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Metals
Chapter Twenty:
A SURVEY OF THE
REPRESENTATIVE ELEMENTS
193
194
195
196
197
198
199
The Atomic
Radii of
Some Atoms
in Picometers
1910
QUESTION
Theperiodictableisareflectionofanunderlyingrationalethat
manifestsitselfwithpredictable,observablepropertiesofthe
elements.However,thereareoftensharpdifferencesbetween
thefirstelementinacolumnandtheremainingelementsofthe
column.Whichofthefollowingaccountsformostofthose
differences?
1. Thefirstmemberofagroupmaynotbeametalinthefirst
fewoftherepresentativegroups.
2. Thefirstmemberofthegroupisoftenametalloid.
3. Thefirstmembertypicallyhasanunusuallysmallatomic
radii.
4. Thefirstmemberhashighelectronegativity.
Copyright Houghton Mifflin Company. All rights reserved.
1911
QUESTION
Whatisitaboutthesizeofthefirstelementinmanygroupsthat
causesittoforminmoleculesratherthanaggregatesby
subsequentgroupmembers?
1. Sincethefirstmemberofthegrouphasanunusuallysmall
atomicradii,theytendtohaveverylowelectronegativities
whichdoesnotallowaggregatestoform.
2. Thefirstmemberofthegroupstendtohavestrongnuclear
toelectronattractions,whichkeepstheirelectrons
unavailableforbondingtomanyatoms.
3. Thesmallsizeofthefirstmembersofthegroupmakesit
possibletohaveahighdegreeofpibonding.Thisinvolves
moreelectronsinthebondinginamolecule,whichprevents
muchaggregatebonding.
4. Iamnotsurewhatcausesthis.
Copyright Houghton Mifflin Company. All rights reserved.
1912
Chapter Metals:
1914
1915
1916
QUESTION
Whataretheproductsofabalancedequationthatrepresentsthe
reactionofagroup1Ametalwithwater?Note:Mrepresentsa
group1Ametal.
1.
2.
3.
4.
MOH
2MOH
2MOH+H2
M2O2+2H2
1917
1918
1919
1920
Group 1A
Group 2A
Group 3A
Group 4A
Group 5A
1921
Group 1A
Group 2A
Group 3A
Group 4A
Group 5A
1922
Chapter
TRANSITION METALS
AND COORDINATION
CHEMISTRY
Copyright Houghton Mifflin Company. All rights reserved.
2123
2124
2125
Oxidation states
Transition metals have a wide range of
oxidation states and can easily change
from one oxidation state to another.
2126
2127
2128
QUESTION
Ofthefollowingproperties,whichisnottrueofthefirstrow
oftransitionmetals?
1. Theenergylevelsof4sand3dareverysimilar.
2. The4slevelgainselectronsfirst,butnoneofthefirstrow
transitionmetalionshave4selectrons.
3. Thereducingabilitiesofthemetalsinthefirstrow
alwaysincreasefromlefttoright.
4. Inchemicalreactions,thefirstrowtransitionmetalsform
positiveions.
2129
Electron configuration
Cr and Cu have unfilled 4s orbitals
since there is more stability in the half
or completely filled 3d orbitals.
2130
Orbital Filling
2131
2132
QUESTION
Ofthefollowing,whichisthecorrectelectronconfiguration
forthegroundstatechromiumatom?
1.
2.
3.
4.
[Ar]3d6
[Ar]4s13d5
[Ar]4s23d4
[Ar]4s13d44p1
2133
2134
1
t
c
Rea
What is the expected electron
configuration of Sc+?
Explain.
2135
2136
2137
Typical
Compounds
of Iron
2138
Typical
Compounds
of Cobalt
2139
Typical
Compounds
of Nickel
2140
2141
QUESTION
Transitionmetalsincompoundstypicallydisplayawide
varietyofoxidationstates.Inwhichoftheionsorcompounds
listedhereisthereatransitionmetalwiththesameoxidation
numberasCrinCr2O72?
1.
2.
3.
4.
Ni(NH3)6(NO3)2
Fe(OH)(H2O)52+
MnO4
K2FeO4
2142
Coordination Compounds
2143
A Coordination Compound
. . . typically consists of a complex ion
and counter ions (anions or cations as
needed to produce a neutral
compound)
[Co(NH3)5Cl]Cl2
[Fe(en)2(NO2)2]2SO4
Copyright Houghton Mifflin Company. All rights reserved.
2144
2145
2146
2147
2148
QUESTION
Whatistheformulaoftris(ethylenediamine)manganate(II)
nitrate?
1.
2.
3.
4.
[Mn(en)3]NO3
[Mn(en)4](NO3)2
[Mn(EDTA)3]NO3
[Mn(en)3](NO3)2
2149
The Bidentate
Ligand
Ethylenediamine
2150
The
Coordination
of EDTA with a
2+ Metal Ion
2151
QUESTION
HowmanysecondarybondingsitesareusedbytheFeionin
thefollowing:
[Fe(en)2(NO2)2]2SO4
1.
2.
3.
4.
2
4
6
8
2152
QUESTION
Whichionorcompound,ifany,containsthemetalionwith
thegreatestcoordinationnumber?
[Fe(en)2(NO2)2]Cl;[Cr(NH3)4Cl2]+;K3[Fe(C2O4)3]
1.
2.
3.
4.
[Fe(en)2(NO2)2]Cl
[Cr(NH3)4Cl2]+
K3[Fe(C2O4)3]
Allhavethesame.
2153