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Heating
(Review Ch. 9)
The heat required to heat an object is proportional to:
Mass of the sample (m)
Heat for one gram for 1 degree (Specific Heat Capacity)
Temperature change required. (T)
q = (m)(S.H.)(T)
The product, mass times specific heat is the heat capacity. cp
q = cp T (calorimetry)
When a hot sample is in contact with a colder one, the heat gained
by the colder sample must equal the heat lost by the hot sample.
The heat required to vaporize one mole of a liquid is its molar
heat of vaporization. Hvap
The heat removed when one mole of a liquid is frozen is the molar
heat of fusion.
Hfusion
The heat to absorbed when a mole of solid passes directly from the
solid into to the gas phase is called the molar heat of sublimation.
Hsub
(sign?)
Is the comparison between H and E correct?
(Should more heat be required at constant pressure?)
CH3CH2CF3 CH3NHCH3
CH3COCH3
SPONTANEOUS MIXING
Miscibility
IMF
IMF
If IMF = IMF
Remove partition
SPONTANEOUS MIXING
Miscibility
SPONTANEOUS MIXING
Miscibility
SPONTANEOUS MIXING
Miscibility
Random location for all particles
Miscible
PROBLEMS:
1. Place the following under H2O or CCl4 indicating which of
solvent you think the following is soluble.
NaCl CH3OH
CH3OCH3
H2O
NaCl
CH3OH
SO2
HCl
SO2
Br2
HCl
CCl4
CH3OCH3
Br2
( )
1/T
Or ln(P2/P1) = - Hvap /R (1/T2 - 1/T1)
Slope = rise
run
VAPOR PRESSURE
1. If the intermolecular force is HIGH, few molecules can
escape the liquid surface and the vapor pressure is LOW.
2. INCREASING the temperature increases the fraction
of the molecules that can escape and INCREASES
vapor pressure.
3. The BOILING POINT is the temperature at which the
vapor pressure is equal to the applied pressure. (at the
NORMAL boiling point, the vapor pressure is 1.00 atm.)
4. At the melting point, the solid and the liquid have the
same vapor pressure.
checkpoint
p
r
e
s
s
u
r
e
Liquid
1 atm
Solid
4
3
2
Gas
PROBLEMS:
1
Refer this phase diagram:
Temperature
1. What is the composition at each of the points numbered:
1, 2, 3, 4, 5, 6, 7, 8, 9.
2. Describe what occurs in moving from point 1 to point
5 and from point 6 to point 9.
3. Identify the: Critical point, Triple point,
checkpoint
Supercritical fluid region.
PROBLEMS:
4. Copper forms a face-centered cubic unit cell with an
edge length of 361 pm. What is the radius of the
copper atom? What is the density of copper?
Body Centered Cubic Lattice
Radius:
2 L = 4R
(1.414)(361 pm)
R=
4
4 (At.Wt.)
6.02 x 1023
Density =
L3
Density =
R = 128 pm
2
10
cm
L = 361 x 10 m
1m
L = 3.61 x 10-8 cm
(4)(63.54)
(6.02 x 1023)(3.61 x 10-8)3
-12
= 8.97 g/cm3
checkpoint
Rate of
escape
Gas molecules
EQUALS
Rate of
return
3
2
8 corners(patticles)
Unit Cell
1/8 x 8 = 1 particle
(1) At.Wt.
L
per unit cell
6.02 x 1023
Density
=
m/V=
Length of unit cell(L) = 2R
L3 (2R)3
3L
2L
3L =4R
Density =
2 x Atomic Mass
6.02 x 1023
L3
Phase Diagrams
5
p
r
e
s
s
u
r
e
Liquid
1 atm
Solid
3
2
Gas
Temperature
HYDROGEN BONDING
(BRIDGING)
Hydrogen bonded to an atom
with same electronegaivity:
X
180o
Hydrogen bonded to O, N or F:
Adjacent atom with lone pair:
X
+
Attraction
Pair of electrons
SINGLE MOLECULE
+
+
ADJACENT MOLECULE
Attr.
ELECTRONEGATIVITY
INCREASE:
1.0 1.5
Li
2.1
H
2.0 2.5
Be
3.0
C
P
OBSERVATION:
When comparing atoms on different rows
on the periodic table, the element closest
to the noble gas on its row will have
the higher electronegativity.
3.5 4.0
N
O
Cl
Br
I
INCREASE:
DIPOLE MOMENTS
Spherical electron distribution
No charge separation
r = 0 and = 0
Center of negative charge
UNSYMMETRICAL
MOLECULES
VSEPR:
(m+n)
2. AX2
3. AX3
4. AX4
5. AX5
AX2E (N)
AX3E (N)
AX4E (N)
AXE2(N)
AX2E2 (N) AXE3 (N)
AXE4 (N)
6. AX6 S AX5E (N) AX4E2 (S) AX3E3 (N) AX2E4 (S) AXE5 (N)
EXAMPLE: SF3- anion Valence electrons = 6 + 3 x7 +1 = 28
3
2
SF3- anion is Non symmetrical
8 28
2 4
VSEPR = A X3 E 2 and POLAR.
24
4
O ----- H
H
This is a H-O covalent bond
N
H
H
H
return
5 parts
return
London Dispersion
boiling point
CH4O
CH3CN
CH3F
15 parts
return
P(atm)
1.0
1
ab
T(oC)
cd
7 points
Segment 1Point #6
Your problem:
Platinum (at. mass = 195.08) has a density of 21.45 g/cm3
and forms a face centered cubic crystal. What is the diameter of
the platinum atom?
1 part