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LEARNING OUTCOMES :
Students should be able to;
explain the redox processes and cell
At cathode
RED CAT
2eAka: reduction at cathode
- Eg : Cu2+ + 2eCu
- Oxidation no increase
At anode
- Eg:Mg
Mg 2++
Cu(s)
Half cells
Zn 2+ (aq) + 2e -
Cu 2+(aq) + Zn(s)
(aq)
Cu(s) + Zn 2+
[ox] : C 2 H 5 OH
CH 3 CHO + 2H + + 2e-
Mn2+ + 4H 2 O
5C 2 H 5 OH
5 x [ox] + 2 x [ R ]
6
5 C 2 H 5 OH + 2MnO 4- + 16H+ + 10e5 C H 3 CHO + 10H+ + 10e- + 2Mn2+ + 8H2O
Cancel H + and e- on both side of equation
lost of H (Ox)
5 C 2 H 5 OH + 2MnO 4- + 6H+
5 C H 3 CHO + 2Mn2+ +
8H2O
lost of O (R )
Cr 3+
11) Fe 2+
Fe 3+
2) Balance element except O and H
Coefficient
i. Balance O with H 2 O(in the other
side)
ii. Balance H with H + (in the other side)
Cr 2 O 7 22Cr 3+ + 7H 2O
2Cr 3+ + 7H
Cl 2 + Cr 3+
Cl - + Cr O 4 2-
2Cr O 4 2- + 16H+ + 6 Cl +
8
16H 2 O
3Cl 2 + 2Cr 3++ 16OH
i) 3Cl 2 + 6eii) 2Cr 3++ 8H2O
2Cr O 4 2- + 6 Cl + 8H2O
6 Cl (R )
2Cr O 4 2- + 16H+ + 6e- (Ox)
Eg 2 : HNO 3 + I 2
answer: 10HNO 3 + I 2
+ 4H 2 O
HIO3 + NO 2
10NO 2 + 2HIO3
Solution:
i)
HNO3
ii)
I2
NO 2
HIO3
Cu
electrode
ZnSO4(aq)
Porous pot
Zn electrode
CuSO4(aq)
CuSO4
salt bridge
ZnSO4
porous pot
Function:
Maintains electrical neutrality
Completes the circuit by allowing ions carrying
charge to move from one cell to the other
Zn(s) + Cu 2+ (aq)
Cu(s)
Zn 2+(aq) +
pdt
rxt
pdt
Eg:
Given;
anode : Mg(s)
Mg2+(aq) + 2ecathode : Ag+(aq) + eAg (s)
1)Write cell notation
2)Write the overall cell rx
Solution
1)Mg(s) / Mg2+(aq) // Ag+(aq) / Ag (s)
2)Mg(s) + 2 Ag+(aq)
Mg2+(aq) +
2Ag (s)
(ox) = Mg(s)
(Rd ) = (Ag+ + e= 2Ag + 2e-
Mg2+(aq) + 2eAg )2
2Ag
measured by a
voltmeter
as
Solution:
E cell = E cathode E anode
E
cell
cell equation :
anode = Zn(s)
Zn2+(aq) + 2e-
(reverse) [Ox]
cathode = Cu2+(aq) + 2e-
1) Fe2+
Ox
2) Ag++ eOIL RIG
Ox is loss of e-
Fe3+ + e-
Ag
Red
red
is
gain of e-
Therefore;
+ve electrode = Ag (cathode),
-ve electrode = Pt in solution Fe2+ , Fe3+
(anode)
:. e- flow from Pt in Fe2+ , Fe3+ to Ag in the
external circuit.
ii) Pt(s) / Fe2+(aq), Fe3+ (aq) // Ag+(aq) /Ag(s)
Eg 4:
A cell is constructed by putting a
Pt electrode in a solution
containing Fe2+ and Fe3+ ions. It is
then connected by means of a
porous pot to another cell
containing a Pt electrode in a
solution of Mn2+, MnO 4- and H+ ions.
Volume of solution are 1.0 M and at
a T of 25C.
porous pot
Mn2+ ,MnO4- ,H+
Pt
Fe2+ , Fe3+
MnO4- ,
H+ ions
-Ve = Pt in solution of Fe2+ , Fe3+
b) E = Ecathode Eanode
Mn2+ +
Fe3+ + e-
LEARNING OUTCOMES :
Students should be able to;
predict the stability of aqueous ions from
E values;
predict the power of oxidising and
reducing agents from E values;
predict the feasibility of a reaction from
Ecell value and from the combination of
various electrode potentials: spontaneous
and nonspontaneous electrode reactions.
