Corrosion Control Certification

November 30, 2009

Introduction Corrosion & Corrosion Control Certification Program

USA

EU
Japan

Summary

ISO 9001

NACE CP Specialists (4) ECDA

( ) () ( )

1 (CIPS/DCVG survey equipments)

( )

( ) ( )

(CP-RRMS) (third party damage)

/ : CIPS/DCVG (ELSYCA) CP, electroplating, ECM

PRINCIPLES OF CORROSION & CORROSION CONTROL

Thermodynamically natural process

: M Mn+ + ne: O2 + 2H2O + 4e- 4OHAnode Cathode Electronic conductor Ionic Conductor (electrolyte) (+) Closed circuit

Corrosion in an extractive metallurgy in reverse.

2.0

1.5

Counts (Arb. Unit)

1.0

Fe

0.5

Fe C

Si Al

P Fe
2 4 6 8 10

0.0 0

Energy (keV)

SRB

$276 billion
is the annual

Cost of Corrosion in the USA

10

Utilities: Transportation: Infrastructures: Government: Production/Mfg.:

$47.9 billion-34% $29.7 billion-22% $22.6 billion-16% $20.1 billion-15% $17.6 billion-13%

TOTAL: $138 billion

11

Highway Bridges Gas and Liquid Transm. Pipelines Waterways and Ports Hazardous Materials Storage Airports Railroads Gas Distribution Drinking Water and Sewer Systems Electrical Utilities Telecommunication Motor Vehicles Ships Aircraft 1.00 Railroad Cars Hazardous Materials Transport Oil and Gas Expl.and Production Mining Petroleum Refining Chem., Petrochem., Pharm. Pulp and Paper Agricultural Food Processing Electronics Home Appliances Defense Nuclear Waste Storage $-

$8.3 $7.0 $0.3 $7.0 $$$5.0 $36.0 $6.9 $$23.4 $2.7 $2.2 $0.5 $0.9 $1.4 $0.1 $3.7 $1.7 $6.0 $1.1 $2.1 $$1.5 $20.0 $0.1 $10 $20 $30 $40

Protective Coatings: Corrosion Resistant Alloys: Cathodic and Anodic Protection: Engineering Plastics/Polymers: Corrosion Control Services: Corrosion Inhibitors:

$108.6 billion $7.7 billion $6.6 billion $1.8 billion $1.2 billion $1.1 billion

TOTAL: $121.4 bil.

13

Material selection, e.g., CS to CRA Coatings & linings (organic, inorganic) Cathodic & anodic protection Corrosion inhibitor Design Factors, etc.

If an active-passive alloy is maintained in the passive region with the potentiostat, its corrosion rate will reduced to ipass. This technique is based on the formation of protective film on metals by externally applied anodic currents.

An inhibitor is a chemical substance that, when added in small concentration to an environment, effectively decreases the corrosion rate. A minimum conc. of inhibitor must be present to maintain the inhibiting surface film. Thus, good circulation and the absence of any stagnant areas are necessary to maintain the required level of inhibitor concentration. An addition of inhibitors reduces icorr by increasing the Tafel slope and/or by reducing the exchange current density.
E E

Anodic inhibitor

log i

Cathodic inhibitor

log i

A. Adsorption-type inhibitors Organic compounds which adsorb on the metal surface and suppress metal dissolution and reduction reactions. Typical of this class of inhibitors are the organic amines.
B. Hydrogen evolution poisons The susbstances such as As, Sb, P, and S retard hydrogen recombination reaction, thereby reducing corrosion rate of a metal in acid solutions.

C. Scavengers These substances act by removing corrosive species from solution : Sodium sulfite : 2Na2SO3 + O2(sol.) 2Na2SO4 Hydrazine : N2H4 + O2 N2 + 2H2O
D. Oxidizers or passivators - effective only in metals showing active/passive transition. : CrO42- , NO2-, MoO42- , WO42- , and ferric salt

Coating + CP A steel pipe protected by an organic coating

An unprotected steel pipe buried in a corrosive soil

Corrosion Certification

()

() / //

NACE CP specialist

Provide qualification for specialized individuals Build confidence in the quality of services provides Encourage growth and updating knowledge Enhance professional development Provide a sense of achievements Exchange technical experiences

Corrosion Certification in Other Countries (USA, EU, Japan)

History Founded by a group of pipeliners in 1943, then expanded into other industries Since 1943 NACE has: Produced over 100 standards Developed numerous training and certification programs Grown to over 17,000 members worldwide www.nace.org

