3 Lechattwo

Le Chatelier's
Principle
Lesson 3
A(g)
B(g)
AB(g)
2 particles
1 particle
more pressure
less pressure
When the reaction shifts to the right it lowers the pressure

When the reaction shifts to the left it increases the pressure
50 Particles
Shifting right reduces the particles and the pressure
50 Particles
49 Particles
49 Particles
48 Particles
4HCl(g) + 2O2(g)
2H2O(l) + 2Cl2(g)
6 gas particles
2 gas particles
more pressure
less pressure
When the reaction goes left it increases the pressure by making more
particles.
2SO3(g)
2SO2(g)
O2(g)
2 gas particles
3 gas particles
less pressure
more pressure
When the reaction goes right it increases the pressure by making more
particles.
I2(g) + Cl2(g)
2 gas particles
2ICl(g)
2 gas particles
the pressure is the same on both sides

This reaction will not shift with pressure.
6.1
Increasing the pressure by decreasing the volume shifts the

reaction to the side with the fewest gas molecules. Only (g)
count for gas particles.
Simulation
4HCl (g) +
2O2 (g)
2H2O (l)
2Cl2 (g)
98kJ
6.1

Simulation
4HCl (g) +
2O2 (g)
Decrease the volume
2H2O (l)
2Cl2 (g)
98kJ
6.1

Simulation
4HCl (g) +
2O2 (g)
2H2O (l)
Decrease the volume and you Increase Pressure!
2Cl2 (g)
98kJ
6.1

Simulation
4HCl (g) +
2O2 (g)
2H2O (l)

All concentration increase!
2Cl2 (g)
98kJ
6.1

Simulation
4HCl (g) +
2O2 (g)
Count gas particles!
2H2O (l)
2Cl2 (g)
98kJ
6.1

Simulation
6
4HCl (g) +
2
2O2 (g)
2H2O (l)
2Cl2 (g)
98kJ
6.1

Simulation
shifts to products to decrease the pressure
6
2
4HCl (g) +
2O2 (g)
2H2O (l)
+ 2Cl2 (g) +
98kJ
6.2
Decreasing the pressure by increasing the volume shifts the

reaction to the side with the most gas molecules. Only (g) count
for gas particles.
Simulation
6
4HCl (g) +
2
2O2 (g)
2H2O (l)
Increase the volume and you Decrease Pressure!
2Cl2 (g)
98kJ
6.2

for gas particles.
Simulation
6
4HCl (g) +
2
2O2 (g)
2H2O (l)
2Cl2 (g)
98kJ
6.2

for gas particles.
Simulation
6
4HCl (g) +
2
2O2 (g)
2H2O (l)
2Cl2 (g)
98kJ
6.2

for gas particles.
Simulation
shifts to the reactants to increase the pressure
6
2
4HCl (g) +
2O2 (g)
2H2O (l)
+ 2Cl2 (g) +
98kJ
4HCl (g) +
2O2 (g)
2H2O (l)
2Cl2 (g)
Describe the shift in the above equilibrium system for each stress
indicated. Describe how [HCl], [O2], and [Cl2] change.
Stress
Shift
[HCl]
[O2]
[Cl2]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
[HCl]
Shift
[HCl]
[O2]
[Cl2]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
[Cl2]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
[Cl2]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
[Cl2]
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
[Cl2]
V or P
We do
98kJ
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
98kJ
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
[Cl2]
V or P
We do
P
Rx does
4HCl (g) +
6
2O2 (g)
2H2O (l)
2Cl2 (g)
98kJ
Stress
Shift
[HCl]
[O2]
[Cl2]
[HCl]
[O2]
Add water
[Cl2]
V or P
We do
P
Rx does
The Forward and Reverse Rates and Shifting

Explain in terms of the immediate changes to the forward and reverse
rates after each stress why each shift occurs
2CO(g) +
1.
O2(g)
CO is added.
Shift
Forward
Reverse
2CO2(g)
energy

2CO(g) +
1.
O2(g)
CO is added.
Shift
Forward
Reverse
2CO2(g)
energy

2CO(g) +
1.
O2(g)
CO is added.
Shift
Forward
Reverse
2CO2(g)
energy

2CO(g) +
1.
O2(g)
2CO2(g)
CO is added- more reactant collisions.
Shift
Forward
Reverse
energy

2CO(g) +
1.
O2(g)
2CO2(g)
CO is added- more reactant collisions.
Shift
Forward
Reverse
Right
Increases
No change
energy

2CO(g) +
2.
O2(g)
CO is removed.
Shift
Forward
Reverse
2CO2(g)
energy

2CO(g) +
2.
O2(g)
CO is removed.
Shift
Forward
Reverse
2CO2(g)
energy

2CO(g) +
2.
O2(g)
CO is removed.
Shift
Forward
Reverse
2CO2(g)
energy

2CO(g) +
2.
O2(g)
CO is removed.
Shift
Forward
Reverse
left
decreases
no change
2CO2(g)
energy

