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7.2, 7.3)
Basic types of polymers
Polymer structure
Temperature: Tg and Tm
Morphology: Amorphous vs. S/C
Blends + additives altering
properties
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Elastomers:
Thermosets and thermoplastic!!
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Commodity Thermoplastics
Commodity: Polyethylene (PE), Polystyrene
(PS), Polypropylene (PP), Polyvinyl Chloride
(PVC or vinyl) 80% of all thermoplastics!!
Also, Styrene Acrylonitrile (SAN) the
copolymer we tested in lab
Flows at elevated temperatures.
Has a glass transition temperature.
Long polymer chains
Can be remelted and recycled.
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Engineering Thermoplastics
Engineering Plastics: Polycarbonate (PC),
Acrylonitrile-butadiene-styrene (ABS),
Polyamide (Nylons, PA)
Engineered plastics account for about
10% of all plastic usage.
Generally have higher tensile strength and
elongation than commodity plastics
Thermosetting Plastics
Elastomers
Butyl, natural rubber (polyisoprene),
EPDM, neoprene, nitrile, etc..
Characterized by high deformation
(extremely flexible) generally greater
than 100%.
Almost all are thermosetting with
exception of TPEs
LINEAR
Linear polymers no
bonding, polymers
intertwined 2D can
be amorphous or
crystalline
Van der Waals only forces holding molecules
together!
BRANCHED
Branched polymers higher
strength and stiffness than
linear, highly resilient
deformation resisted due to
entwined molecules
CROSS-LINKING
THERMOSETS!!!
Plastics
Thermoplastic vs. Thermoset - Properties
Chemical Resistance
Thermoplastic Some have good chemical resistance, but most can
Molded-in-stresses (warpage)
Thermoplastic caused by uneven cooling, part design, mold design,
Plastics
Thermoplastic vs. Thermoset - Properties
Toughness
Coloration
Shrinkage
Plastics
Thermoplastic vs. Thermoset - Properties
CHAIN STIFFENING
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For more on
Polymer Structure
See PLET 250
power point!!
Access rxm61 course ware data disk for METBD
470.
/
GeneralCourseSupplements/PlasticInfo/Reference
PLET250_materialt
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Morphology
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73: Morphology:
KEY POINTS:
After reviewing the morphology presentation, students
should:
Be able to name and describe the two basic morphologies of
thermoplastic materials
Understand the difference between Tg and Tm and the
significance of each.
Understand Orientation and how it affects properties.
Be able to name several property differences that exist between
the two different morphologies
Be able to name several materials that belong to each
morphological family
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Overview
7.3: Morphology:
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7.3: Morphology:
Amorphous
Amorphous polymers appear random and jumbled when allowed
to cool in a relaxed state. They appear very similarly to their
molten state, only the molecules are closer together.
They can be described as being similar to a large pot of spaghetti
noodles.
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7.3: Morphology:
Semi-crystalline
A portion of the molecular chains in semi-crystalline polymers tend
to fold-up into densely packed regions called crystals as the
polymer cools.
If more than 35% of the polymer chain will form these crystals
the polymer is classified as semi-crystalline.
Semi-crystalline
regions
Amorphous
regions
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7.3: Morphology:
Example
Think of Semi-crystalline materials like ramen
noodles. When in their solid state, they have a
compact ordered arrangement
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7.3: Morphology:
Example
Amorphous materials are like cooked ramen noodles in that there is a random
arrangement of the molecules and there are no crystals present to prevent the chains
from flowing
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7.3: Morphology:
Degree of Crystallinity
There are many different factors that can determine the amount of crystals or
degree of crystallinity of a plastic component.
Cooling rate it takes time for the polymer chains to fold up. If we cool the
polymer more quickly, we form fewer crystals
Additives some additives can be put into plastics to increase the degree
of crystallinity while others can disrupt the formation of the crystals giving
us a lower degree of crystallinity
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Material Types
Amorphous
Polyvinyl Chloride (PVC)
General Purpose Polystyrene (GPPS)
Polycarbonate (PC)
Polymethylmethacrylate (PMMA or Acrylic)
Acrylonitrile Butadiene Styrene (ABS a terpolymer)
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Material Types
Semi-crystalline
Polyethylene (PE, HDPE, LDPE, etc.)
Polypropylene (PP)
Polyamides (PA Nylon)
Polyesters
Polyethylene Terephthalate (PET)
Polybutylene Terephthalate (PBT)
Polyoxymethylene (POM - Acetal)
Polytetrafluoroethylene (PTFE Teflon)
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7.3: Morphology:
Temperature
For most materials, we are concerned with the melting point and boiling
point. These are the temperatures at which the matter experiences a change
of state
oSolid to Liquid
oLiquid to Gas
For thermoplastic materials, we are concerned with:
oGlass Transition Temperature
oMelting Temperature
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7.3: Morphology:
Ex. Polyethylene and Polypropylene both have low Tgs. They are
way below room temperature. That is why milk jugs and yogurt
containers are flexible when you take them out of the
refrigerator.
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7.3: Morphology:
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7.3: Morphology:
continue to soften
The molecules absorb enough energy and move far enough apart (increase
the free volume) that the material can flow.
When we refer to the melt temperature for amorphous materials, it is usually
the temperature at which we can process it.
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7.3: Morphology:
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Amorphous Thermoplastics
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Viscosity =
ice!
Spec volume
= opposite of
ice!
Key: distinct Tm
Semi-Crystalline polymer
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7.3: Morphology:
Properties
Chemical Resistance
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Properties
Optical Properties
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Properties
Impact Resistance
The material structure determines the impact resistance, but as a
general rule, S/C materials are more brittle than Amorphous.
The chain portions that are folded up in the crystal restrict the
polymer chains as they try to move past one another when a
force is applied making the S/C materials more brittle.
Polycarbonate is used in safety glasses, but General Purpose
Polystyrene (GPPS) is very brittle both are amorphous, but
have different polymer structures.
On the S/C side, Polyethylene is very ductile at room
temperature because it is above its Tg, but Nylon and Polyester
are brittle at room temperature.
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Properties
Viscosity
S/C materials by their very nature flow more easily than Amorphous
materials.
The same mechanism that allows the material to fold up into dense crystals
allows the polymer chains to slide past one another easily in the melted
state.
Flash
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Properties
Weather Resistance
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Properties
Weather Resistance
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Properties
Shrinkage
Because they fold up into crystal structures, S/C materials have higher
shrinkage rates when compared to Amorphous materials.
In injection molding most amorphous materials will shrink between 0.0030.007 in/in (0.3-0.7%)
S/C materials shrink differently depending
upon the level of crystallinity that they achieve.
Some will shrink over 0.025 in/in depending
on processing variables, part thickness, and
additives.
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Crystalline vs Amorphous
Thermoplastics:
Crystalline (actually usually semicrystalline):
Atomic bonds regular and repeated
Have a defined melting point Tm
Can contain some degree of amorphous
polymer
Usually translucent to opaque
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Crystalline vs Amorphous
Thermoplastics:
Amorphous:
Extensive chain branching
All thermosets are amorphous
Exhibit glass tranistion temperatures Tg
Below Tg, polymer acts stiff and rigid
Above Tg, polymer acts soft and rubbery
Morphology
Questions?
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Additives:
Know basic additives shown in table 7-1.
Additives broken into 5 categories of
modifiers:
Mechanical property modifier
Surface property modifier
Chemical property modifier
Processing modifier
Aesthetic property modifier
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Key to
strengthening:
Limit ability of
molecules to
move or align
themselves!
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