not lay-up more than 8mm to excessive heating or of laminate at one time resin on gelation
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LAMINATE DEFECTS
RESIN-RICH AND GLASS-RICH AREAS (WASHING)
This defect is almost entirely confined to chopped strand mat reinforced laminates and is caused by excessive working of the material during fabrication leading to displacement of the glass and consequently to glass-rich and resin-rich areas. Resin-rich areas in a laminate are points of weakness and, if excessive, call for rejection of the moulding
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LAMINATE DEFECTS
Fault Resin-rich and Glass-rich Areas Cause Generally with mat laminates, caused by over-rolling of the reinforcement after binder has dissolved Remedy Check operator is fully trained. No more rolling than is necessary to remove air should be carried out
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LAMINATE DEFECTS
DELAMINATED AREAS WITHIN BODY OF LAMINATE Internal delaminations are caused by the application of excessive local force, usually when the moulding is being removed from the mould, or by local contamination of the reinforcement. An internal delamination may also be detected by tapping the surface of the laminate with a coin. A delaminated area gives a dead sound whilst a perfect area gives a clear ringing sound
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LAMINATE DEFECTS
DELAMINATED AREAS WITHIN BODY OF LAMINATE
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LAMINATE DEFECTS
LAMINATE FAULTS AND CAUSES
Fault Cause Remedy
Check storage and handling of reinforcement. Cleanliness is essential. Localized contamination Occasionally chrome of reinforcement finishes are misapplied. This is shown by green patches on Delaminated Areas Reinforcement. Reject within Body of Laminate Inadequate wetting of glass. Brushes or rollers Caused by operator contaminated with water carelessness or solvent Use of excessive force Minor form of crazed in removing mould tool areas (below) Introduction to GRP and Hand Laid-up
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LAMINATE DEFECTS
LAMINATE FAULTS AND CAUSES
Resin-rich patches
Fault
Cause
Remedy
See Resin-rich Glass-rich Areas and
Crazed Areas
Treat mouldings with respect particularly Local impact damage. before post-cure. Use Excessive localized absolute minimum of force used in removing force when stripping moulding from mould mouldings. Check release agent application methods Loss of monomer by evaporation Gel-time too long
Check resin formulation. Air-inhibited resin Use resin not prone to system used Introduction to GRP and Hand Laid-up air inhibition GRP Moulding 151
LAMINATE DEFECTS
CRAZED AREA
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LAMINATE DEFECTS
INTERNAL DRY PATCHES (WHITE LAMINATES) White laminates are found when the resin fails to wet the surface of the reinforcement. As a result the pattern of the reinforcement may be clearly seen
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LAMINATE DEFECTS
INTERNAL DRY PATCHES (WHITE LAMINATES) This condition is caused by gross contamination of the reinforcement, by the use of a finish which is not compatible with the resin system, or by local exotherm. The result is an unacceptably weak and possibly porous laminate. Small areas may be considered for repair but large areas should always be rejected (Read NES for more details)
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LAMINATE DEFECTS
Fault Cause Remedy and
Attempting to impregnate more than See Resin-rich one layer of glass at a Glass-rich Areas time
Internal Dry Patches Use of insufficient resin. Inadequate consolidation Incorrect finish on glass
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LAMINATE DEFECTS
Fault Cause Workshop temperature too low Loss of styrene caused by draughts Remedy
Undercure
Presence of inhibitors Check materials e.g unsuitable pigments Incorrect resin formulation, e.g too Check resin formulation little catalyst or accelerator Introduction to GRP and Hand Laid-up
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THANK YOU
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EXTRA SLIDES
LINKS
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SPUN YARN
A yarn made by taking a group of short staple fibers, which have been cut from the longer continuous filament fibers, and then twisting these short staple fibers together to form a single yarn, which is then used for weaving or knitting fabrics
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CRIMP
When warp and weft (fill) yarns interlace in fabric they follow a wavy or corrugated path. Crimp percentage is a measure of this waviness in yarns. Percentage crimp is defined as the mean difference between the straightened thread length and the distance between the ends of the thread while in the cloth, expressed as a percentage. C=(l-p)/p*100% where, c = crimp, l = uncrimped length and p = crimped length Warp is the lengthwise or longitudinal thread in a roll, while weft is the transverse thread
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SATIN WEAVE
A weave in which each weft thread floats over as many as 12 warps and then under a single warp. The next weft passes over the same number of warps, but is woven in by different warps
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NOTCH TOUGHNESS
Notch toughness is the ability that a material possesses to absorb energy in the presence of a flaw A tough material will resist the initiation of a crack at points of stress concentration. Although, under certain abnormal conditions, the stress may rise locally to such levels that a crack is initiated, a tough material will better resist the propagation of the crack. The consideration of fracture mechanics principles may be necessary in some instances. Some examples of when notch toughness should be specified include:
dynamic or impact loading fatigue loading service temperatures below 25 degrees F.
