Professional Documents
Culture Documents
Atomization
- It is the conversion of molecules to their component atoms
in gaseous state
In Flame Emission
-Atoms in gaseous state in the flame absorb thermal energy
from the flame itself, some of the atoms get excited & as they
return back to the ground state they emit radiation having energy
equal to that absorbed.
-The emission is proportional to the number of excited atoms,
which is proportional to the total number of atoms in the flame
i.e. the sample concentration
Flame Spectra
The spectra of gaseous, atomic particles consist of well defined
narrow discrete.
The resonance wave - length (at which the most intense absorption
and emission occur) is : 671 nm for lithium, 589 nm for sodium
and 767 nm for potassium.
1-Flame atomizer.
2- Monochromator
3- Detector.
4- Readout meter.
1-Flame Atomizer
a-Atomization of the sample.
b- Source of thermal energy to excite the atoms.
The atomizer is composed of :
Nebulizer:
is a device by which sample solution is divided into very fine
droplets which are aspirated into fine spray or aerosol.
As the oxidant flows it withdraws the sample from the capillary
in
very fine droplets
Then mixed in the premixing chamber with the fuel gas .
In the burner
The combustion of fuel occurs producing the necessary heat for atomization
and excitation but not ionization .
2- Monochromator
2- Chopper
5- Detector
3- Atomizer
6- Read out meter
2-The chopper
its function is to fluctuate the source output.
It is a circular disc divided into four quarters two are mirrored and two are opened.
3- Atomizer:
- No flame noise.
4- Monochromator:
Grating to eliminate other resonance lines from the source
or other radiation from the flame or sample