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CONTENTS
I. What is bioethanol?
II. Bioethanol Production
III. Feedstocks
IV. Fuel Properties
V. Application
VI. Advantages
VII.Disadvantages and Concerns
VIII.Ethanol Controversy
IX. Comparison of Bioethanol and Biodiesel
X. Case study [Brazil]
XI. Future development
What is bioethanol?
Colourless and clear liquid
Used to substitute petrol fuelfor road
transport vehicles
One of the widely used alternative
automotive fuel in the world (Brazil & U.S.A are
the largest ethanol producers)
Bioethanol Production
Wheat/Grains/Corn/Sugar-cane can be used
to produce ethanol. (Basically, any plants that
composed largely of sugars)
Bioethanol Production
Bioethanol Production
Bioethanol Production
Wet milling process
corn kernel is soaked in warm water
proteins broken down
starch present in the corn is released
(thus, softening the kernel for the milling
process)
microorganisms, fibre and starch products
are produced.
In the distillation process, ethanol is
produced.
Bioethanol Production
Dry milling process
Clean and break down the corn kernel into
fine particles
Sugar solution is produced when the
powder mixture (corn germ/starch and
fibre) is broken down into sucrose by
dilute acid or enzymes.
Yeast is added to ferment the cooled
mixture into ethanol.
Bioethanol Production
Sugar fermentation
Hydrolysis process breaks down the
biomass cellulosic portion into sugar
solutions which will then be fermented
into ethanol.
Yeast is added and heated to the solution.
Invertase acts as a catalyst and convert
the sucrose sugars into glucose and
fructose. (bothC6H12O6).
Bioethanol Production
Chemical reaction 1
Bioethanol Production
Fractional Distillation Process
After the sugar fermentation process, the
ethanol still does contain a significant
quantity of water which have to be
removed.
In the distillation process, both the water
and ethanol mixture are boiled.
Ethanol has a lower boiling point than
water, therefore ethanol will be converted
into the vapour state first condensed
and separated from water.
Feedstocks
Sugar is required to produce ethanol by
fermentation.
Plant materials (grain, stems and leaves) are
composed mainly of sugars
almost any plants can serve as feedstock for ethanol
manufacture
corn
Europe
Feedstocks
R&D activities on using lignocellulosic
(woody materials) as feedstock
Lignocellulosic biomass is more abundant and
less expensive than food crops
higher net energy balance
accrue up to 90% in greenhouse gas savings,
much higher than the first generation of biofuel
However, more difficult to convert to sugars due
to their relatively inaccessible molecular
structure
Fuel Properties
Fuel Properties
Gasoline
Molecular weight
111
[kg/kmol]
Density [kg/l] at 15C 0.75
Bioethanol
46
34.8
Boiling temperature
[C]
Reid Vapour
Pressure [kPa] at
15C
0.80-0.82
41.3
26.4
31
21.2
97
109
86
92
8
14.7
11
9.0
30-190
78
75
16.5
Energy content
Bioethanol has
much lower
energy content
than gasoline
about two-third of
the energy
content of
gasoline on a
volume base
Fuel Properties
Fuel Properties
Gasoline
Molecular weight
111
[kg/kmol]
Density [kg/l] at 15C 0.75
Bioethanol
46
34.8
Boiling temperature
[C]
Reid Vapour
Pressure [kPa] at
15C
0.80-0.82
41.3
26.4
31
21.2
97
109
86
92
8
14.7
11
9.0
30-190
78
75
16.5
Octane number
Octane number of
ethanol is higher than
petrol
hence ethanol has
better antiknock
characteristics
increases the fuel
efficiency of the
engine
oxygen content of
ethanol also leads to a
higher efficiency,
which results in a
cleaner combustion
process at relatively
low temperatures
Fuel Properties
Fuel Properties
Molecular weight
[kg/kmol]
Density [kg/l] at 15C
Oxygen content [wt%]
Lower Calorific Value
[MJ/kg] at 15C
Lower Calorific Value
[MJ/l] at 15C
Octane number
(RON)
Octane number
(MON)
Cetane number
Stoichiometric
air/fuel ratio [kg
air/kg fuel]
Gasoline
111
Bioethanol
46
0.75
0.80-0.82
34.8
Boiling temperature
[C]
Reid Vapour
Pressure [kPa] at
15C
41.3
26.4
31
21.2
97
109
86
92
8
14.7
11
9.0
30-190
78
75
16.5
Application
Application
Blending of ethanol with a small proportion of a
volatile fuel such as gasoline -> more cost effective
Various mixture of bioethanol with gasoline or
diesel fuels
Advantages
Exhaust gases of ethanol are much cleaner
it burns more cleanly as a result of more complete
combustion
Carbon neutral
the CO2 released in the bioethanol production process is
the same amount as the one the crops previously
absorbed during photosynthesis
Advantages
Decrease in ozone formation
The emissions produced by burning ethanol are less reactive with
sunlight than those produced by burning gasoline, which results
in a lower potential for forming ozone
Energy security
esp. Countries that do not have access to crude oil resources
grow crops for energy use and gain some economic freedom
Ethanol Controversy
Is it justifiable?
..to use agriculture land to grow energy crops instead of food
crops when there are so many starving people in the world. In
the developed countries that is not a problem, but in the
developing ones where we have a large number of people
living below the poverty this may lead to a crisis.
Ethanol Controversy
Is burning biofuel more environmentally friendly
than burning oil?
Fact that producing biofuel is not a "green process
requires tractors and fertilisers and land
With the increase in biofuel production, more forests will
be chopped down to make room for biofuel, CO2
Bioethanol
Biodiesel
Environment
Both reduce greenhouse gas emissions as biofuels are primarily derived from
al Benefit
crops which absorb carbon dioxide.
Compatibility ethanol has to be blended with fossil
Able to run in any diesel generated
fuel like gasoline, hence only compatible engines
with selected gasoline powered
automobiles.
Costs
Gallons per
acre
Cheaper
More expensive
420 gallons of ethanol can be generated 60 gallons of biodiesel per acre
per acre
soybeans
cost of soybean oil would significantly
increase if biodiesel production is
increased as well.
Energy
Greenhousegas
Emissions
(GHG)
Future development
For bioethanol to become more sustainable to
replace petrol, production process has to be more
efficient
Reducing cost of conversion
Increasing yields
Increase the diversity of crop used
Thank
You!