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2. Iridium crystallizes in a face-centered cubic unit cell that has an edge length of 3.833. The
atom in the center of the phase is in contact with the corner atoms. Calculate the atomic
radius of an iridium atom. Calculate the density of Iridium.
;
the unit cell contains 4 Ir atoms since it is face-centered cubic. Therefore,
the amu is multplied by 4.
3. Indicate the type of crystal (molecular, metallic, covalent network, or ionic) each of the
following would form upon solidification: CaCO 3, Pt, ZrO2 (MP=2677C; ionic), Kr, benzene
and I2.
4. For each of the following pair, determine which will have the higher melting point: B
(2092C; covalent) and BF3(-127C; molecular); Na(97.8C; metallic) and NaCl(~775C;
ionic); TiO2(~1830C; ionic) and TiCl4(-24C; molecular); LiF and MgF2.
Phase Diagrams
1. Explain why the heats of fusion is generally lower than heats of vaporization.
2. Name the phase transitions in each of the following situations:
3. Refer to Figure 11.27b in your book. Describe the phase changes (and the
temperatures at which they occur) when CO 2 is heated from -80C to -20C at
a) constant P of 3 atm and b) a constant pressure of 6atm.
4. Given the same phase diagram on the problem above, will solid CO 2 float on
liquid CO2 (Hint: the CO2 diagram shows a positive slope at the solid to liquid
interphase)? As it is heated, will solid CO 2 sublime or melt under a
pressure of
1atm?