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Water is life
Save water save life
Universe comprises of three parts of water and one part of
land.
Of the earths water 97% is in the ocean .
Of the remaining 3%
16%
electrical
utilities
8%irrigation
4%
industry
2%
domestic
use
Importance of water
Hard water:
Hard water forms scum when it comes
HARDNESS OF WATER
Hardness of water is that characteristic property which
prevents the lathering of soap easily . This is due to
presence of certain salts of calcium, magnesium and other
heavy metals dissolved in water .
2C17H35COONa + MgSO4(C17H35COO)2Mg
+Na2SO4
Magnesium Stearate
TYPES OF HARDNESS
Temporary hardness:
Permanent hardness
It is due to the presence of chlorides sulphates and
carbonates of calcium, magnesium and other heavy
metals . Unlike temporary hardness ,permanent
hardness is not removed on boiling
Units :
1 ppm = 1 part of CaCO3 present in 106parts of
water
1 mg/lit = 1 mg of CaCO3 present in 1 lit of
water
Relationship between units:
1 mg/lit = 1ppm
EDTA
EBT
[ M-EBT ] complex
wine red
pH 10
MetalEDTA
complex
PROCEDURE:
Part: 1:
Preparation of Standard Hard water:
Transfer a known mass (about 1gm) of
calcium carbonate into a 1000ml volumetric
flask. Add 40-50 ml(approximately) of water.
Add dilute hydrochloric acid till a clear solution
is obtained. Make up the volume to the mark
by adding water.
Part: 2:
Standardization of EDTA:
Part:3:
Determination of Total Hardness of Test
Sample of Water:
Pipette out 10ml of test sample of water in the
conical flask. Add 5ml (approx) of buffer and
3 to 4 drops of Eriochrome black-T indicator.
The solution attains wine-red colour. Titrate
the contents of the conical flask against EDTA
solution till the colour changes from wine-red
to blue. Note the burette reading and repeat
the titration to get concurrent results. Let the
volume of EDTA solution consumed in this
titration be V2 ml.
The total hardness of the test sample of water
is calculated as follows:
BOILER
TROUBLES
BOILER TROUBLES
TYPES
1.Carry over (priming and foaming)
2.Boiler corrosion
3. Scale and Sludge
4.Caustic embrittlement
1.Carry over:
The phenomenon of carrying of water along
with impurities by steam is called carry over.
a)PRIMING:
b) FOAMING:
It is the production of persistent foam or bubbles in
boilers, which do not break easily.
It is due to the presence of substances like oils
Foaming can be avoided by
i. adding anti-foaming chemicals like castor oil
ii. removing oil from boiler water by adding
compounds like NaAlO2.
Priming and Foaming occurs together and are
objectionable because dissolved salts in boilers
deposited and reduce the efficiency or decreases life
of machinery or cause difficult to maintain the
pressure.
2.Boiler Corrosion:
Decay of boiler material by a chemical or electro
chemical attack by its environment.
Main sources for boiler corrosion are
a. Dissolved oxygen
b. Dissolved carbon dioxide
c. Acids from dissolved salts
a.Dissolved oxygen
Water usually contains about 8ml of
Rust
2Na2SO3
N2H4
Na2S
+ O2 2 Na2SO4
+ O2
N2 + 2H2O
+ 2O2
Na2SO4
H2CO3
MgCO3 + H2CO3
i) By addition of inhibitors
a)SLUDGE:
It is formed at colder portions of the boilers.
It is formed by substances, which have greater
solubility in hot water than cold water. (MgCO3,
MgCl2, MgSO4, CaCl2)
It can easily scrapped off with a wire brush.
Disadvantages:
Sludges are poor conductors of heat.
Disturbs the working of boilers.
Prevention of Sludge Formation:
By using well-softened water.
By frequently blow-down operation.( It is nothing
but the removal concentrated water through an out let at
the bottom of the boiler under pressure.)
b)SCALES:
These are difficult to remove
The main sources for the formation of scales
are
Decomposition of calcium bicarbonate
Ca(HCO3)2 CaCO3
+ H2O + CO2
Ca(OH)2 + CO2
4.Caustic Embrittlement:
Caustic embrittlement is a phenomenon in
which the boiler material becomes brittle due to
accumulation of caustic substances.
In high-pressure boilers, sodium carbonate is
hydrolyzed to yield NaOH.
Softening of water
It can be done by 2 methods
1) Internal treatment.
2) External treatment.
Internal Treatment
In this method, raw water is treated inside the boiler.
A) Phosphate
It is generally applicable to high pressure boilers.
conditioning
Scale formation is avoided by adding
sod.phospate, which reacts with Mg,Ca salts
forming soft adherent compunds and easily
removed by blow down operation.
