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Prof. R. Shanthi
What is Heat?
Prof. R. Shanthi
What is Heat?
Prof. R. Shanthi
Units of Heat
The SI unit is the joule (J),
which is equal to Newton-metre (Nm).
Historically, heat was measured in terms of the ability
to raise the temperature of water.
The calorie (cal): amount of heat needed to raise the
temperature of 1 gramme of water by 1 C0 (from
14.50C to 15.50C)
In industry, the British thermal unit (Btu) is still used:
amount of heat needed to raise the temperature of 1 lb
of water by 1 F0 (from 630F to 640F)
Prof. R. Shanthi
Prof. R. Shanthi
Sensible Heat
What is 'sensible heat?
Prof. R. Shanthi
Prof. R. Shanthi
Q = m c dT = m c T
Prof. R. Shanthi
Q = m c T cannot be used.
Instead, we use the following equation:
Q = H = m h
where H is the enthalpy change in the substance
and h is the specific enthalpy change in the substance.
Prof. R. Shanthi
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Exchange of Heat
Calculate the final temperature (tf), when 100 g iron at 80oC is
tossed into 53.5g of water at 25oC.
Data: c = 0.452 J/g oC for iron and 4.186 J/g oC for water
tf = 34.2oC
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Latent Heat
What is latent heat?
Prof. R. Shanthi
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Phases of Matter
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Phase Change
Heat required for phase changes:
Melting: solid liquid
Vaporization: liquid vapour
Sublimation: solid vapour
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Prof. R. Shanthi
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Saturated liquid
Superheated
steam
Saturated steam
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Prof. R. Shanthi
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Latent Heat
Latent heat is the amount of heat added per unit mass of
substance during a phase change
Latent heat of fusion is the amount of heat added to melt
a unit mass of ice OR it is the amount of heat removed
to freeze a unit mass of water.
Latent heat of vapourization is the amount of heat added
to vaporize a unit mass of water OR it is the amount of
heat removed to condense a unit mass of steam.
Prof. R. Shanthi
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Water:
Specific Heat Capacities and Latent Heats
Specific heat of ice 2.06 J/g K (assumed constant)
Heat of fusion for ice/water 334 J/g (assumed constant)
Specific heat of water 4.18 J/g K (assumed constant)
Latent heat of vaporization cannot be assumed a
constant since it changes significantly with the pressure,
and could be found from the Steam Table
How to evaluate the sensible heat gained (or lost) by
superheated steam?
Prof. R. Shanthi
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Water:
Specific Heat Capacities and Latent Heats
How to evaluate the sensible heat gained (or lost) by
superheated steam?
Q = m c T
cannot be used since changes in c with changing
temperature is NOT negligible.
Instead, we use the following equation:
Q = H = m h
provided the system is at constant pressure and the
associated volume change is negligible.
Prof. R. Shanthi
Enthalpies could be referred from the Steam21
Table
Properties of Steam
Learnt to refer to Steam Table to find properties of
steam such as saturated (or boiling point) temperature
and latent heat of vapourization at give pressures, and
enthalpies of superheated steam at various pressures and
temperatures.
Reference:
Chapter 6 of Thermodynamics for Beginners with worked
examples by R. Shanthini
(published by Science Education Unit, Faculty of Science,
University of Peradeniya)
(also uploaded at http://www.rshanthini.com/PM3125.htm)
Prof. R. Shanthi
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-20oC
Prof. R. Shanthi
ice
23
0oC
-20oC
Prof. R. Shanthi
120.2oC
0oC
-20oC
Prof. R. Shanthi
superheated steam
Specific heat
boiling point of water at 2 bar
Latent heat
Specific heat
0oC
-20oC
Prof. R. Shanthi
Latent heat
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Prof. R. Shanthi
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Hot fluid
at TH,in
Cold fluid
at TC,in
Prof. R. Shanthi
Hot fluid
at TH,out
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Prof. R. Shanthi
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Heat Exchanger
Heat lost by the hot fluid = Heat gained by the cold fluid
.m
hot
.
)=m
Specific heat
of hot fluid
Prof. R. Shanthi
cold
Temperature
decrease in the
hot fluid
Specific heat
of cold fluid
Temperature
increase in the
cold fluid
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Heat Exchanger
Heat lost by the hot fluid = Heat gained by the cold fluid
.m
hot
.
)=m
cold
Prof. R. Shanthi
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Heat Exchanger
If the heat exchanger is NOT well insulated, then
Heat lost by the hot fluid = Heat gained by the cold fluid
+ Heat lost to the environment
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Assignment
Give the design of a heat exchanger
which has the most effective heat
transfer properties.
Learning objectives:
1) To be able to appreciate heat transfer applications in pharmaceutical
industry
2) To become familiar with the working principles of various heat
exchangers
3) To get a mental picture of different heat exchangers so that solving
heat transfer problems in class becomes more interesting
Prof. R. Shanthi
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Heat Transfer
is the means by which
energy moves from
a hotter object to
a colder object
Prof. R. Shanthi
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Convection
is the flow of heat carried by moving gas or liquid.