NACE Standards Education Programs Professional Recognition Coating Inspector Training Cathodic Protection Certification Annual Conference NACE Periodicals: Corrosion, MP. Books

Current NACE Training & Certification Programs

Generalist Certifications Corrosion Technician Corrosion Technologist Sr. Corrosion Technologist

Materials/Design Chemical Inhibition Cathodic Protection Coatings Technology

Corrosion Specialist Specialty Certifications

Coating Inspector Certification Cathodic Protection Specialist

Chemical Treatment Specialist

Material Selection/Design Specialist Protective Coatings Specialist Internal Corrosion Certification

29

Criteria
Based on references and experiences Plus
Open book examinations (traditional path) Participation to a certain number of selected NACE training courses (parallel path)

Recertification Intervals
CP 1 & Corrosion Technician = every 3 yrs
All others = every 5 years Based on work history

1.

12 years Cathodic Protection work experience including 4 years in responsible charge as documented in this application and 2 years post-high school training in Math or Science from approved Technical/Trade School (please complete information below and send via regular mail a copy of your certificate) PLUS CP Technician Certification or equivalent training as listed below (exam and course only) OR CP Specialist class or equivalent training as listed below (exam only) 6 years Cathodic Protection work experience including 4 years in responsible charge as documented on this application and a 4-year Physical Science or Engineering Degree (please complete information in space below and send via regular mail a copy of your degree) PLUS CP Technician Certification or equivalent training as listed below (exam and course only) OR CP Specialist class or equivalent training as listed below (exam only) 4 years Cathodic Protection work experience in responsible charge AND one of the following: - Bachelor's degree in Engineering or Physical Sciences and an advanced degree in Engineering or Physical Sciences that required a qualification exam - PE, P eng., or equivalent PLUS CP Technician Certification or equivalent training as listed below (exam and course only) OR CP Specialist class or equivalent training as listed below (exam only)

2.

3.

Revenues

Expenses

Coating Inspector Program It was developed to meet worldwide industry needs for a recognized needs for a recognized standard for coating inspectors training and for improved coating applications inspection.

More than 3,600 people worldwide are recognized at different levels of coating inspector training.

NACE CP is the leading training & certification tool for industry CP is a 4 level hands-on Program
Level 1 Tester Level 2 Technician Level 3 Technologist Level 4 Specialist

Corrosion 101 DVD (for DOD) Water Facilities Corrosion Control Training (for DOD) Marine CP 2 (for NAVSEA)

FROSIO, the Norwegian Professional Council for Education and Certification of Inspectors for Surface Treatment has been at the forefront of the field since it was established in 1986. About one thousand inspectors from over 40 different countries have been certified in accordance with NS 476 which is available in Norwegian and English language versions and has provided the basis for prEN 12837. Although FROSIO does not run its own training courses, the FROSIO Board has responsibility for the content of training courses, in accordance with NS 476. Two levels of inspector are appointed: inspector and assistant inspector. In the UK, the Institute of Corrosion has established a training centre in Sheffield with a structure based on the requirements of EN 45013. The requirements of the certification scheme are outlined in document ICorr Req 96: Requirements for the Certification of Personnel engaged in Painting and Coating Inspection. Certification is available for Painting Inspectors, Cathodic Protection Technicians, Pipeline Coatings Inspectors, Metallic Coatings Inspectors, and others, at up to three levels (Trainee, Assistant and Senior).

In France, ACQPA is concerned with the implementation of NF EN 45013, which deals with personnel, and NF EN 45011, which relates to paints and paint systems. It offers certificates for paint systems and for personnel involved in application and supervision, and for inspection personnel (using the FROSIO system under license). Also, CFPC, a financially autonomous branch of CEFRACOR, has been established to promote the certification of personnel in the field of cathodic protection and offers two levels of certification conforming with the AFNOR Standards NFA 05910, which deals with levels of competence, and NFA 05991, which covers certification of personnel in accordance with EN 45013. In Italy, APCE, the Italian Association for the Protection against Electrolytic Corrosion Underground has collaborated with CICPNP, a certification body for non-destructive testing personnel, to develop a certification body for personnel working in the cathodic protection field. http://www.efcweb.org/Structure/Working_Parties-p-104085/WP_7-p104100/Certification_of_personnel.html

Countries
Standards

France
NFA05-690 (Qualification) NFA06-691 CFPC ((CEFRACOR) mandated by AFNOR Recueil dexamen CFPC CP Expert CP Specialist CP Technician 4 (buried, marine, concrete, internals)

