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PENGERTIAN
KOROSI: PENURUNAN KUALITAS
LOGAM KARENA REAKSI DENGAN
LINGKUNGAN
Penggolongan Korosi:
1. Uniform/general attack (korosi umum)
2. Galvanic corrosion (korosi galvanis)
3. Crevice corrosion (korosi celah)
4. Pitting corrosion (korosi sumur)
5. Intergranular corrosion (korosi batas butir)
6. Selective leaching (korosi selectif)
7. Erosion corrosion (korosi erosi)
8. Stress corrosion (korosi tegangan)
Daerah yang
kemungkinan terkena
korosi.
Cara
pencegahannya.
Environment
Proper material
Nitric acid
Stainless steels
Caustic
Hydrofluoric acid
Monel (Ni-Cu)
Hot hydrochloric
acid
No
6
Environment
Nonstaining
atmospheric
exposure
Proper material
Aluminium
7
8
Distilled water
Hot strong oxidizing
solution
Tin
Titanium
9
10
Ultimate resistance
Concentrated
sulfuric acid
Tantalum
Steel
E.g : Stainless
Steels
wt.% Cr
2. Nickel
Structure: FCC (austenite forming
element/stabilize austenitic structure)
Added to produce austenitic or duplex stainless
steels. These materials possess excellent
ductility, formability and toughness as well as
weld-ability.
Nickel improves mechanical properties of
stainless steels servicing at high temperatures.
Nickel increases aqueous corrosion resistance of
materials.
Influence of Cr on
iron base alloy
containing 8.39.8wt.%Ni
3. Carbon
Very strong austenite forming element (30x
more effective than Ni). I.e. if austenitic
stainless steel 18Cr-8Ni contains 0.007%C,
its structure will convert to ferritic structure.
However the concentration of carbon is
usually limited to 0.08%C (normal
stainless steels) and 0.03%C (low carbon
stainless steels to avoid sensitization during
welding).
Minor alloying
elements :
Manganese
Austenitic forming element. When necessary can be
used to substitute Ni. Concentration of Mn in stainless
steel is usually 2-3%.
Molybdenum
Ferritic forming element. Added to increase pitting
corrosion resistance of stainless steel (2-4%).
Molybdenum addition has to be followed by decreasing
chromium concentration (i.e. in 18-8SS has to be
decreased down to 16-18%) and increasing nickel
concentration (i.e. has to be increased up to 10-14%).
Improves mechanical properties of stainless steel at
high temperature. Increase aqueous corrosion
resistance of material exposed in reducing acid.
Tungsten
Is added to increase the strength and toughness of
martensitic stainless steel.
Copper
Is added to increase corrosion resistance of
stainless steel exposed in environment containing
sulfuric acid.
Silicon
Reduce susceptibility of SS to pitting and crevice
corrosion as well as SCC.
Three
Tensile stress
is below yield
point
Tensile
stress
Corrosive
environment is
often specific to
the alloy system
Susceptible
material
Corrosive
environment
Stress
corrosion
cracking
Surface morphology
Example of crack
propagation during
intergranular stress
corrosion cracking
(IGSCC) ASTM A245
carbon steel
Fracture surface of
intergranular SCC on
carbon steel in hot nitric
solution
Fracture surface of
transgranular SCC on
austenitic stainless steel in
hot chloride solution
Electrochemical effect
pitting
Zone 1
cracking
zones
passive
Zone 2
active
Control/prevention :
Reduce
Alteration of Environment
Environment factors
affecting corrosion design
:
Dust particles and man-made pollution CO,
NO, methane, etc.
Temperature high T & high humidity
accelerates corrosion.
Rainfall excess washes corrosive materials
and debris but scarce may leave water
droplets.
Proximity to sea
Air pollution NaCl, SO 2, sulfurous acid, etc.
Protective Coatings /
Wrapping
Provide barrier between metal and environment.