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Why electrochemistry?
Electroplating metals
Electrical production (batteries, fuel cells)
Loses electrons
Loses hydrogen
Gains oxygen
Cu 2+ (aq) + 2 Ag(s)
Gain e - =Reduction
Oxidation Numbers
- the charge an atom would have if the electrons belonged to
the more EN atom
- there are a few rules to help us out
Na
Na0
H2
H20
F2
F20
Oxidation Numbers
- the charge an atom would have if the electrons belonged to
the more EN atom
Na
Na+1
Ca
Ca+2
S-2
N-3
Oxidation Numbers
- the charge an atom would have if the electrons belonged to
the more EN atom
NaCl
Na+1Cl-1
AsI5
As+5I5-1
Cu(NO3)2
Cu+2(N+5O3-2)2
H2Cr2O7
H2+1Cr2+6 O7-2
Oxidation Numbers
- the charge an atom would have if the electrons belonged to
the more EN atom
Oxidation Numbers
- the charge an atom would have if the electrons belonged to
the more EN atom
Oxidation Numbers
- the charge an atom would have if the electrons belonged to
the more EN atom
(SO4)-2
(S+6O4-2)-2
(NO3)
(N+5O3-2)-
(Cr2+3O4)-2
(Cr2O4)
-2
Oxidation Numbers
Oxidation Numbers
Do the five problems on your notes sheet
a. Cr2O3
d. KCl
b. H2Cr2O7
e. Mg(OH)2
c. AsCl5
Redox:
Reduction occurs when an atom gains one or more
electrons.
Ex:
Oxidation occurs when an atom or ion loses one or
more electrons.
Ex:
LEO goes GER
Copper metal reacts with silver nitrate to form silver
metal and copper nitrate:
Cu + 2 Ag(NO3) 2 Ag + Cu(NO3)2.
Practice
Identify in the following reactions what is
oxidized and what is reduced
2K + Cl2 2KCl
K0 goes from 0 to +1, it is oxidized
Cl0 goes from 0 to -1, it is reduced
Practice
Identify in the following reactions what is
oxidized and what is reduced
Practice
Identify in the following reactions what is
oxidized and what is reduced
Zn + Pb+2(aq) Zn+2(aq) + Pb
Zn0 goes from 0 to +2, it is oxidized
Pb+2 goes from +2 to 0, it is reduced
Agents
Ca0 + 2 H+1Cl-1 Ca+2Cl-12 + H20
Since Ca0 is being oxidized and H+1 is being reduced, the
electrons must be going from the Ca0 to the H+1.
Since Ca0 would not lose electrons (be oxidized) if H+1
werent there to gain them, H+1 is the cause, or agent, of
Ca0s oxidation. H+1 is the oxidizing agent.
Since H+1 would not gain electrons (be reduced) if Ca0
werent there to lose them, Ca0 is the cause, or agent, of
H+1s reduction. Ca0 is the reducing agent.
Writing Half-Reactions
Ca0 + 2 H+1Cl-1 Ca+2Cl-12 + H20
Oxidation: Ca0 Ca+2 + 2e Reduction: 2H+1 + 2e- H20
PRACTICE SOME!
HALF REACTIONS
Write both half reactions for the following
reaction:
Cu + AgNO3 Cu(NO3)2 + Ag
Reduction: Ag+ Ag
Ag+ + 1e- Ag
Oxidation:
Cu Cu+2
Cu Cu+2 + 2eCu - 2e- Cu+2
HALF REACTIONS
Write both half reactions for the following
reaction:
I20 I+5
I20 2I+5 + 10eI20 - 10e- 2I+5
Half Reactions
Write both half reactions for the following
reaction:
Sn0 Sn+2
Sn0 Sn+2 + 2eSn0 - 2e- Sn+2
Practice Half-Reactions
Dont forget to determine the charge of each species first!
4 Li + O2 2 Li2O
Oxidation Half-Reaction:
Reduction Half-Reaction:
Zn + Na2SO4 ZnSO4 + 2 Na
Oxidation Half-Reaction:
Reduction Half-Reaction:
STEP 1:
Balancing redox reactions in acid can be easy, if
you follow the rules. We'll work through an
example step by step introducing each rule in
turn.
Suppose you want to balance the following
equation:
Cr2O72- + NO2- --> Cr3+ + NO3- (acid)
STEP 2
First, split the reaction into two half
reactions. One half reaction will show the
oxidation; the other half reaction will show
the reduction. It is not necessary at this
point to know in advance which is which:
Cr2O72- --> Cr3+
NO2- --> NO3-
STEP 3
Balance any atom other than oxygen or
hydrogen first. Work with one half reaction
at a time. In the first half reaction, there are
2 Cr on the left hand side and only 1 Cr on
the right hand side. Balance the Cr first:
Cr2O72- --> 2 Cr3+
NO2- --> NO3-
STEP 4
All that remains is charge balance. To balance the charge, find the net
charge on each side of the half reaction, and add as many electrons as
needed to the more positive side so as to equal the charge on the more
negative side. In this case the net charge on the left hand side of the
half reaction is +12 ( +14 for the 14 hydrogen ions and -2 for the
dichromate ion). The net charge on the right hand side is +6 (+6 due to
two Cr3+ ions and 0 for the 7 water molecules). The net charge on the
left hand side (+12) is more positive than the charge on the right hand
side (+6). By adding 6 electrons (6e-) to the left hand side, the net
charge will be the same on both sides of the half reaction:
6 e- + 14 H+ + Cr2O72- --> 2 Cr3+ + 7 H2O
STEP 5
You need to find the least common multiple (lcm)
of 2 and 6. In this case, the lcm is 6. Next, multiply
each of the half reactions by the factor needed to
obtain the 1 cm. Therefore, multiply the first half
reaction by 1 and the second half reaction by 3:
1 x ( 6 e- + 14 H+ + Cr2O72- --> 2 Cr3+ + 7 H2O )
3 x ( H2O + NO2- --> NO3- + 2 H+ + 2 e- )
STEP 6