(warm air rises, gives up heat, cools, then falls)
Radiation
is the flow of heat without need of an intervening medium.
(by infrared radiation, or light)
Prof. R. Shanthi
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Conduction
Convection
Radiation
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Conduction
HOT
(lots of vibration)
COLD
(not much vibration)
Heat travels
along the rod
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Conduction
Conduction is the process whereby heat is transferred
directly through a material, any bulk motion of the
material playing no role in the transfer.
Those materials that conduct heat well are called
thermal conductors, while those that conduct heat poorly
are known as thermal insulators.
Most metals are excellent thermal conductors, while
wood, glass, and most plastics are common thermal
insulators.
The free electrons in metals are responsible for the
excellent thermal conductivity of metals.
Prof. R. Shanthi
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Q =kA
( )t
T
L
Q = heat transferred
k = thermal conductivity
A = cross sectional area
T = temperature difference
between two ends
L = length
t = duration of heat transfer
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Thermal Conductivities
Substance
Thermal
Conductivity
k [W/m.K]
Substance
Thermal
Conductivity
k [W/m.K]
Syrofoam
0.010
Glass
0.80
Air
0.026
Concrete
1.1
Wool
0.040
Iron
79
Wood
0.15
Aluminum
240
Body fat
0.20
Silver
420
Water
0.60
Diamond
2450
Prof. R. Shanthi
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Q =kA
( )t
T
L
x
Prof. R. Shanthi
T T1
x
Q =
k A (T1 T2)
x
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Q =
k A (T1 T2)
x
x
Prof. R. Shanthi
T T1
x
T1 T2
x/(kA)
Q =
kA
kB
kC
xA
xB
xC
T1 T2
(x/kA)A
Prof. R. Shanthi
T2 T3
(x/kA)B
T3 T4
(x/kA)C
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Q =
T1 T2
(x/kA)A
T2 T3
(x/kA)B
T3 T4
(x/kA)C
= T1 T2 + T2 T3 + T3 T4
Q =
T1 T4
(x/kA)A + (x/kA)B + (x/kA)C
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Prof. R. Shanthi
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Example 1
An industrial furnace wall is constructed of 21 cm thick
fireclay brick having k = 1.04 W/m.K. This is covered on
the outer surface with 3 cm layer of insulating material
having k = 0.07 W/m.K. The innermost surface is at 1000oC
and the outermost surface is at 40oC. Calculate the steady
state heat transfer per area.
Solution: We start with the equation
Q =
Tin Tout
(x/kA)fireclay + (x/kA)insulation
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Example 1 continued
.
(1000 40) A
Q =
(0.21/1.04) + (0.03/0.07)
Q
A
= 1522.6 W/m2
Prof. R. Shanthi
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Example 2
We want to reduce the heat loss in Example 1 to 960 W/m2.
What should be the insulation thickness?
Solution: We start with the equation
Q =
Tin Tout
(x/kA)fireclay + (x/kA)insulation
(1000 40)
2
W/m
=
960
=
A
(0.21/1.04) + (x)insulation /0.07)
(x)insulation
Prof. R. Shanthi
= 5.6 cm
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ri
To
Q =
Ti To
[ln(ro/ri)] / 2kL
Prof. R. Shanthi
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r3
Ti
Material A
r1
Material B
Q =
To
Ti To
[ln(r2/r1)] / 2kAL + [ln(r3/r2)] / 2kBL
Prof. R. Shanthi
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Example 3
A thick walled tube of stainless steel ( k = 19 W/m.K) with
2-cm inner diameter and 4-cm outer diameter is covered
with a 3-cm layer of asbestos insulation (k = 0.2 W/m.K).
If the inside-wall temperature of the pipe is maintained at
600oC and the outside of the insulation at 100oC, calculate
the heat loss per meter of length.
Solution: We start with the equation
Q =
Ti To
[ln(r2/r1)] / 2kAL + [ln(r3/r2)] / 2kBL
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Example 3 continued
Q =
2 L ( 600 100)
[ln(2/1)] / 19 + [ln(5/2)] / 0.2
Q
L
Prof. R. Shanthi
= 680 W/m
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Convection
is the flow of heat carried by moving gas or liquid.
(warm air rises, gives up heat, cools, then falls)
Radiation
is the flow of heat without need of an intervening medium.
(by infrared radiation, or light)
Prof. R. Shanthi
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Convection
Convection is the process in which heat is carried from
place to place by the bulk movement of a fluid (gas or
liquid).
Prof. R. Shanthi
Convection
It explains why breezes come from the ocean in the day
and from the land at night
Prof. R. Shanthi
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Qconv. =
Tsurface Tfluid
1/(hA)
Prof. R. Shanthi
Example 4
The convection heat transfer coefficient between a surface at 50oC and
ambient air at 30oC is 20 W/m2.K. Calculate the heat flux leaving the
surface by convection.
Solution:
Flowing fluid at Tfluid = 30oC
= h A (Tsurface Tfluid)
conv.
h = 20 W/m2.K
Prof. R. Shanthi
Example 5
Air at 300C flows over a flat plate of dimensions 0.50 m by 0.25 m.