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Abrasion
The process of wearing down or rubbing away by means of friction
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BUCKLING
In practice, buckling is characterized by a sudden failure of a structural member subjected to high compressive stress, where the actual compressive stress at the point of failure is less than the ultimate compressive stresses that the material is capable of withstanding.
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TOOTH PITCH
The distance between one tooth tip and the next
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Application of GelCoat
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Application of CSM
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Sheet Release
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MOULDING TOOLS
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GEL-COAT DEFECTS
SURFACE FIBRE PATTERN Causes
Gel-coat not cured sufficiently before commencing lay-up
Remedy
Ensure adequate cure of gel-coat Ensure gel-coat minimum thickness of 0.3mm
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GEL-COAT DEFECTS
STAR CRACKING Causes
Result of an over thick gel-coatoccurs when laminate has received a reverse impact
Remedy
Ensure gel-coat no thicker than 0.5mm
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GEL-COAT DEFECTS
CRAZING Causes
Gel-coat too thick Use a brittle resin or resin containing excess monomer
Excessive accelerator in formulation or curing temperature too high (Sometimes gives orange peel effect)
Remedy
Use even thickness gel-coat
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GEL-COAT DEFECTS
PIN HOLES IN GEL-COAT
Causes
Gel-coat not wetting release agent on mould Minute air bubbles in the surface of the laminate. Caused by poor mixing of filler into thixotropic gel-coat and/or overbrushing of gel-coat when applied to mould Occluded air in the filler used in resin formulation
Remedy
Use non-silicone wax on mould surface followed by a PVA release agent Mix resin by mechanical means. Apply resin carefully using minimum brushwork consistent with uniform resin coverage
Use only fillers which have been treated for use with polyester or epoxy resin as appropriate
Mould under clean conditions. Ensure that dust cannot fall on mould before application of gel-coat
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GEL-COAT DEFECTS
CRATERING AND BLISTERING Causes
Usually caused by air or solvent trapped between gel-coat and laminate proper. If reinforcement is carefully rolled down this defect should not occur
If parting agent not thoroughly dry, volatiles will cause lifting of gel-coat
Remedy
Check resin:glass ratio; a deficiency of resin often causes air bubbles. Check the grade of any glass mat used. If the binder is insoluble in the resin the fibre will not bed down. Ensure that parting agent is thoroughly dry before applying gel-coat
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GEL-COAT DEFECTS
WRINKLING OF SURFACE Causes
Too thin a gel-coat which is under cured. Often on vertical surfaces
Remedy
Prevent drainage of gel-coat by ensuring adequate amount of thixotropic agent in formulation Ensure that there are no draughts in vicinity of the moulding
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Distortion or Warping
Use a reinforced gel-coat Use thin gel-coat Use a specially formulated gel-coat resin Ensure gel-coat no thicker than 0.5mm
Star Cracking
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MOULDING OPERATION
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STEEL PATTERN
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GRP MOULD
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