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Evaluating Properties
Learning Outcomes
Explain key concepts, including phase and
pure substance, state principle for simple
compressible systems, p-v-T surface,
saturation temperature and saturation
pressure, two-phase liquid-vapor mixture,
quality, enthalpy, and specific heats.
Analyze closed systems, including
applying the energy balance with property
data.
Phase
A quantity of matter that is homogeneous
throughout in both chemical composition and
physical structure.
Homogeneity in physical structure means that
the matter is all solid, or all liquid, or all vapor
(gas).
Examples:
The air we breathe is a gas phase consisting of a
mixture of different gases.
Drinking water with ice cubes contains two phases of
water: liquid and solid.
Vinegar and olive oil salad dressing contains two
different liquid phases.
Pure Substance
A substance that is uniform and invariable
in chemical composition.
A pure substance can exist in more than
one phase, but its chemical composition
must be the same in each phase.
Examples:
Drinking water with ice cubes can be regarded
as a pure substance because each phase has
the same composition.
A fuel-air mixture in the cylinder of an
automobile engine can be regarded as a pure
substance until ignition occurs.
p-v-T Surface
For pure, simple compressible systems,
pressure can be determined as a function of
temperature and specific volume:
p = p(T, v)
The graph of this relation for water is
indicated by the p-v-T surface shown.
Single-phase regions on the surface include
solid, liquid, and vapor.
p-v-T Surface
The dome-shaped region composed of
the two-phase liquid-vapor states is called
the vapor dome.
A state at which a phase change begins
or ends is called a saturation state. Lines
bordering the vapor dome are called the
saturated liquid and saturated vapor lines.
Phase Change
Consider a closed system consisting of a unit mass of liquid
water at 20oC contained within a piston-cylinder assembly.
This state is represented by l (highlighted by the blue dot).
Liquid states such as this, where temperature is lower than
the saturation temperature corresponding to the pressure at
the state, are called compressed liquid states.
Saturated Liquid
As the system is heated at constant pressure, the
temperature increases considerably while the specific
volume increases slightly.
Eventually, the system is brought to the state
represented by f (highlighted by the blue dot).
This is the saturated liquid state corresponding to
the specified pressure.
At these states,
the system now
consists of a
two-phase
liquid-vapor
mixture.
Saturated Vapor
If the system is heated further until the last bit of
liquid has vaporized it is brought to the saturated
vapor state.
This state is represented by g (highlighted by the blue
dot).
At saturated vapor states, x = 1.
Superheated Vapor
When the system is at the saturated vapor state, further
heating at fixed pressure results in increases in both
temperature and specific volume.
This state is represented by s (highlighted by the blue dot).
Vapor states such as this, where temperature is higher than
the saturation temperature corresponding to the pressure at
the state, are called superheated vapor states.
Steam Tables
Tables of properties for different substances
are frequently set up in the same general
format. The tables for water, called the
steam tables, provide an example of this
format. The steam tables are in appendix
tables A-2 through A-5.
Table A-4 applies to water as a superheated
vapor.
Table A-5 applies to compressed liquid water.
Tables A-2 and A-3 apply to the two-phase,
liquid-vapor mixture of water.
Single-Phase Regions
Since pressure and temperature
are independent properties in
the single-phase liquid and
vapor regions, they can be used
to fix the state in these regions.
Tables A-4/A-4E (Superheated
Water Vapor) and A-5/A-5E
(Compressed Liquid Water)
provide several properties as
functions of pressure and
temperature, as considered
next.
Table A-5/A-5E
Table A-4/A-4E
Single-Phase Regions
Properties tabulated in Tables A-4 and A-5 include
Temperature (T)
Pressure (p)
Table A-5/A-5E
Table A-4/A-4E
h = u + pv
Enthalpy is a property because it is defined in terms of properties;
physical significance is associated with it in Chapter 4.
Single-Phase Regions
Example: Properties associated with superheated
water vapor at 10 MPa and 400oC are found in
Table A-4.
v = 0.02641 m3/kg
h = 3096.5 kJ/kg
u = 2832.4 kJ/kg
s = 6.2120 kJ/kgK
Table A-4
Linear Interpolation
When a state does not fall exactly on the grid of values provided
by property tables, linear interpolation between adjacent entries
is used.
Example: Specific volume (v) associated with superheated
water vapor at 10 bar and 215oC is found by linear interpolation
between adjacent entries in Table A-4.
slope =
=
(240 200)oC
(215 200)oC
Table A-4
v = 0.2141 m3/kg
V = Vliq + Vvap
Dividing by the total mass of the mixture, m, an average
specific volume for the mixture is:
V Vliq Vvap
v
State 2
2 kg
of water
Q = 250 kJ
Saturated vapor
p2 = 2.5 bar
p2 = 2.5 bar
2
T1 = 100 C
o
p1 = 1 bar
1
KE + PE +U = Q W
where the kinetic and potential energy changes are neglected.
Thus
W = Q m(u2 u1)
Specific Heats
Three properties related to specific internal energy and specific
enthalpy having important applications are the specific heats cv
and cp and the specific heat ratio k.
u
cv
T v
(Eq. 3.8)
h
cp
(Eq. 3.9)
cp
cv
(Eq. 3.10)
v(T, p) vf(T)
u(T, p) uf(T)
(Eq. 3.11)
(Eq. 3.12)
(Eq. 3.13)
h(T, p) hf(T)
(Eq. 3.14)
u = u(T)
For a substance modeled as incompressible, cp = cv;
the common specific heat value is represented by c.
u2 u1 = c(T2 T1)
(Eq. 3.20a)
(Eq. 3.20b)
8.314 kJ/kmolK
1.986 Btu/lbmoloR
1545 ftlbf/lbmoloR
(Eq. 3.22)
With v = Mv, an
alternative form of the
compressibility factor is
pv
Z=
(Eq. 3.24)
RT
where
R=
R
M
(Eq. 3.25)
Ammonia
Carbon dioxide
Air
pv = RT
(Eq. 3.32)
pV = mRT
(Eq. 3.33)
pv R T
(Eq. 3.34)
pV = nRT
(Eq. 3.35)
u = u(T)
(Eq. 3.36)
With Eqs. 3.32 and 3.36, the specific enthalpy also depends
on temperature alone at such states:
h = u + pv = u(T) + RT
(Eq. 3.37)
(ideal gas)
(Eq. 3.38)
On integration,
u T2 u T1 c v (T ) dT (ideal gas)
T2
T1
(Eq. 3.40)
dh
dT
(ideal gas)
(Eq. 3.41)
On integration,
h T2 h T1 c p (T ) dT (ideal gas)
T2
T1
(Eq. 3.43)
(Eq. 3.50)
(Eq. 3.51)
State 1
T1 = 300 K
1 kg of air
State 2
T2 = 1500 K
T2 = 1500 K
T1 = 300 K
p2
2
p1
KE + PE +U = Q W
Polytropic Process
A polytropic process is a quasiequilibrium
process described by
(Eq. 3.52)
pV n = constant
The exponent, n, may take on any value from
to + depending on the particular process.
For any gas (or liquid), when n = 0, the process is a
constant-pressure (isobaric) process.
For any gas (or liquid), when n = , the process is
a constant-volume (isometric) process.
For a gas modeled as an ideal gas, when n = 1, the
process is a constant-temperature (isothermal)
process.