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structures
CHM 474
Overview
Bonding
Ionic
Covalent
Metallic
Structure
Giant
ionic
Simple
Giant
molecular covalent
Giant
Metallic
Example
Sodium
chloride
Water
Diamond
Iron
Macromolecule Crystals
A macromolecule is a big molecule that
contains a network of covalent bonds
binding its particles. The particles are
non-metal
atoms.
Examples
of
macromolecules are graphite, diamond,
silicon, silicon carbide, silica and boron
Substances with
macromolecular
structures are always
solids at room
conditions
Diamond
Graphite
Macromolecules..
Long chains of molecules
containing a very large number of
atoms
Examples: plastics, proteins, some
carbohydrates
Higher m.p./b.p. than simple
molecules due to much stronger
van der Waals forces
ALLOTROPES
Allotropy
manner)
is
Allotropes of
carbon
Diamond
One
of the
allotropes of carbon
Allotropes:
Isotopes:
Diamond
Has
Diamond
Each
Properties of Diamond
Very
Properties of Diamond
Does
not conduct
electricity
All
in water
DIAMOND
Uses of Diamond
Used
1.
2.
3.
4.
Graphite
Structure of Graphite
Arrangement
of carbon
atoms in one
layer
Arrangement
of layers
Strong
covalent
bond
Strong
covalent
bond
Weak force
between
layers
GRAPHITE
Covalent
bonds
GRAPHITE
Graphite has a
layer
structure
which is quite
difficult to draw
convincingly in
three
dimensions. The
diagram
below
shows
the
arrangement of
the
atoms
in
each layer, and
the
way
the
layers
are
2.
Properties of Graphite
The
Reason:
Each carbon atom has
one electron that is
not used in bonding.
Free to move Able to
conduct electricity
Uses of Graphite
Pencil
Physical Properties of
Giant Covalent
Physical state
Substances
At
and B.P.
High
Physical Properties of
Giant Covalent
Solubility in water
Substances
Insoluble
Electrical
in water
conductivity
Do
Graphite
Diamond
1.
a)
b)
c)
(Metal Non-metal)
d)
Bonding Structure
(Non-metal Non-metal)
2.
Sodium
Potassium
Strong
bond / Giant ionic structure
chloride
Carbon Dioxide
3550 oC /4827 oC
98oC/883oC
Diamond
770 oC /1420 oC
- 78 oC / - 57 oC
Answer
(a) In dry ice, the atoms are joined together within the molecules by
strong covalent bonds while only weak van der Waals forces exist
between molecules. The melting and boiling points of dry ice are low
since only weak van der Waals forces are needed to be overcome
during the processes of melting and boiling. Besides, dry ice
consists of simple molecules with no mobile electrons. Thus, it does
not conduct electricity. Carbon dioxide is only slightly soluble in water
because it is non-polar in nature.
Answer