QUANTUM

PHASE
TRANSITION
PRENSENTING BY-

Nn0.

DIPENDRANATH MONDOL
GITANJALI JANA
JYOTSHNA DHILLON
NILANJAN BHAUMIK

M.Sc Physics
IIT Guwahati

Introduction
Phase transitions which occur at zero temperature
when some non-thermal parameter like pressure,
chemical composition or magnetic field is changed
are called quantum phase transitions.
They are caused by quantum fluctuations. We
shall give a an
introduction to quantum phase transitions after
collecting a few basic facts about phase transitions
and critical behaviour we discuss the importance of
quantum mechanics and the relation between
quantum and classical transitions as well as their
experimental relevance.

hase transition : From classical to

uantum Phase transition.
Phase transition is a very common phenomenon to us..
Melting of ice at 272K or the transition of iron from ferromagnet to
paramagnet at 770 are the examples phase transition .
But 1st one is a phase transition with latent heat or a discontinuity at
the 1st energy derivative with respect to Temperature but 2nd one has
first discontinuity at 2nd Derivative. And we classify classical phase
transition this way.
Everyday examples include the Meltof ice, more complicated is the
transition of a metal into the superconducting state upon lowering the
temperature. The universe itself is thought to have passed through
several phase transitions as the high-temperature plasma formed by
the Big Bang cooled to form the world as we know it today. Phase
transitions occur upon variation of an external control parameter;
their common characteristics is a qualitative change in the system
properties.

Quantum phase transitions have become a

topic of vivid interest in current condensed matter physics. At first

As we will see below, quantum critical behavior, arising from the

peculiar excitation spectrum of the quantum critical ground
state, can influence measurable quantities over a wide range of
the phase diagram. The physical properties of the quantum
fluctuations, which can destroy long-range order at absolute
zero, are quite distinct from those of the thermal fluctuations
responsible for traditional, finite-temperature phase transitions.
WHAT IS PHASE?

BASIC PHENOMONA OF QUANTUM

PHASE TRANSITION
We start out with briefly collecting the basic concepts of phase
transitions and critical behaviour which are necessary for the
later discussions. Phase transitions are traditionally classified into
first-order and continuous transitions. At first-order transitions the
two phases co-exist at the transition temperature examples are
ice and water at 0 C, or water and steam at 100 C. In contrast,
at continuous transitions the two phases do not co-exist. An
important example is the ferromagnetic transition of iron at 770
C, above which the magnetic moment vanishes. This phase
transition occurs at a point where thermal fluctuations destroy
the regular ordering of magnetic moments this happens
continuously in the sense that the magnetization vanishes
continuously when approaching the transition from below. The
transition point of a continuous phase transition is also called
critical point.
In the following we concentrate on systems near a
continuous phase transition. Such a transition can usually be
characterized by an order parameter this is a thermodynamic

While the thermodynamic average of the order parameter is zero

in the disordered phase, its fluctuations are non-zero. If the critical
point is approached, the spatial correlations of the order
parameter fluctuations become long-ranged. Close to the critical
point their typical length scale, the correlation length , diverges
as
|t|
(1)
where is the correlation length critical exponent and t is some
dimensionless measure of the distance from the critical point.
The typical time scale for a decay of the fluctuations is the
correlation (or equilibration) time tc As the critical point is
approached the correlation time diverges as
c z |t|z
(2)
where z is the dynamic critical exponent. Close to the
critical point there is no characteristic length scale other than
and no characteristic time scale other than c.
The divergencies (1) and (2) are responsible for the socalled critical phenomena. At the phase transition point,

exponents completely characterizes the critical behavior near

a particular phase transition.

Quantum mechanics and the vicinity of

the critical point
The question of to what extent quantum mechanics is important for
understanding a continuous phase transition has at least two
aspects. On the one hand, quantum mechanics can be essential to
understand the existence of the ordered phase, (e.g.,
superconductivity) this depends on the particular transition
considered. On the other hand, one may ask whether quantum
mechanics influences the asymptotic critical behaviour. For this
discussion we have to compare two energy scales, namely hc,
which is the typical energy of long-distance order parameter
fluctuations, and the thermal energy kBT.
Quantum mechanics will be important as long as this typical energy
scale is larger than the thermal energy kBT; on the other hand, for
hc kBT a purely classical description can be applied to the
order parameter fluctuations. In other words, the character of the
order parameter fluctuations crosses over from quantum to classical
when hc falls below kBT.

Phase transitions and

critical
behavior

Order Parameter: (1st introduced by Landau):

An order parameter is a thermodynamic quantity that is zero
in one phase (the disordered) and non-zero and non-unique
in the other (the ordered) phase.
For the ferromagnetic transition, the total magnetization is
an order parameter
| t |
Thermodynamic average of the
order parameter is zero in
the disordered phase but its fluctuations are non-zero.
Close to the critical point the spatial correlations of the order
parameter fluctuations become long-ranged.

Their typical length scale, the correlation length , diverges as

c

| t |

Where t = |T Tc|/Tc
The typical time scale for a decay of the fluctuations is the
c
correlation (or equilibration) time .(
)As the critical point is
approached the correlation time diverges as

QUANTUM MECHANICS NEAR CRITICAL

POINT
How important quantum mechanics is
for the asymptotic behavior close to the
critical point ?
Answer is easy :Quantum mechanics
does not play any role for the critical
behavior if the transition occurs at a
finite temperature.
At zero Temperature It does play a role.
To distinguish fluctuationsK Twith
C
predominantly thermal and quantum
Cdepending on whether their
character
KT
thermal energy
is larger or

Now from Eqn (2) typical time scale c of

the fluctuations diverges as a continuous
transition is approached. Correspondingly,
the typical frequency
Scale c goes to zero and with it the typical
energy scale .
If the transition occurs at some finite
temperature Tc quantum mechanics will
therefore become unimportant for |t| < tx
with the crossover distance tx given by
tx T 1/z
..(4)