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WATER TREATMENT
PROCESSES
Process
Driving
force
Ion Exchange (IX)
Electrodialysis (ED)
Chemical
Electrical
Pressure
Distillation (MSF)
Thermal
2
WATER TREATMENT
PROCESSES
Process
Feed TDS
Product TDS
mg/I max.
mg/I
IX
1500
<1
ED
3000
RO
40,000
MSF
70,000
5-10
ION EXCHANGE
The feedwater to an ion exchange system
must meet the following specifications
Suspended solids
Nil
Turbidity
<5
NTU
Heavy metals
<0.05
mg/l
Organic matter
low
Fouling index
<0.05
Oil
Absent
Free chlorine
Nil
4
Function
Softening
Dealkalization
Removes hardness
Reduces alkalinity
Demineralization
Reduces TDS
SOFTENING
Service stage is represented by the following
reactions
Ca(HCO3)2(l)
2 NaR(s)
CaR2(s)
2NaHCO3(l)
MgCI2(l)
2 NaR(s)
MgR2(s)
2NaCl
Exhausted
Resin
Soft
Water
(l)
Hard
Water
Regenerated
Resin
SOFTENING
The regeneration stage is represented by the
following reactions
CaR2(s)
CaCl2(l)
2 NaC1(l)
2NaR(s)
MgR2(s)
MgCl2(l)
2 NaCl (l)
2NaR(s)
Exhausted
Waste
resin
effluent
Regenerant
Regenerated
(Common Salt)
resin
7
DEALKALIZATION
The dealkalization processes are
Split stream dealkalization
Dealkalization with a weak acid
cation (WAC) resin.
Combination of WAC and softener
8
SPLIT STREAM
DEALKALIZATION
SPLIT STREAM
DEALKALIZATION
Reactions during service
a) Softener
Ca(HCO3)2(l)
2 NaR(s)
CaR2(s)
2NaHCO3(l)
MgCI2(l)
2 NaR(s)
MgR2(s)
2NaCl
(l)
Hard
water
Regenerated
resin
Exhausted
resin
Soft
water
10
SPLIT STREAM
DEALKALIZATION
Reaction
during service
b) HI Unit
Ca(HCO3)2(l)
H2CO3(l)
Temporary
Carbonic
hardness
MgCl2(l)
2HR(s)
CaR2(s)
Regenerated
resin
+
2HR(s)
Exhausted
resin
MgR2(s)
acid
2 HCl
(l)
Permanent
Free
hardness
mineral acid
Na2SO4(l)
Regenerated
Exhausted
resin
resin
2HR(s)
2NaR(s)
+11
SPLIT STREAM
DEALKALIZATION
Reaction during service
c) Blend
NaHCO3(l)
2NaHCO3(l)
HCl (l)
+
NaCl (l)
H2SO4(l)
H2CO3(l)
Na2SO4(l)
2H2CO3(l)
Alkalinity
Free
mineral acid
Neutral
salt
Carbonic
acid
H2O(l)
CO2 (g)
12
SPLIT STREAM
DEALKALIZATION
Reactions during regeneration
a) Softener
CaR2(s)
2NaCl (l)
2NaR(s)
2NaR(s)
CaCl2(l)
MgR2(s)
2NaCl (l)
MgCl2(l)
Exhausted
resin
effluent
Sodium
chloride
Regenerated
resin
Waste
b) HI Unit
CaR2(s)
CaCl2(l)
2HCl (l)
2HR(s)
MgR2(s)
2HCl (l)
2HR(s)
13
DEALKALIZATION WITH A
WEAK ACID CATION (WAC)
RESIN
Reactions
a)
Service
Ca(HCO3)2(l)
2HR(s)
CaR2(s)
2HR(s)
MgR2(s)
HR(s)
NaR(s)
2H2CO3(l)
Mg(HCO3)2(1)
2H2CO3(I)
NaHCO3(1)
Alkaline
Carbonic
Regenerated
H2CO3(I)
Exhausted
14
2HCl (l)
2HR (s)
2HCl (l)
2HR (s)
HCl (l)
HR (s)
Hydrochloric
Regenerated 15
CaCl2(l)
MgR2(s)
MgCl2(l)
NaR (s)
NaCl (l)
Exhausted
COMBINATION OF WAC
AND SOFTENER
The WAC resin reacts with alkaline salts
only and not with neutral salts in water.
The combination of WAC and Softener is
used therefore when permanent hardness is
present in water.
The WAC efficiently removes the temporary
hardness and the downstream Softener
exchanges the permanent hardness.
16
DEMINERALIZATION
There are two basic processes
Two bed
Mixed bed (MB)
But there are several extensions and
combinations of these basic processes
which progressively improve the quality of
water and the efficiency of the processes.
17
...DEMINERALIZATION
The reactions during service of the strong acid cation
(SAC) exchanger are as follows
Ca(HCO3)2(l)
H2CO3(l)
Temporary
Carbonic
hardness
MgCl2(l)
2HR(s)
CaR2(s)
Regenerated
resin
+
2HR(s)
Exhausted
resin
MgR2(s)
acid
2 HCl
(l)
Permanent
Regenerated
Exhausted
Free
hardness
resin
resin
mineral acid
Carbonic acid is unstable and dissociates to carbon dioxide.
