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equilibrium
Section 14.1
Reversible Reaction
Example
CaCl2(aq) + Na2SO4(aq) CaSO4(s) +
2NaCl(s)
Because Cl- and Na+ are spectator ions, the net ionic
equation better describes what is happening
Ca2+(aq) + SO42-(aq)
CaSO4(s)
As HI is formed,
fewer collisions
occur between H2
and I2 molecules and
the rate of forward
reaction drops
As HI molecules are
made, more
collisions occur and
the rate of reformation of H2 and
I2 increases.
Higher concentration of
products than reactants.
Products are favored.
Higher concentration of
reactants than products.
Reactants are favored.
SYSTEMS AT EQUILIBRIUM
Objectives
1. Write Keq expressions for reactions in
equilibrium, and perform
calculations with them.
2. Write Keq expressions for the
solubility of slightly soluble slats,
and perform calculations with them.
Equilibrium Constant
A general equation can be written for
a reversible reaction
aA + bB cC + dD
The ratio of products to reactants is
expressed as:
Ke
q
Equilibrium Constant
The value of Keq gives us an
indication of whether the reaction
favours the products or reactants
If K > 1 then equilibrium favours
products i.e. there will be more
products than reactants
If K < 1 then equilibrium favours the
reactants i.e. there will be more
reactants than products
Keq big:
numerator
(products) is
smaller than the
denominator
(reactants).
Concentrations of
reactants will be
greater than
those of
Keq small:
numerator
(products) is
larger than the
denominator
(reactants).
Concentrations of
products will be
greater than
those of
reactants. This is
a favorable
reaction.
Point of Solubility
Solubility
Equilibrium is
dynamic as ions
crystallize at the
same rate as ions
re-enter solution in
a saturated
solution.
EQUILIBRIUM SYSTEMS
AND STRESS
Objectives
1. State Le Chteliers principle
2. Apply Le Chteliers principle to determine
whether the forward or reverse reaction is
favored when stresses are applied to the system
Temperature
Concentration
Pressure
Le Chteliers principle
The principle that states that a system in
equilibrium will oppose a change in a way that
helps eliminate the change
if a chemical system is at equilibrium and we
add a substance (either a reactant or a
product), the reaction will shift so as to
reestablish equilibrium by consuming part of
the added substance.
Conversely, removal of a substance will result
in the reaction moving in the direction that
forms more of the substance.
Change in Concentration
Add product = increases the
concentration of product
The system responds by decreasing
this new concentration and creating
more reactant.
An increase in the reverse reaction
occurs the equilibrium shifts left
Add reactant = the exact reverse
occurs
Change in Temperature
Recall: exothermic reactions release energy
& endothermic reactions absorb energy
Forward
reaction
absorbs
heat
Heat added
Heat
removed
Moves to side to
consume added
heat
Moves to
side to add
heat
removed
Change in Pressure
In an equilibrium, a pressure increase
favors the reaction that produces fewer gas
molecules.
A pressure decrease favors the reaction
the produces more gas molecules.
Changes in pressure only affect gases in
equilibrium
If there are equal gas molecules on both
sides of the equation, pressure changes will
not affect equilibrium
2NO2(g) N2O4(g)
N2 + 3H2 2NH3
Effect on
Equilibrium
Shift to right
(produce more
products)
Shift to left
(produce more
reactants)
Change
What Occurs
Addition of
Reactant
Added reactant
consumed
Addition of
Product
Added product
consumed
Increase in
Pressure
Pressure
decreased
Decrease in
Pressure
Pressure
increased
Increase Temp.
Heat is
consumed
Shift in endo.
direction
Decrease Temp.
Heat is
produces
Shift in exo.
direction