Professional Documents
Culture Documents
ALLOY STEELS
Alloy steels are iron-carbon alloys, to which alloying
elements are added with a purpose to improve the
steels properties as compared to the carbon steels.
Contain more than 1.0% of other elements instead of
Fe and C.
Purpose of alloying
Increase hardenability
Improve strength at ordinary temperature
Improve mechanical properties at either high or low
temperatures
Improve toughness at any minimum hardness or strength
Increase wear resistance
Increase corrosion resistance
Improve magnetic properties
CARBON STEELS
Carbon steels are group
by their percentage of
carbon content per
weight. The higher the
carbon content the
greater the hardness,
strength and wear
resistance after heat
treatment.
Low-carbon steel, also
called mild steels, has
less than 0.30% carbon.
Used in everyday
industrial products like
bolts, nuts, sheet, plate
and tubes.
CARBON STEELS
Medium-carbon steel has 0.30% to 0.60% carbon.
Used for jobs requiring higher strength such as
machinery, automotive equipment parts, and
metalworking equipment.
High-carbon steel has more than 0.60% carbon.
Used parts that require the highest strength,
hardness, and wear resistance. Once manufactured
they are heat treated and tempered
STAINLESS STEELS
STAINLESS STEELS
STAINLESS STEELS
Stainless steels tend to have lower carbon content
since increased carbon content lowers the corrosion
resistance of stainless steels.
Since the carbon reacts with chromium it decreases the
available chromium content which is needed for developing
the protective fi lm.
STAINLESS STEELS
Using stainless steels as reinforcing bars, has
become a new trend, in concrete structures
such as highways buildings and bridges.
It is more benefi cial than carbon steels because it is
resistant to corrosion from road salts and the
concrete itself.
Rebar
corrosion in
concrete
Liquid
+ L
L + Fe3C
Austenite
Carbon
910C Steel
723C
0%
12
+ Fe3C
Cast Iron
+ Fe3C
0.8%
~2%
~3%
13
Application:
Engine
Brake drum
Clutch plate
Furnace part
NODULAR(DUCTILE) IRON
Inoculation with Ce or Mg or both causes graphite to
form as spherulites, rather than fl akes
Also known as spheroidal graphite (SG), and nodular
graphite iron
Far better ductility than grey cast iron
15
MICROSTRUCTURE
Graphite spheres
surrounded by ferrite
Usually some pearlite
May be some
cementite
Can be hardened to
martensite by heat
treatment
16
PROPERTIES
Strength higher than grey cast iron
Ductility up to 6% as cast or 20% annealed
Low cost
Simple manufacturing process makes complex shapes
17
APPLICATIONS
Automotive industry 55% of ductile iron in USA
Crankshafts, front wheel spindle supports, steering
knuckles, disc brake callipers
18
19
MICROSTRUCTURE
PROPERTIES
Similar to ductile iron
Good shock resistance
Good ductility
Good machineability
21
APPLICATIONS
Similar applications to ductile iron
Malleable iron is better for thinner castings
Ductile iron better for thicker castings
>40mm
Vehicle components
Power trains, frames, suspensions and wheels
Steering components, transmission and diff erential
parts, connecting rods
Railway components
Pipe fi ttings AS3673
22
If increase silicon
CHARACTERISTICS AND
APPLICATION OF NONFERROUS
ALLOY MATERIALS
TITANIUM
Low density (S.G. of 4.5, as compared to steel at
approx 8)
Similar strengths to steels
Highly corrosion resistant
Melts at 1670C
Use restricted to <400 C
TITANIUM
Used in
Aerospace parts
Racing cars, motorcycles and bicycles
Pipework and heat exchangers in chemical plants and
oil installations.
Titanium heatexchangers
WHAT IS CORROSION?
Corrosion is the oxidation of a metal due to an
ELECTROCHEMICAL reaction. The oxidizing agent is
most often O2 (atmospheric corrosion) or H+ (chemical
corrosion) or both.
Why is it a problem?
Financial - $350 Billion Dollar Annual Problem in U.S.
(4.25% of GNP) Department of Defense spends $6
8 Billion
RECIPE FOR
CORROSION
Active metal
Electrolyte
Water
Oxygen
(atmospheric
corrosion)
Acid
(chemical
corrosion)
Salt
High
temperature
Corrosion
Triangle
Metal
Oxidize
Electrochemical Corrosion
Electrochemical corrosion - Corrosion produced by the
development of a current in an electrochemical cell that
removes ions from the material.
Electrochemical cell - A cell in which electrons and ions
can flow by separate paths between two materials,
producing a current which, in turn, leads to corrosion or
plating.
