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Raoults Law
= 0.660 mol
= 6.559 mol
from
Appendix B
Find Xwater:
60 mL water x 0.997 g x 1 mol
mL
18.015 g
40 mL alcohol x 0.786 g x 1 mol
mL 46.07 g
Xwater = 3.321
3.321+0.682
= 0.8296
= 3.321 mol
= 0.682 mol
= 0.170
Tb = Kbm
The molality of solute particles in our sugar solution is
the same as the molality of the sugar itself.
m = mol sugar = 0.660 mol sugar
kg water
0.11815 kg water
Tb = (0.51C/m) (5.586m)
= 5.586 m
2.8C = 2.8C
Tb = Tbp(solution) - Tbp(pure=solvent)
Tbp(solution) = 100.00C + 2.8C = 102.8C
= 11.18 m
= 5.7C
note the
difference!!
Tf = Kfm
m = mol sugar = 0.660 mol sugar = 5.586 m
kg water
0.11815 kg water
Tf = (1.86C/m) (5.586m) = 10.4C
Tf = Tfp(pure solvent) - Tfp(solution) = 10.4C
Tfp(solution) = 0.00C 10.4C = -10.4C
Tf = Kfm
m = mol ions = 1.32 mol ions
= 11.17 m
kg water 0.11815 kg water
Tf = (1.86C/m) (11.17m) = 20.8C
Tf = Tfp(pure solvent) - Tfp(solution) = 20.8C
Tfp(solution) = 0.00C 20.8C = - 20.8C
If we had used CaCl2, Tfp(solution) would be even
lower. Thats why CaCl2 is sometimes used to salt
icy sidewalks.
= Kbm or Tf = Kfm
= 0.0976 m
Tf = Kfm
Tf = 29.8C (0.0976 m) = 2.908C
m
Osmotic Pressure
The last colligative property we
will study is osmotic pressure.
It is based on the tendency of
solvent molecules to move
toward an area of lesser
concentration.
This movement causes osmotic
pressure when the areas of
differing solvent concentration
are separated by a
semipermeable membrane.
Osmotic Pressure
Osmotic pressure is
the pressure that
must be applied to
the solution in order
to just stop the
movement of solvent
molecules into the
solution.
Osmotic Pressure
The equation relating
osmotic pressure () to
concentration is very
similar to the ideal gas
law
= MRT
M = molarity particles in
the solution
R = gas constant
T = temperature in K
Hypertonic Solutions
Osmotic pressure plays an important role in living
systems. For example, the membranes of red blood
cells are semipermeable.
When we eat too
much salt, the high
concentration of
salt in our plasma
makes it
hypertonic relative
to the inside of the
red blood cell and
causes water to
diffuse out of the
red blood cells.
Hypotonic Solutions
When we perspire
heavily and then
drink a lot of water
(not gatorade), the
low concentration
of salt in our
plasma makes it
hypotonic relative
to the inside of the
red blood cell and
causes water to
diffuse into the red
blood cells.
Isotonic Solutions
When we lose a lot of fluids and have to replace them,
the ideal situation is to receive fluids that are neither
hypertonic nor hypotonic. Fluids that have the same
osmotic pressure are said to be isotonic.
The osmotic pressure of blood is 7.7 atm at 37C. What
concentration of saline solution (NaCl in sterile water) is
isotonic with blood at human body temperature?
Using M = /RT,
M = molarity of solute particles =
7.7 atm
0.08206 L-atm (310. K)
mol-K
. = 0.30 M