Co2+ + 2e- Co
Ni2+ + 2e- Ni
Sn2+ + 2e- Sn
Pb2+ + 2e- Pb
Fe3+ + 3e- Fe
2H+ + 2e- H2 (g)
S + 2H+ + 2e- H2S (g)
Sn4+ + 2e- Sn2+
Cu2+ + e- Cu+
-0.28
-0.25
-0.14
-0.13
-0.04
0.00
+0.14
+0.15
+0.16
+0.17
Cu2+ + 2e- Cu
2H2O + O2 + 4e- 4OH-
+0.34
+0.40
Solution:
Sps on the left side of red rx = ox
agents
Sps on right hand side of red rx =
red agents
Most +ve E0 value, most powerful ox
agent and most ve, least powerful.
1)[Ox] agents: Zn2+ < I2 < Fe3+<
VO2< MnO4
2)[Rd] agents :
< Zn
E values :
c) Feasibility of a Reaction
SPONTANEOUS AND NONSPONTANEOUS RXS:
1)DEF: Spontaneous Rx = a process that
occur by itself outside influence or an
external energy.
NON-spontaneous rx = a rx that must be
driven by an external source of energy.
Most rxs occur non-spontaneosly
+ Cl2
c)2Cu +
Cu 2+ +Cu
Solution:
S1: identify which sps undergo [Ox] and Rd from the
Rx en
S2: substitute E of each sps in the formula (C I A) to
calculate E cell
S3: determine whether value of E cell +ve or ve
a)Zn
Zn2+ +2e- (Ox) Anode E = -0.76 V
Cu2+ + 2eCu (Rd) Cathode E = +0.34 V
E cell = +0.34 (-0.76) = +1.10V
* Rx is feasible => occur spontaneously !
cell
= +1.23 (+1.36)
= -0.13 v
c) Cu + + eCu E=
+0.52v(Rd@cat)
Cu +
Cu 2++ e- E=
+0.15v(Ox@anode)
E cell = +0.52-(+0.15)
= +0.37v
* Rx is feasible, will occur
spontaneously
redox rx :
3Ag(s) + Al3+(aq) 3Ag+(aq) +
Al(s)
E0cell = -2.46 V
:. Rx not feasible
LEARNING OUTCOMES :
Students should be able to;
calculate the non-standard cell
potential, Ecell, of a cell using the
Nernst equation.
describe the importance of the
development of more efficient
batteries for electric cars in terms of
smaller size, lower mass and higher
voltage, as exemplified by hydrogenoxygen fuel cell.
Nernst Equation
To calculate cell potential (E
)from
cell
cell
=E
cell
0.059
z
Where :
E
E
cell
[Products ions]c
log
[Reactants ions]a
= electrode potential
cell
z = no of moles of etransferred
Eg. 1 :
The case of a Daniell cell:
Cu2+(aq) + Zn(s) Cu(s) + Zn2+(aq)
with cell diagram ;
Zn(s) / Zn2+(1.8M) // Cu2+(0.5M) / Cu(s)
What is the emf of the cell above?
Solutn :
1)
Eg. 3 :
A cell with rxs :
VO2+ + 2H+ + e- VO2+ + H2O E0 =
+1.00V
Zn2+ + 2e- Zn
E0 =
-0.76V
is set up where T = 250C,
[VO2+] = 2.0M, [H+] = 0.50M,
[VO2+] = 1.0x10-2M, [Zn2+] = 1.0x10-1M
Calculate the cell potential.
Solutn :
Ox : Zn Zn2+ + 2eRd : 2VO2+ + 4H+ + 2e-
2VO2+ + 2H2O
2)
Zn(s)/Zn2+(0.024M)//Zn2+(2.4M)/Zn(
s)
Answers :
1) +0.618 V
2) +0.059 V
Electric cars
The ideal battery :
i) Compact
ii) Lightweight
iii) High voltage
iv) Cheap
v) Long driving range
vi) Quick recharge
vii)Endurance
Advantage : no emission of
pollutants
Disadvantage : time consuming to
recharge the batteries