Oxidation reaction - The anode reaction by which
electrons are given up to the electrochemical cell.
Reduction reaction - The cathode reaction by which
electrons are accepted from the electrochemical cell.
34
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
35
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
TYPES OF CORROSION
:
Corrosion is the primary means by
which metals deteriorate. Most metals
corrode on contact with water (and
moisture in the air), acids, bases, salts,
aggressive metal polishes, and other
solid and liquid chemicals. Metals will
also corrode when exposed to gaseous
materials like acid vapors,
formaldehyde gas, ammonia gas, and
sulfur containing gases.
Corrosion Mechanism :
Corrosion Mechanism is the destructive
attack, or deterioration, of a metal by
chemical or electrochemical reaction with its
environment. Corrosive attack of metals is an
electrochemical process. In a galvanic cell,
two dissimilar metals (e.g., iron and copper)
are placed in electrical contact in the
presence of oxygen and moisture. Separate
chemical reactions take place at the surfaces
of the two metals, creating a fl ow of electrons
through the connecting wire.
Uniform Corrosion
UNIFORM CORROSION
This type of corrosion includes the commonly
recognized rusting of iron and other metals.
Pitting
PITTING CORROSION
This is a localized type of attack, with the rate of
corrosion being greater at some areas than at others.
If appreciable attack is confi ned to a relatively small,
fi xed area of metal, acting as anode, the resultant
pits are described as deep. If the area of attack is
relatively larger and not so deep, the pits are called
shallow. Depth of pitting is sometimes expressed by
the pitting factor , the ratio of deepest metal
penetration
to
average
metal
penetration
as
determined by the weight loss of the specimen. A
pitting factor of unity represents uniform attack.
Iron buried in the soil corrodes with formation of
shallow pits, whereas stainless steels immersed in
seawater characteristically corrode with formation of
deep pits.
Erosion-Corrosion
EROSION CORROSION
when subjected to high - velocity liquids, undergo a
pitting type of corrosion called impingement attack ,
or erosion corrosion .
Copper and brass condenser tubes, for example, are
subject to this type of
attack.
Fretting Corrosion
Cavitation Erosion
Selective Corrosion
Intergranular Corrosion
Corrosion Fatigue
Galvanic Corrosion
Crevice Corrosion
SELECTIVE CORROSION
Selective corrosion can be found in alloys and
resulting from the fact that the components of the
alloy corrode at diff erent rates.
CORROSION CONTROL:
Bracket easier
to replace than
pipe!
Bluing
B l u i n g i s a p a ss iv a t io n p ro c e s s i n w h ic h s t e e l i s p a r t ia l ly p ro t e c t e d a g a i n s t r u st, a n d is n a m e d
a ft e r t h e b l u e - b la c k a p p e a r a n c e o f t h e re s u lt in g p ro t e c t i v e fi n i s h . Tr u e g u n b lu in g is a n
e l e c t ro c h e m ic a l c o n v e r si o n c o a t in g re s u lt in g f ro m a n ox i d i z in g c h e m ic a l re a c t i o n w i t h i ro n o n t h e
s u r f a c e s e l e c t iv e l y f o rm i n g m a g n e t i t e ( Fe 3 O 4 ) , t h e b l a c k ox i d e o f i ro n, w h ic h o c c u p ie s t h e s a m e
v o l u m e a s n o rm a l iro n. D o n e f o r b o lt s c a ll e d b l a c ke n i n g
MATERIAL SELECTION:
Importance of Oxide fi lms
The fundamental resistance of stainless steel to
corrosion occurs because of its ability to form an
oxide protective coating on its surface. This thin
coating is invisible, but generally protects the
steel in oxidizing environments (air and nitric
acid). However, this fi lm loses its protectiveness
in environments such as hydrochloric acid and
chlorides. In stainless steels, lack of oxygen also
ruins the corrosion protective oxide fi lm,
therefore these debris ridden or stagnant
regions are susceptible to corrosion.
Types of CP:
sacrifi cial anodes zinc, magnesium or aluminum. The sacrifi cial
anodes are more active (more negative potential) than the metal
of the structure theyre designed to protect. The anode pushes
the potential of the steel structure more negative and therefore
the driving force for corrosion halts. The anode continues to
corrode until it requires replacement,
Impressed current CP done for large structures (pipes, off shore
platforms, etc) where a galvanic (or sacrifi cial) anode can not
economically deliver enough current.
Galvanized steel again, steel is coated with zinc and if the zinc
coating is scratched and steel exposed, the surrounding areas of
zinc coating form a galvanic cell with the exposed steel and
protects in from corroding. The zinc coating acts as a sacrifi cial
anode.
TQ