Na2SO4(l)
+ 2HR(s)
2NaR(s) +
H2CO3(l)
H2O(l)
+
CO2 (g)
H2SO4(l)
18
...DEMINERALIZATION
The reactions during service of the strong base
anion (SBA) exchanger are as follows
H2SO4(l)
2ROH(s)
R2SO4(s)
2H2O(l)
HCl(l)
ROH (s)
RCl(S)
H2O(l)
Free
Regenerated
mineral acid resin
CO2(l)
Carbon
dioxide
SiO2(l)
Cation
slip
ROH(s)
Demineralised
water
RHCO3(s)
Regenerated
resin
Silica
NaCl(l)
Exhausted
resin
Exhausted
resin
ROH(s)
RHSiO3(s)
Regenerated
resin
Exhausted
resin
ROH(s)
RCl(s)
Regenerated
resin
Exhausted
resin
NaOH
P-Alkalinity
19
...DEMINERALIZATION
The reaction during regeneration of the strong
acid cation (SAC) exchanger are as follows
CaR2(s)
2HCl (l)
2HR(s)
2HCl (l)
2HR(s)
HCl (l)
HR(s)
Hydrochloric
Regenerated
20
CaCl2(l)
MgR2(s)
MgCl2(l)
NaR(s)
NaCl (l)
Exhausted
...DEMINERALIZATION
The reactions during regeneration of the strong
base anion (SBA) exchanger are as follows
R2SO4(s)
Na2SO4(l)
+ 2NaOH(l)
RCl(s)
NaCl(l)
+ NaOH(l)
ROH(s)
RHCO3(s) + NaOH(l)
NaHCO3(l)
ROH(s)
RHSiO3(s) + NaOH(l)
NaHSiO3(l)
ROH(s)
Exhausted
Regenerated
Sodium
2ROH(s)
21
Waste
...DEMINERALIZATION
Another two bed demineralization process
utilises a weak base anion (WBA) exchanger
after the strong acid cation (SAC) exchanger
when silica removal is not required.
The reactions of the WBA resin during service
are
HCl(l)
R .(s)
HCl (s)
H2SO4(l)
R .(s)
R H2SO4
(s)
22
...DEMINERALIZATION
The reactions of the WBA resin during regeneration
are
R HCl (s)
+ H2O(l)
+ NaOH(l)
R .(s)
+ NaCl(l)
R H2SO4(s) + 2NaOH(l)
2H2O(l)
R .(s)
Exhausted
resin
Regenerated
Waste
resin
effluent
Sodium
hydroxide
+ Na2SO4(l) +
23
...DEMINERALIZATION
A partial list of demineralization treatment
schemes.
SAC
SBA
SAC
DG
SBA
SAC
DG
SBA
MB
SAC
DG
SBA
CATPOL
SAC
DG
WBA -
SBA
WAC
SAC -
DG
WBA -
LBC
DG
LBA
MB
DG - Degasser
Cation
MB
SBA - MB
24
REGENERATION TECHNIQUES
Individual units - softener, cation, anion - are
regenerated by the coflow or counterflow
method
Pair of units - WAC - SAC, WBA - SBA - are
regenerated in thoroughfare mode with the
regenerant flowing from the secondary unit to
the primary unit.
Mixed beds are regenerated sequentially or
simultaneously.
25
COFLOW/COUNTERFLOW
REGENERATION
The direction of flow of the regenerant can be
the same as that of the service flow or
opposite to it.
When the regenerant flow is in the same
direction as the service flow the regeneration
process
is
called
cocurrent
or
coflow
regeneration.
When the regenerant flow is in the direction
opposite to the service flow, the regeneration
process is called countercurrent or counterflow
26
regeneration.
COFLOW UNIT
27
28
COFLOW REGENERATION
Coflow regeneration comprises the following
basic steps
Backwash
Regenerant injection
Rinse
The rinse step may include a slow rinse followed
by the final rinse
29
COUNTERFLOW
REGENERATION
Counterflow regeneration provides superior
quality of treated water as compared to
coflow regeneration.
Consequently
counterflow
regeneration
results in a lower consumption of chemicals
as compared to coflow regeneration.
Counterflow
regeneration
special requirements.
needs
some
30
COUNTERFLOW
REGENERATION
bed
during
the
31
COUNTERFLOW UNIT
32
INTERNAL ARRANGEMENT OF
COUNTERFLOW UNIT
33
COUNTERFLOW
REGENERATION
Regenerant injection
Regenerant rinse
Final rinse
34
REGENERANT INJECTION
CONCENTRATIONS
The table below lists the regenerants and the
injection concentrations into various units.
Regenerant
Unit
Concentration (% w/v max.)
NaCl
Softener
15
HCl
WAC/SAC/MB
H2SO4
WAC
SAC/MB
0.8
1.5 - 5
NaOH
WBA/SBA/MB
WBA-SBA
5
2-4
35
THOROUGHFARE REGENERATION
In thoroughfare regeneration, the primary
invariably is a coflow unit while the
secondary may be a coflow or counterflow
unit.
In WAC - SAC system, the WAC is regenerated
coflow and the SAC is regenerated
counterflow always.
In WBA - SBA pair of units, the WBA is
regenerated coflow while the SBA may be
either coflow or counterflow regenerated
dependent on the silica residual desired. 36
FLOW DIAGRAM OF MB
SEQUENTIAL
SERVICE
38
FLOW DIAGRAM OF MB
SIMULTANEOUS
SERVICE
39
40