3MCl2 + 2Na3PO4 M3(PO4)2 + 6NaCl
B) Carbonate
conditioning
In low pressure boilers, scale formation can be
avoided by adding sodium carbonate to boiler
water, when salts like CaSO4 can be converted
into CaCO3 . CaCo3 can be removed by blow
down process.
Na2CO3 + CaSO4 CaCO3 + Na2SO4
C) Calgon conditioning:
It involves in adding Sod. Hexa meta phosphate
soluble complex
EXTERNAL TREATMENT:
External treatment: This treatment is
1. Lime-Soda process:
In this method soluble Ca & Mg salts in water
are converted in to insoluble compounds, by
adding calculated amount of Lime and soda.
CaCO3 and Mg(OH)2, so precipitated, are
filtered off.
CaCO3 +2NaCl
With Lime:
Ca(H CO3)2+ Ca(OH)2
MgCl2 + Ca(OH)2
CaCl2+ Na2CO3
2CaCO3 + 2H2O
Mg(OH)2 + CaCl2
CaCO3
+2NaCl
at a temperature of 80-150oC
The reactions proceed faster
Softening capacity increased
Precipitates and sludge formed settle down rapidly
No coagulants are needed
Much of the dissolved gases driven out of the water
Filtration of softened water is fast.
Hot L-S process provides water containing
residual hardness off 15 -30ppm.
2. ZEOLITE (PERMUTIT)
PROCESS:
and soda.
Process:
Na2Ze + Ca(HCO3)2 2NaHCO3 + CaZe
Na2Ze + MgCl2
2NaCl + MgZe
Na2Ze + CaSO4 Na2SO4 + CaZe
Regeneration:
After some time the zeolite is converted in to Ca and
Mg Zeolites and it gets exhausted.
At this stage the supply of this hard water is stopped
and the exhausted Zeolite is reclaimed by heating it
with 10% NaCl
CaZe + 2 NaCl CaCl2 + Na2Ze
On washing with cold water , CaCl2 and MgCl2 can be
removed and regenerated.
Advantages:
It removes the hardness up to 10ppm.
The equipment used is very compact.
No impurities are precipitated, so there is no
formation
of sludge or scale.
It requires less time.
Examples of resins:
OOH
water molecule.
H+ +OH- H2O
Thus water coming from the exchanger is free
Desalination
Disadvantages:
The life time of membrane is quite high
Electrodialysis
Dialysis is a process in which diffusion of smaller
Potable/Domestic/Municipal Water
Screening
Sedimentation
Coagulation
Filtration
Disinfection(chlorination & ozonization)
the following:
1. Screening: Water is allowed to pass
stand
Coagulation
Disadvantages:
Bleaching powder introduces Ca2+ hardness in water and adds lime
residue.
Excess of it gives bad smell and bad taste. Excess chlorine is irritating to
mucous membrane.
(c)By chlorination
Cl2 + H2O HCl + HOCl
Bacteria + HOCl killed bacteria
De-chlorination
Over chlolrinated water can be de chlorinatede by passing it
through a bed of activated carbon. Excess chlorine can also be
removed by adding SO2 (or) NaSO3.
SO2 + Cl2 + 2H 2O H2SO4 + 2HCl
Na2SO3 + Cl2 + H2O Na2SO4 + 2 HCl
(d) By using chloramine (NH2Cl): It is obtained by mixing
chlorine and NH3 in 2:1 ratio. It has better bactericidal action than
chlorine. It is more stable and not producing any irritating odour.
NH3 + Cl2 HCl + NH2Cl
NH2Cl+ H2O NH3 + HOCl
(e) Disinfection by ozone: O3 is prepared by passing silent
electric discharge through cold, dry O2. It is highly unstable.
O3 O2 + (o)
O3 is an excellent, harmless disinfectant. It is highly unstable and
decomposes to give nacent oxygen (o). (o) is a powerful oxidizing
agent. It oxidizes organic matter in water and also kills bacterias.
b) Reducing substances
De-chlorination
Over chlolrinated water can be de chlorinatede by passing it
through a bed of activated carbon. Excess chlorine can also be
removed by adding SO2 (or) NaSO3.
SO2 + Cl2 + 2H 2O H2SO4 + 2HCl
Na2SO3 + Cl2 + H2O Na2SO4 + 2 HCl
(d) By using chloramine (NH2Cl): It is obtained by mixing
chlorine and NH3 in 2:1 ratio. It has better bactericidal action than
chlorine. It is more stable and not producing any irritating odour.
NH3 + Cl2 HCl + NH2Cl
NH2Cl+ H2O NH3 + HOCl
(e) Disinfection by ozone: O3 is prepared by passing silent
electric discharge through cold, dry O2. It is highly unstable.
O3 O2 + (O)
O3 is an excellent, harmless disinfectant. It is highly unstable and
decomposes to give nacent oxygen (O). (O) is a powerful oxidizing
agent. It oxidizes organic matter in water and also kills bacterias.
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