Depending upon the type of the places occupied by the solute, solid solution can be either substitutional or interstitial. Substitutional solid solution is formed when atoms of small atomic radii fit into the empty spaces or interstices of the lattice structure. Interstitial solid solution is created when atom of small atom radii fits into the empty space or the interstices.
Depending upon the type of the places occupied by the solute, solid solution can be either substitutional or interstitial. Substitutional solid solution is formed when atoms of small atomic radii fit into the empty spaces or interstices of the lattice structure. Interstitial solid solution is created when atom of small atom radii fits into the empty space or the interstices.
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Depending upon the type of the places occupied by the solute, solid solution can be either substitutional or interstitial. Substitutional solid solution is formed when atoms of small atomic radii fit into the empty spaces or interstices of the lattice structure. Interstitial solid solution is created when atom of small atom radii fits into the empty space or the interstices.
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Download as PPT, PDF, TXT or read online from Scribd
V Metals, combination of metals, usually created in liquid state, but in solid state called mechanical mixtures, V The largest proportion V ?
called base metals, the
other element called
alloying element a
a
a V jormed when two or V Depending upon the more elements are type of the places completely insoluble occupied by the in the solid state, exp: solute, solid solution lead and iron can be either substitutional or interstitial. V Substitutional V Interstitial According to Interstitial solid the Hume-Rothery solution is formed Rules, solvent and when atom of small solute atoms must atomic radii fit into differ in atomic the empty spaces or size by less than 15% interstices of the in order to form this lattice structure type of solution.
Substitutional alloy Interstitial alloy
V Relative size factor V Chemical affinity factor: The farther apart the elements are in periodic table, the greater is their chemical affinity
V Relative valency factor: V Crystal structure factor:
A metal of higher Metals having same valance can dissolve crystal structure will only a small amount of have greater solid a lower valance metal, solubility while the lower valance metal may have good solubility for the higher valance metal V In ideal subtitutional V These regular solid solution solute arrangements of atoms and solvent atoms are are called ´? randomly distributed or ´ on lattice sites, at
elevated temperatures there is a random distribution of solute and solvent atoms, during slow cooling the atoms begin to take up preferred positions, and the solution become ordered ?hether two elements will V Density of the alloy form a substitutional or an interstitial solid solution can Mathematically: be predicted by , or by the
of the following quantities:
?here: Then Density =
ǒ (rho) is the atoms Density, ?eight of atoms/cells is the Mass, is the Volume. Volume of unit cell Transmission Electron Microscope (TEM) Atom-prove Field Ion Microscope (APFIM) V jormed when there is an excess of an alloying element added to a base metal in a solid solution. V It is present within the solid solution. A solid solution of copper V Different structure and and arsenic properties to the solid solution. V Can either be a compound or an intermediate solid solution.