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Subatomic particles
Atoms are composed of three subatomic particles: protons,
neutrons and electrons. The two important properties of
these particles are mass and charge:
Particle
Relativemass
Relative charge
proton
+1
neutron
electron
1/1840
-1
mass
number (A)
atomic
number (Z)
carbon-13
Isotopes of chlorine
About 75% of naturally-occurring chlorine is chlorine-35 (35Cl)
and 25% is chlorine-37 (37Cl).
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17 protons
17 protons
18 neutrons
20 neutrons
17 electrons
17 electrons
Isotopes of carbon
There is also more than one isotope of carbon:
Isotope
Protons
Neutrons
12
13
14
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Weighing atoms
Mass spectrometry is an accurate instrumental technique
used to determine the relative isotopic mass (mass of each
individual isotope relative to carbon-12) and the relative
abundance for each isotope. From this, the relative atomic
mass of the element can be calculated.
Some uses of mass
spectrometry include:
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carbon-14 dating
forensic science
space exploration.
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Mass spectrometry
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100
B (80%)
11
80
60
40
10
B (20%)
20
0
0
6
m/z
10
12
Calculating Ar
Most elements have more than one isotope. The relative
atomic mass of the element is the average mass of the
isotopes taking into account the abundance of each isotope.
Example: what is the Ar of boron?
In a sample of boron, 20% of the atoms are 10Br and 80%
are 11Br.
If there are 100 atoms, then 20 atoms would be 10Br and
80 atoms would be 11Br.
The relative atomic mass is calculated as follows:
Ar of Br = (20 10) + (80 11)
100
Ar of Br = 10.8
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Calculating Ar of magnesium
In a sample of magnesium, 79.0% of the magnesium
atoms are 24Mg, 10.0% are 25Mg and 11.0% are 26Mg.
Example: What is the Ar of magnesium?
1. Calculate mass abundance
of each isotope
24 79.0
25 10.0
26 11.0
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Ar calculations
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Glossary
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Multiple-choice quiz
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Models of atoms
At GCSE level, the model of the
atom states that a nucleus is
surrounded by shells of electrons.
Each shell holds a different
maximum number of electrons:
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1 st
2 nd
3 rd
4 th
5 th
6 th
7 th
8 th
9 th
10
th
11
th
12
th
ionization energy
electron removed
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900
800
700
600
500
400
Be
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Mg
Ca
Sr
element
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Energy levels
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1000
However, aluminiums
800
value is below that of
magnesium. This suggests
600
that the third principal
400
energy level is not one
Na Mg Al Si P S Cl Ar
single energy level.
element
The sub-levels
There are four sub-levels,
labelled in order of
increasing energy: s, p, d
and f. Each holds a
different number of
electrons.
Each principal
energy level
contains a
different
number of
sub-levels.
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10
14
principal energy
level, n
max no.
electrons
sub-levels
1s
2s, 2p
3s, 3p, 3d
18
32
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Order of sub-levels
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23
1s22s22p63s23p64s23d3
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8 + 2 = 10
1s22s22p6
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28
1s22s22p63s23p64s23d8
1s22s22p63s23p63d8
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Electron orbitals
It is impossible to exactly locate the position of an electron
within an energy sub-level. By measuring the electron density
around the nucleus, it is possible to define regions where
electrons are most likely to be found at any one time. These
regions are called orbitals.
Each energy sub-level has one or more orbitals, each of
which can contain a maximum of two electrons.
sub-level no. orbits max no.
electrons
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10
14
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spin diagram
for
magnesium,
1s22s22p63s2
400
Na Mg Al Si P S Cl Ar
element
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phosphorus
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sulfur
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copper
1s22s22p63s23p64s13d5
1s22s22p63s23p64s13d10
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Glossary
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Multiple-choice quiz
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What is periodicity?
The term periodicity describes a repeating pattern in
properties of elements across periods of the periodic table.
The Russian chemist Dmitry
Mendeleev is credited with being the
creator of the first version of the
periodic table. He observed that when
the elements are arranged in order of
atomic mass, there are recurring
patterns in certain properties.
The modern periodic table can be used
to analyse trends in properties such as
atomic radius across periods and
down groups.
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covalent
radius
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0.190
Mg
0.145
Al
0.118
Si
0.111
0.098
0.088
Cl
0.079
Ar
0.071
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Element
Na
11
12
Mg
13
Al
14
Si
15
16
17
Cl
Ar
18
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What is shielding?
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11
0.190
Mg
12
0.145
Al
13
0.118
Si
14
0.111
15
0.098
16
0.088
Cl
17
0.079
Ar
18
0.071
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There is a general
increase in the first
ionization energies
across period 3.
1400
1200
1000
800
ionization
energy (kJ mol-1)
lower
ionization
energies
than
expected
Si
Cl
Ar
element
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magnesium
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aluminium
phosphorus
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sulfur
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temperature (K)
3000
2500
2000
1500
1000
500
0
Na
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boiling point
melting point
Mg
element
Al
Silicon
Silicon has a macromolecular
structure similar to that of
diamond.
Each silicon atom is
bonded to four
neighbouring silicon atoms
by strong covalent bonds.
These must be broken in
order for silicon to melt.
This requires a lot of
energy, so silicon's melting
and boiling points are high.
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Period 3 non-metals
The melting and boiling points of phosphorus, sulfur and
chlorine are much lower than those of silicon.
temperature (K)
This is because
they have a
simple molecular
structure with
weak van der
Waals forces
holding the
molecules together.
3500
3000
2500
2000
1500
1000
500
0
Na
Mg
Al
Si
P
element
Cl
Ar
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Glossary
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Multiple-choice quiz
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