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Course Information
Credit Hours: 3
Contact Hours:
Lecture (2hrs/week)
Tutorial (1hr/week)
Practical (2 hrs/week)
Assessment
Comprehensive Final Examination 50%
Tests (3 Tests) 30%
Quizzes & Assignments 10 %
Weekly Practical Report 10 %
COURSE CONTENT
1. Units of Measurement
2. Elements, Compounds, Chemical Equations
and Calculations
3. Concepts of Acid-Base Neutralization
4. Structure of an Atom
5. Periodic Table
6. Chemical Bonds
7. Oxidation and Reduction Reactions (Redox)
8. Introduction to Organic Chemistry
CHAPTER 1
UNITS OF
MEASUREMENTS
S.I Units
Significant figures
Scientific notation
Dimensional analysis
Conversion of S.I units
CHEMISTRY
Chemistry is the study of matter and
the changes it undergoes.
Either macroscopic or microscopic
(atomic or molecular) approach.
Macroscopic
Microscopic
CHANGES in CHEMISTRY
A physical change does not alter the
composition or identity of a substance.
Examples are ice melting and sugar
dissolving.
A chemical change alters the composition
or identity of the substance(s) involved.
Examples hydrogen burns in air to form
water.
hydrogen burns in air to
form water
MEASUREMENTS
Measurements of the macroscopic properties can be
determined directly.
Pipette, burette, measuring cylinder to measures the
volume
Thermometer measures the temperature
Balance measures the mass
Stop watch measures the time
Measurements of the microscopic properties must be
determined by indirect method.
Mass spectrometer measure the molecular or atomic
mass
Spectrophotometer measure the energy, frequency,
wavelength, due to excitation, vibration, rotation or
stretching of the molecules
SI UNITS
Quantity
SI to English Equivalent
English to SI Equivalent
Length
1 km = 0.6214 mile
1 m = 1.094 yard
1 m = 39.37 inches
1 cm = 0.3937 inch
1 mi = 1.609 km
1 yd = 0.9144 m
1 ft = 0.3048 m
1 in = 2.54 cm
Volume
1 ft3 = 0.02832 m3
1 gal = 3.785 dm3
1 qt = 0.9464 dm3
1 qt = 946.4 cm3
1 fluid ounce = 29.57 cm3
Mass
1 kg = 2.205 lb
1 g = 0.03527 ounce (oz)
1 lb = 0.4536 kg
1 oz = 28.35 g
Length
Memorise this!
weight = c x mass
on earth, c = 1.0
1 kg on earth
on moon, c ~ 0.1
0.1 kg on moon
Volume
S.I derived unit for
volume is cubic meter
3
(m
)
3
1 cm = (1 x 10-2 m)3 = 1 x 10-6 m3
1 dm3 = (1 x 10-1 m)3 = 1 x 10-3 m3
1 L = 1000 mL = 1000 cm3 = 1 dm3
1 mL = 1 cm3
Density
Density S.I derived unit for density is
kg/m3
3
1 g/cm3 = 1 g/mL
=
1000
kg/m
m
mass
density = volume d = V
Temperatures
Kelvin ( K )
The Absolute temperature scale begins
at absolute zero and only has positive
values.
Celsius ( oC )
The temperature scale used by science,
formally called centigrade, most
commonly used scale around the world.
Water freezes at 0oC and boils at 100oC.
Fahrenheit ( oF )
Commonly used scale in the U.S. for
o
Temperatures
K = C + 273.15 F =
0
273.15 K = 0 0C
373.15 K = 100 0C
9 x 0C + 32
5
32 0F = 0 0C
212 0F = 100 0C
16
5 x (0F 32) = 0C
9
0
C = 5 x (0F 32)
9
0
C=5
x (172.9 32) = 78.3 0C
9
Scientific Notation
The number of atoms in 12 g of
carbon:
602,200,000,000,000,000,000,000
6.022 x 1023
The mass of a single carbon atom in
grams:
0.0000000000000000000000199
1.99 x 10-23
N x 10n
N is a number
between 1 and 10
n is a positive or
negative integer
Scientific Notation
568.762
0.00000772
n>0
n<0
568.762 = 5.68762 x 102 0.00000772 = 7.72 x 10-6
Addition or Subtraction
1. Write each quantity
with the same
exponent n
2. Combine N1 and N2
3. The exponent, n,
remains the same
Scientific Notation
Multiplication
5.0
x
10
1. Divide N1 and N2
4-9
=
(8.5
5.0)
x
10
2. Subtract exponents n1 and n2
= 1.7 x 10-5
Significant Figures
1 significant figure
3 significant figures
4 significant figures
2 significant figures
3 significant figures
2 significant figures
3001 g
4 significant figures
0.0320 m3
3 significant figures
2 significant figures
560 kg
3 significant figures
Significant Figures
Addition or Subtraction
The answer cannot more digits to the right of the decimal
point than any of the original numbers.
89.332
+1.1
90.432
3.70
-2.9133
0.7867
1 decimal point
round off to 90.4
1 decimal point
2 decimal point
round off to 0.79
2 decimal point
Significant Figures
Multiplication or Division
The number of significant figures in the result is set
by the original number that has the smallest number
of significant figures.
4.51 x 3.6666 = 16.536366 = 16.5
3 sig figs
Significant Figures
Exact Numbers
Numbers from definitions or numbers of
objects are considered to have an infinite
number of significant figures
The average of three measured lengths; 6.64, 6.68
and 6.70?
6.64 + 6.68 + 6.70
= 6.67333 = 6.67 = 7
3
Because 3 is an exact number
accurate
&
precise
precise
but
not accurate
not accurate
&
not precise
Dimensional Analysis
Method of Solving Problems
1. Determine which unit conversion factor(s) are needed
2. Carry units through calculation
3. If all units cancel except for the desired unit(s), then
the problem was solved correctly.
given quantity x conversion factor = desired quantity
given unit x
desired unit
given unit
= desired unit
Dimensional Analysis
Method of Solving Problems
How many mL are in 1.63 L?
Conversion Unit 1 L = 1000 mL
1000 mL
1.63 L x
= 1630 mL
1L
2
1L
L
1.63 L x
= 0.001630
1000 mL
mL
conversion units
meters to miles
seconds to hours
60 min
mi
x
= 767
hour
1 hour