If the convection heat transfer coefficient is 250 W/m2.K, determine
the heat transfer rate from the air to one side of the plate when the
plate is maintained at 40C.
Solution:
Flowing fluid at Tfluid = 300oC
Heated surface at Tsurface = 40oC
= h A (Tsurface Tfluid)
conv.
= 250 W/m2.K x 0.125 m2
x (40 - 300)oC
= - 8125 W/m2
h = 250 W/m2.K
A = 0.50x0.25 m2
Prof. R. Shanthi
Forced Convection
In forced convection, a fluid is forced by external forces
such as fans.
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Free Convection
In free convection, a fluid is circulated due to buoyancy
effects, in which less dense fluid near the heated surface rises
and thereby setting up convection.
70
Prof. R. Shanthi
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Q
T
x
Q =
TA T1
1/(hAA)
Prof. R. Shanthi
T1 T2
x/(kA)
Fluid B
at TB < T2
=
T2 TB
1/(hBA)
72
Q =
TA T1
1/(hAA)
Q =
T1 T2
x/(kA)
T2 TB
1/(hBA)
TA TB
1/(hAA) + x/(kA) + 1/(hBA)
Q = U A (TA TB)
where U is the overall heat transfer coefficient given by
Prof. R. Shanthi
73
ro
Ti r
i
To
Q = U A (TA TB)
where
1/UA = 1/(hAAi) + ln(ro/ri) / 2kL + 1/(hBAo)
Prof. R. Shanthi
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Example 6
Steam at 120oC flows in an insulated pipe. The pipe is
mild steel (k = 45 W/m K) and has an inside radius of 5
cm and an outside radius of 5.5 cm. The pipe is covered
with a 2.5 cm layer of 85% magnesia (k = 0.07 W/m K).
The inside heat transfer coefficient (hi) is 85 W/m2 K, and
the outside coefficient (ho) is 12.5 W/m2 K. Determine the
heat transfer rate from the steam per m of pipe length, if
the surrounding air is at 35oC.
Solution: Start with
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Example 6 continued
1/UA = 1/(hAAi) + ln(ro/ri) / 2kL + + 1/(hBAo)
1/UA = 1/(85Ain) + ln(5.5/5) / 2(45)L
+ ln(8/5.5) / 2(0.07)L + 1/(12.5Aout)
Ain = 2(0.05)L and Aout = 2(0.08)L
1/UA = (0.235 + 0.0021 +5.35 + 1) / 2L
Prof. R. Shanthi
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Example 6 continued
UA = 2L / (0.235 + 0.0021 +5.35 + 1)
Q = U A (120 35)
air
steel
= 81 L
insulation
Q / L = 81 W/m
Prof. R. Shanthi
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Convection
Radiation
is the flow of heat without need of an intervening medium.
(by infrared radiation, or light)
Prof. R. Shanthi
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Radiation
Radiation is the process in which energy is transferred by
means of electromagnetic waves of wavelength band between
0.1 and 100 micrometers solely as a result of the temperature
of a surface.
Heat transfer by radiation
can take place through
vacuum. This is because
electromagnetic waves
can propagate through
empty space.
Prof. R. Shanthi
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= A T4
80
Why is the
mother shielding
her cub?
Prof. R. Shanthi
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82
= A T4
= 2.83 x 1026 W
T4 =
2.83 x 1026 W
(1) (5.67 x 10-8 W/m2.K4) (5.98 x 1018 m2)
Prof. R. Shanthi
T = 5375 K
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Example 7
What is the rate at which radiation is emitted by a surface
of area 0.5 m2, emissivity 0.8, and temperature 150C?
Solution:
Q
t
0.8
Q
t
= A T4
[(273+150) K]4
0.5 m2
Prof. R. Shanthi
85
Example 8
If the surface of Example 7 is placed in a large, evacuated chamber
whose walls are maintained at 25C, what is the net rate at which
radiation is exchanged between the surface and the chamber walls?
Solution:
Q
t
= A (T4 - To4 )
[(273+25) K]4
[(273+150) K]4
Q
t
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Example 8 continued
Note that 547 W of heat loss from the surface occurs at
the instant the surface is placed in the chamber. That
is, when the surface is at 150oC and the chamber wall
is at 25oC.
With increasing time, the surface would cool due to
the heat loss. Therefore its temperature, as well as the
heat loss, would decrease with increasing time.
Steady-state conditions would eventually be achieved
when the temperature of the surface reached that of the
surroundings.
Prof. R. Shanthi
87
Example 9
Under steady state operation, a 50 W incandescent light bulb has a
surface temperature of 135C when the room air is at a temperature
of 25C. If the bulb may be approximated as a 60 mm diameter
sphere with a diffuse, gray surface of emissivity 0.8, what is the
radiant heat transfer from the bulb surface to its surroundings?
Q
t
Solution:
= A (T4 - To4 )
[(273+135) K]4
Q
t
[(273+25) K]4
Prof. R. Shanthi
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