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Preparation:
CAS & EINECS are identifications codes Risk phrases (from CHIP data- see later)
Alcohol Ethoxylate <1% Phosphoric acid 15 30% Benzotriazole <1% Formaldehyde <1%
Hazards identified (i.e. those known about when the product is used in the way the manufacturer intends)
Irritating to eye and skin Large amounts could be hazardous to aquatic environment
Always check out first aid information with your Departmental First Aider or Safety Services
Fire fighting measures The material is non-flammable If involved in a fire anyway, it may produce hydrogen chloride (an acid gas) Breathing apparatus is relevant to the Fire Service not us!
Measures for spillage or accidental release Spillage contain with sand or earth Beware of slipping hazard Do not allow to go down the drains (report
any significant leakage down the drains to the water authorities take advice)
You will need to ensure that your department stocks appropriate materials to deal with these incidents.
In this case, largely common sense information but for some products it could be more critical
NB It does not tell you what sort of gloves are appropriate. You would need to find this out by consulting a gloves manufacturer regarding the hazardous materials in the product see the Guidance section of Safety Services website
In terms of hazard, both high pHs (strong alkali) and low pHs (strong acid) are nasty. For substances with pHs around 7 acidity & alkalinity are not generally a problem.
Irritating to organic tissue (skin & eyes) Inhalation of aerosol may cause irritation Ingestion irritation to mouth & digestive tract
(its a strong acid) again!)
Eye contact may cause severe irritation (acid Skin contact irritation! Connected with first aid information here, but in some circumstances, may give details of longer term medical problems, where appropriate
Biodegrades does not remain in soil etc Dont release into surface waters
eg detergents can cause unsightly rivers and may affect waterproofing of water birds
Disposal considerations
Use suitable PPE (see previous information) Rinse out containers Dont allow to enter drains Dispose of according to local regulations Do not mix with other waste
This is not as formidable as it sounds a bit of advice from Safety Services or Estates will help
Transport information
None
Where substances need special consideration for transport, it will be detailed here usually only applicable to larger quantities
Regulatory information
Irritant to eyes and skin Keep away from children First aid information
These are risk phrases associated with the CHIP regulations simple advice phrases There may also be symbols as here , indicating irritant.
R1: Explosive when dry R2: Risk of explosion by shock, friction, fire or other sources of ignition R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition R4: Forms very sensitive explosive metallic compounds R5: Heating may cause an explosion R6: Explosive with or without contact with air R7: May cause fire R8: Contact with combustible material may cause fire R9: Explosive when mixed with combustible material R10: Flammable R11: Highly flammable R12: Extremely flammable R14: Reacts violently with water R15: Contact with water liberates extremely flammable gases
R20: Harmful by inhalation R21: Harmful in contact with skin R22: Harmful if swallowed R23: Toxic by inhalation R24: Toxic in contact with skin R25: Toxic if swallowed R26: Very toxic by inhalation R27: Very toxic in contact with skin R28: Very toxic if swallowed R29: Contact with water liberates toxic gas. R30: Can become highly flammable in use R31: Contact with acids liberates toxic gas R32: Contact with acids liberates very toxic gas Up to: R66: Repeated exposure may cause skin dryness or cracking R67: Vapours may cause drowsiness and dizziness R68: Possible risk of irreversible effects
Other information (variable) In this case it tells you its immediate application and how to use it
REMEMBER
MSDSs are NOT Risk Assessments! They make no distinction between a gram and a tonne of a substance. When using substances you must carry out a risk assessment but use the information in MDSDs to help you. Controls should be proportional to risk! Not all MSDSs contain comprehensive. information, although they should have! If in doubt, always consult an expert.