2CO(g) +
3.
O2(g)
2CO2(g)
Temperature is increased.
Shift
Forward
Reverse
energy

2CO(g) +
3.
O2(g)
2CO2(g)
energy
Temperature is increased- both forward and reverse rates

increase.
Shift
Forward
Reverse

2CO(g) +
3.
O2(g)
2CO2(g)
energy

increase.
Shift
Forward
Reverse

2CO(g) +
3.
O2(g)
2CO2(g)
energy

increase.
Shift
left
Forward
Reverse

2CO(g) +
3.
O2(g)
2CO2(g)
energy

increase.
Shift
left
Forward
increases
Reverse
increases

2CO(g) +
3.
O2(g)
2CO2(g)
energy

increase.
Shift
left
Forward
increases
Reverse
increases by more

2CO(g) +
4.
O2(g)
Volume is decreased.
Shift
Forward
Reverse
2CO2(g)
energy

2CO(g) +
O2(g)
3
4.
Volume is decreased-
Shift
Forward
Reverse
2CO2(g)
energy
2
Pressure increases!
All concentrations go up!

2CO(g) +
O2(g)
3
4.
energy
Shift
Forward
Reverse
2CO2(g)
right
Pressure increases!

2CO(g) +
O2(g)
3
4.
energy
Shift
Forward
Reverse
2CO2(g)
right
increases
increases
Pressure increases!

2CO(g) +
O2(g)
3
4.
2CO2(g)
energy
Shift
Forward
Reverse
right
increases by more
increases
Pressure increases!

Changes were made to an equilibrium system, a shift occurred, and a
new equilibrium was established. Compare the new forward and
reverse reaction rates and the reactant and product concentrations to
the original ones.
2H2(g) +
1.
O2(g)
The volume is decreased.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
1.
O2(g)
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
1.
O2(g)
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
2H2O(g) + 250 KJ
Pressure increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
1.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
Pressure increases.

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
1.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
right
Pressure increases.

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
1.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
right
increases
Pressure increases.

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
1.
The volume is decreased. Pressure increases.

All Concentrations increase- All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
right
increases
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
1.

Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
right
increases
increases
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
1.

Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
right
increases
increases
increases
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
1.

Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
right
increases
increases
increases
increases
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.
The Temperature is increased.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.

All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.

All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
left

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.

All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
left
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.

All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
left
increases
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.

All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
left
increases
increases
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.

All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
left
increases
increases
increases
increases

the original ones.
3
2
2H2(g) +
O2(g)
2H2O(g) + 250 KJ
2.

All rates increase!
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H2O]
left
increases
increases
increases
increases
decreases

the original ones.
2H2(g) +
3.
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
O2(g)
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
O2(g)
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
O2(g)
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
O2(g)
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
left
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
O2(g)
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
left
increased
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
O2(g)
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
left
increased
increased
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
O2(g)
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
left
increased
increased
increased
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
O2(g)
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
left
increased
increased
increased
increased
2H2O(g) + 250 KJ

the original ones.
2H2(g) +
3.
O2(g)
2H2O(g) + 250 KJ
H2O is added.
Shift
Forward rate
Reverse rate
[O2]
[H2]
[H O]
left
increased
increased
increased
increased
increased as it was added

3 Lechattwo

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

3 Lechattwo

Uploaded by

Copyright:

Available Formats

Le Chatelier's

When the reaction shifts to the right it lowers the pressure

Shifting right reduces the particles and the pressure

Shifting right reduces the particles and the pressure

Shifting right reduces the particles and the pressure

Shifting right reduces the particles and the pressure

Shifting right reduces the particles and the pressure

the pressure is the same on both sides

Increasing the pressure by decreasing the volume shifts the

Increasing the pressure by decreasing the volume shifts the

Decrease the volume

Increasing the pressure by decreasing the volume shifts the

Decrease the volume and you Increase Pressure!

Increasing the pressure by decreasing the volume shifts the

Decrease the volume and you Increase Pressure!

Increasing the pressure by decreasing the volume shifts the

Count gas particles!

Decrease the volume and you Increase Pressure!

Increasing the pressure by decreasing the volume shifts the

Count gas particles!

Decrease the volume and you Increase Pressure!

Increasing the pressure by decreasing the volume shifts the

Decreasing the pressure by increasing the volume shifts the

Count gas particles!

Increase the volume and you Decrease Pressure!

Decreasing the pressure by increasing the volume shifts the

Count gas particles!

Increase the volume and you Decrease Pressure!

Decreasing the pressure by increasing the volume shifts the

Count gas particles!

Increase the volume and you Decrease Pressure!

Decreasing the pressure by increasing the volume shifts the

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

CO is added- more reactant collisions.

The Forward and Reverse Rates and Shifting

CO is added- more reactant collisions.

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

Temperature is increased- both forward and reverse rates

The Forward and Reverse Rates and Shifting

Temperature is increased- both forward and reverse rates

The Forward and Reverse Rates and Shifting

Temperature is increased- both forward and reverse rates

The Forward and Reverse Rates and Shifting

Temperature is increased- both forward and reverse rates

The Forward and Reverse Rates and Shifting

Temperature is increased- both forward and reverse rates

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The Forward and Reverse Rates and Shifting

The volume is decreased.

The Forward and Reverse Rates and Shifting