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EQUILIBRIUMSTAGE OPERATIONS
One class of mass-transfer devices consists
Equilibrium-stage Operations
The closeness of the approach to
equilibrium depends on
the effectiveness of mixing and
mass transfer between the phases
later to
account for any actual departures from
equilibrium
stage cascade,
two typical countercurrent multistage
devices,
TYPICAL DISTILLATION
EQUIPMENT
A plant for continuous distillation is shown in
Figure
Reboiler A is fed continuously with the liquid
mixture to be distilled
The liquid is converted partially into
vapor
boiler than
the
the vapor,
the
boiler so that
there is mass transfer of the low boiler
of increase in pressure
stage because
the vapor coming to a stage has a lower
the liquid passing down to the second stage will still be able to
enrich
the lower quality vapor coming up to the second stage
by
the
leaving condenser D
Part of the condensate is withdrawn
as the product, and
the remainder is returned to the top of the column
plates
into
many small bubbles and
passes in intimate contact through the
pool of liquid on the tray
Because of the action of the vapor bubbles,
the liquid is actually a boiling frothy
mass
The vapor space above the froth contains
a fine mist of droplets formed by
collapsing bubbles
Most of the drops settle back into the
liquid, but
some are entrained by the vapor and
carried to the plate above
MATERIAL BALANCES
Consider the portion of the
Ln
La xa + Vn+1 yn+1 = Ln xn + Va ya
(2)
ENTHALPY
BALANCES
In many equilibrium-stage processes the
problem#1-
Boiling Point
Diagram & Equilibrium Curve
The vapor pressure of benzen &
Vapor pressure
data
S#
Temp, C
80.1
760
85
877
345
90
1016
405
95
1168
475
100
1344
557
105
1532
654
110
1748
743
110.6
1800
760
Solution:
Suppose that benzene is
Xe
pb)
Ye=
xe (pa/P)
Problem#2
Draw the equilibrium curve of
Pa,
mmHg
85
176
273
376
482
588
xe
ye
Xe = pa/ Pt
Ye = (Ca/ M.Wt. of solute) /
IDEAL CONTACT
STAGES
The ideal stage is a standard to which
stage,
DETERMINING THE
NUMBER OF IDEAL STAGES
having
coordinates (xa, ya), and
point b, having
stage, which
is stage 1, is ya or y1
the gs absorber
this separation
EXAMPLE
By means of a plate column, acetone is
absorbed from its mixture with air in
nonvolatile absorption oil. The entering
gas contains 30 mole percent acetone,
and the entering oil is acetone free. Of
the acetone in the air 97 percent is to
be absorbed, and the concentrated
liquor at the bottom of the tower is to
contain 10 mole percent acetone. The
equilibrium relationship is ye = 1.9 xe
Plot the operating line and determine
the number of ideal stages.