Italy
UNI 10875 (Qualification and Certification) CICPND

UK

Netherlands

USA

Certification Organizations Publications

Institute of Corrosion (Icorr) Icorr REQ DOC Requirements for the Certification of Personnel Prof. Grade of Fellow Prof. Grade of Member CP Technician 4 (buried, marine, concrete, internals)

GASTEC and KEMA

NACE

CICPND Code for Certification and Basic Required Knowledge CP Expert CP Engineer CP Operator 4 (buried, marine, concrete, internals)

Professional Recognition Program, CP Engineer CP Specialist CP Surveyor Buried structures only CP Specialist CP Technologist CP Technician/CPtester No sector

Level of Certifications

Application Sectors

Training

Not mandatory

Mandatory (32hr for level 1) (40 hr for level 2)

APCE Yes, except for level 3 on temporary basis Not published CICPND Agreed by CICPND (Italgas, ENI, Napoletana Gas, etc.) 5 yr

Mandatory (40hr) for Technician grade

Agreed universities or companies Yes for CP technicians GASTEC Yes

Not mandatory (except for parallel path)

NACE International Open book exam (except for parallel path) Not published NACE Agreed by NACE

Training centers Examinations

Open (USITV/CJP/AFPI) Yes, except for level 3 on temporary basis Published CFPC Agreed by CFPC (GDF for buried structure) 5 yr

Questions Organization of examinations Examination Centers

Not published ICorr Agrred by Icorr

Not published GASTEC GASTEC

Validity periods

5 yr

5 yr

5 yr

Rhode Islands UST program, USA

RI Department of Environmental Management
Internal inspection must be performed or certified by NACE corrosion expert

OHSA Safety Inspection

Certified Inspector NACE

IMO (Int. Maritime Org.) PSPC ballast tank regulations

NACE coating inspector level 2

Highways Agency in the UK

Mandating certification for qualified inspectors and applicators for protective

coatings (paint) on highway structures via the U.K. Institute of Corrosion.

1959 , http://www1.sphere.ne.jp/jacc/ () -
1961 , 2009 49 1 (199,000) ()
8-12% , 1

()
, , (,), ,

12,000

NACE International European Federation of Corrosion Japan Worldwide harmonization in corrosion education, in certification, and also in corrosion-related standards is needed? Certification system in Korea?

1. 2.

3.

4. 5. 6.

C. Johnson, NACE International Standards & DoD Corrosion Prevention/Control Effort, Mar 2005. D. Supriyatman, The Role of Professional Associations in Improving Maintenance & Production Reliability: A Perspective from Corrosion Mitigation through NACE Trainings, Apr 2008. Corrosion Cost and Preventive Strategies in the United States, Report by CC Technologies Laboratories, Inc. to Federal Highway Administration (FHWA), Office of Infrastructure Research and Development, Report FHWA-RD-01-156, Sep 2001. L.L. Shreir, Corrosion, Vol. I and Vol. II, Newnes-Butterworths Co., 2nd ed., 1976. D.A. Jones, Principles and Prevention of Corrosion, Prentice Hall, 2nd ed., 1996. NACE International Professional Recognition Program

: () 1991, 1994 , 2002

1996.1. 2006.4. 2006.4.

()

() (NACE International) (ACS)

NACE Accredited Cathodic Protection (CP) Specialist (2010)

E-mail: syli@correltech.com; yubbie36@paran.com Skype ID: seonyeob.li 010-3201-7499

Internationally, 1 ton of steel turns into rust every 90 seconds. The energy required to make 1 ton of steel is approximately equal to the energy that an average family consumes over three months.

Of every ton of steel from the worlds production, approximately 50% is required to replace rusted steel.
Source: Zinc Today, Newsletter of the American Zinc Association (Spring 1997)

Technology de-oxygenation light source cavitation + de-oxygenation + electro disinfection hydroclonic filtration + biodegradeable chem ozone injection + electrolysis split pipe + ozone electro-disinfection electrolysis of s/water

Action physical physical

Approval process G8 G9

IMO Basic not req yes

IMO Final
not req yes expect end 08 imminent no info no info no info

Type Approval yes

Coating tests yes no

expect mid 08
pending

physical physical + chem physical physical physical + chem physical

G9

yes

yes ?

G9 G9 G9 G9 no info

yes Yes yes yes

pending

yes no info no info no info