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Polyester
R.Senthil Kumar
sen29iit@yahoo.co.in
sen29iit@gmail.com
What is Flame retardant?
A fabric is deemed to be flame retardant if it
does not ignite and create a self-sustaining
flame when subjected to a heat source.
R.Senthil Kumar,KCT,Coimbatore.
Thermal Behavior of Fibres
The effect of heat on a textile material can produce
physical as well as chemical change.
R.Senthil Kumar,KCT,Coimbatore.
When a fibre is subjected to heat, it pyrolyses at Tp and volatile
liquids and gases, which are combustible, act as the fuels for
further combustion. After pyrolysis, if the temperature is equal
to or greater than combustion temperature Tc, flammable
volatile liquids burn in the presence of oxygen to give products
such as carbon dioxide and water.
R.Senthil Kumar,KCT,Coimbatore.
How to impart Flame Retardancy?
A flame retardant must interfere with the feedback mechanism in one or more of
the following ways :
Removal of heat.
Decrease the amount of combustible gases and promote char formation. This
should happen at reduced temperature so ignition will not occur.
Prevent the access of oxygen to the flame or dilute the fuel gases in the flame to
concentration below which they will not support combustion.
Increase the combustion temperature, Tc, of the fuels and/or interfere with their
flame chemistry.
R.Senthil Kumar,KCT,Coimbatore.
R.Senthil Kumar,KCT,Coimbatore.
Polyester can be made flame retardant via the
following three routes:
1. By introduction of phosphorus containing compounds in the
fibre either through physical mixing with the polymer or
through chemical reaction with the polymer.
R.Senthil Kumar,KCT,Coimbatore.
1.Use of phosphorus containing compounds.
R.Senthil Kumar,KCT,Coimbatore.
2.Use of halogen containing compounds
10-15% by wt. is physically or chemically combined with the
polyester.
R.Senthil Kumar,KCT,Coimbatore.
3.Aromatic Polyester
R.Senthil Kumar,KCT,Coimbatore.
LOI and Elemental Composition Parameter (CP)
R.Senthil Kumar,KCT,Coimbatore.
Flame Retardant Additives for Polyester fibres
R.Senthil Kumar,KCT,Coimbatore.
Thank You
R.Senthil Kumar
Senior Lecturer,
Kumaraguru College of Technology,
Coimbatore-06,
sen29iit@yahoo.co.in
R.Senthil Kumar,KCT,Coimbatore.