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Introduction
Nano
10-9
10-6
10-3
100
103
106
109
Introduction
Carbon
Melting
point: ~ 3500oC
Introduction
Nanocarbon
Fullerene
Tubes
Cones
Carbon black
Horns
Rods
Foams
Nanodiamonds
Introduction
Nanocarbon
Fullerene
Tubes
Cones
Carbon black
Horns
Rods
Foams
Nanodiamonds
Introduction
Nanocarbon
Fullerene
Tubes
Cones
Carbon black
Properties
Bonding
Graphite sp2
Diamond sp3
Properties
Nanocarbon
Shenderova et al.
Nanotechnology 12 (2001) 191.
Properties
Nanocarbon
6 + 6 pentagons
1 5 pentagons
12 pentagons
Properties
Fullerene
The most symmetrical large molecule
Discovered in 1985
- Nobel prize Chemistry 1996, Curl, Kroto, and Smalley
C60,
~1 nm
Properties
Fullerene
Symmetric shape
lubricant
Properties
Fullerene
Symmetric shape
lubricant
Properties
Fullerene
Symmetric shape
lubricant
Properties
Fullerene
Symmetric shape
lubricant
Ferromagnet?
- polymerized C60
- up to 220oC
Properties
Fullerene
Chemically stable as graphite
- most reactive at pentagons
Properties
Fullerene
Chemically stable as graphite
- most reactive at pentagons
Properties
Nanotube
Discovered 1991, Iijima
Roll-up vector:
Ch n a1 m a2
Properties
Nanotube
Discovered 1991, Iijima
Roll-up vector:
Ch n a1 m a2
Properties
Nanotube
Electrical conductanse depending on helicity
Ch n a1 m a2
If
2n m
i , then metallic
3
else semiconductor
Properties
Nanotube
Electrical conductanse depending on helicity
Ch n a1 m a2
If
Current capacity
2n m
i , then metallic
3
else semiconductor
1 MAmps / cm2
Heat transmission
Comparable to pure diamond (3320 W / m.K)
Temperature stability
Carbon nanotube
Caging
May change electrical properties
sensor
Properties
Nanotube
High aspect ratio:
Length:
typical few m
length
1000
diameter
quasi 1D solid
Diameter:
as low as 1 nm
Properties
Nanotube
High aspect ratio:
Length:
typical few m
length
1000
diameter
quasi 1D solid
Diameter:
as low as 1 nm
SWCNT 1.9 nm
Zheng et al. Nature Materials 3 (2004) 673.
Properties
Nanotubes
Carbon nanotubes are
material.
Young Modulus (stiffness):
Carbon nanotubes
Carbon fibers
High strength steel
the
strongest
1250 GPa
425 GPa (max.)
200 GPa
11- 63 GPa
3.5 - 6 GPa
~ 2 GPa
Density:
Carbon nanotube (SW) 1.33 1.40 gram / cm3
Aluminium
2.7 gram / cm 3
ever
known
Properties
Mechanical
http://www.ipt.arc.nasa.gov/gallery.html
Nanoscience Research Group
University of North Carolina (USA)
http://www.physics.unc.edu/~rsuper/research/
Cones
Discovered 1994 (closed form) Ge & Sattler
1997 (open form) Ebbesen et al.
Closed: same shape as HIV capsid
Possible scale-up production (open form)
Storage?
Properties
Hydrogen
19.2 o
Scale bar: 200 nm
38.9 o
60.0 o
84.6 o
112.9 o
Krishnan, Ebbesen et al. Nature 388 (2001) 241.
Properties
Carbon black
Large industry
- mill. tons each year
Application
Writing
Carbon graphite
Application
CNT composites
- 0.1 1 wt% loading
- low perculation treshold
Application
Wu et al. Science
305 (2004) 1273.
Application
Electric devices
Application
Transistor
Vacuum tubes
- Nobel prize 1906, Thomson.
Semiconductor, Si-based
- Nobel prize 1956, Shockley, Bardeen,
and Brattain.
- 2000, Kilby.
IBM, 1952.
Application
Transistor
SWCNT
- 2.6 GHz, T = 4 K
- Logical gates
Emitter
Collector
Base
Application
Antenna
Application
Antenna
Dipole
Radio wave:
~ 3/4 m
m
3 10
c
s ~ 100 MHz
f
3m
8
Application
Antenna
Dipole
Radio wave:
~ 3/4 m
m
3 10
c
s ~ 100 MHz
f
3m
8
Nanotube
L
Optical wave:
~ L / 2 ~ 500 nm
Application
Plasma TV
Application
Application
Application
Application
Application
Yarn
Application
Yarn
MWCNT
Operational -196oC < T < 450oC
Electrical conducting
Toughness comparable to Kevlar
No rapture in knot
Application
Hydrogen storage
2 H2(g) + O2(g) 2 H2O (l) + energy
Mg2NiH
LaNi5H6
3.16 wt%
1.37 wt%
H2 (liquid)
H2 (200 bar)
Application
Hydrogen storage
Aim: 5 - 7 wt% H2
SWCNT
- Dillon et al. (1997) : 8 wt%
(questionable)
- Tarasov et al. (2003): 2.4 wt
% reversible, 25 bar H2,
-150oC.
Cones
- Mealand & Skjeltorp, (2001)
US Patent 6,290,753
Eldrid Svsand, IFE Kjeller
Conclusion
Warnings
Environment and health
No scale-up production of fullerenes and tubes
No scale-up design, yet.
Conclusion
Conclusion
Nanocarbon
- fullerene
- most symmetrical
- tubes
- strongest
- cones
- one of the sharpest
- carbon black - large production
Properties
- electrical, mechanical, thermal, storage, caging
Applications
- antenna, composite, writing, field emission,
transistor, yarn, microscopy, storage
Commercial
Companies: ~ 20 worldwide
- Carbon Nanotechnologies Inc. (CNI)
- SES Research
- n-Tec
Prices:
- Tubes: pure SWCNT $500 / gram (CNI)
MWCNT 20-50 / gram (n-Tec)
- C60 : pure $100-200 / gram (SES Research)
- Cones: Multi 1 / gram (n-Tec)
- Gold : $10 / gram