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CELL
ASTI AWALIA (05)
INTANI MUNDIARTASARI (09)
RIZKY RIANZA (20)
1.Definition
An electrolytic cell is an electrochemical
cell that uses electric energy in order to
undergo chemical reaction. In electrolytic
cell, positive terminal is a place of
oxidation process, so its called anode.
Meanwhile negative terminal is a place of
reduction process, so its called cathode.
Electrolytic cell is opposite of voltaic cell.
2. Work Principle
The work principle of electrolytic cell is
electron (electric) come into solution
through negative terminal (anode).
Certain specie in solution absorb electron
from cathode and undergo reduction.
Other specie released electron in anode
and undergo oxidation. Those situations
will influence to redox reaction process
which happen, those are:
electrode materials
ions round about electrode
matter or ion round about non active
electrode
sum of ion in solution
3. Electrolytic Reactions
Electrolytic reaction in electrolyte solution
happened more complex. Specie which
reacted not only cat ion and anion, but aslo
the water or the electrode. Those are
depend
on the potential specie in the
solution. To write the electrolytic electrolyte
solution, factors that must be attend are :
1. The reactions which competitive in each
electrode.
a) Specie which undergo reduction in cathode is
specie which has positiver potential reduction.
b) Specie which undergo oxidation in anode is
specie which has negativer potential reduction,
or the positiver potential reduction.
L( s ) Lx ( aq ) xe
2. Reactions which happened in cathode
Metal ion
Alkali metal ion, earth alkali, Al3+, and
metal ion with Eo<-0.83 volt is not reduced,
but which reduced is water (solvent).
2 H 2 O( l ) 2e H 2 ( g ) 2OH ( aq )
( aq )
xe L( s )
2 H ( aq ) 2e H 2 ( g )
If used solid (without water), so that metal cation
is reduced
x
(l )
xe L( s )
1) Faradays Law
I The amount of matter which
resulted from
electrolytic reaction compared with amount of
electric current which flew into solution. This
situation can be drawn with Faradays Law I :
The quantity of substance produced at electrode is
equal to the quantity of electricity passing through
the electrolysis.
The formula :
ei t
W
F
W eF
Ar
e
n
W
= the quantity of the product
substances (g)
e
= equivalent weight
F
= faradays constant (F)
i
= electricity (A)
t
= time of reaction (second)
1 faraday = 1 electron = 96,500
2) Faradays Law II
If the same quantities of electricity are passed
through several electrolytic cells, the product
substances resulted by each cell equals to the
equivalent weight and does not depend on the kind of
substances involved in the electrolysis.
The formula :
Wn
W1 W2
....
e1
e2
en
Where :
W
= the quantity of the product
substances (g)
e
= equivalent weight
F
= electricity (F)
i
= electricity (A)
t
= time of reaction (second)
Mr
e
Electron that involved
EXAMPLE
1.Find the electrolytic result from the
melted of MgCl2 with Pt electrode !
Answer :
Cathode : Mg2+(l) + 2eAnode
: 2Cl- (l)
Mg(s)
+
Mg(s) +Cl2
: Cu2+(aq) + 2eCu(s)
: 2Cl-(aq)
Cl2(g) + 2e+
Cu2+(aq) + 2Cl-(aq)
Cu(s) + Cl2(g)
Answer :
AgNO3(aq)
Ag+(aq) + NO3-(aq)
Cathode
: Ag+(aq)+eAg(s)
Anode : 2H2O(l)
4H+(aq)+O2(g)+4e+
4Ag+(aq)+2H2O(l)
4
1
Ag(s)+4H+(aq)+O2(g)
e = 108 = 108
1
F = 11,930 = 0.02 faraday
96,500
EXERCISES
THANK YOU
FOR YOUR
ATTENTION