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Metallurgical Engineering
Metallurgical engineering or
metallurgy is the study of metals
and is the oldest sciences
devoted to the study of
engineering materials.
Extractive Metallurgy
Extractive metallurgy is the study of the
extraction and purification of metals from
their ores.
Extracting a metal from its ore is
conducted in several process steps.
For example, the extraction route from ore
to refined metal includes any or all of the
following process steps.
Mechanical Metallurgy
Mechanical metallurgy is the
study of the techniques and
mechanical forces that shape or
make finished forms of metal.
Physical Metallurgy
Ceramic Engineering
Ceramic engineering, or ceramics,
is the study of the development
and production of products made
from nonmetallic, inorganic
materials by firing at high
temperatures. Ceramic materials
are divided into four groups:
Clay-based materials
Refractories
Glasses
Inorganic cements
Polymer Engineering
Polymer engineering or polymer is
the study of the development and
production of synthetic organic
materials. Polymer are divided
into two groups:
Composite Engineering
Composite engineering, or
composites, is the study of the
applicability of combinations of
materials. Composites are used to
strengthen metals, ceramics, or
polymers and improve their
structural usefulness.
Materials Engineering
Materials engineering, which
crosses the boundaries of all the
branches of materials sciences, is
the study of the evaluation of the
characteristic properties of all
materials.
METAL IDENTIFICATION
Metal is performed by studying certain
characteristics that metals exhibit. A
metal is described as a pure metal or
as an alloy and may be further divided
into and identified as ferrous or
nonferrous. Metals and all other
materials exhibit three types of
properties that help identify the
materials.These properties are:
Physical properties
Mechanical properties
Chemical properties.
Chemical Analysis
Chemical analysis is the key to the
identification of alloys and is used to
determine the weight percentages of all the
elements that make up alloys.
Properties
A property is a measurable or observable
attribute of a material that is of a physical,
mechanical, or chemical nature.
Physical Properties
Physical properties are the
characteristic response of
materials to forms of energy such
as heat, light, electricity, and
magnetism. Color, density,
magnetic permeability, and weight
of a material are physical
properties.
Mechanical Properties
Mechanical properties are the
characteristic dimensional
changes in response to applied
external or internal mechanical
forces.
Chemical Properties
Chemical properties are the
characteristic responses of
materials in chemical
environment. Corrosion
resistance and resistance to acids
and alkalies are examples of
chemical properties.
Process Condition
Metals may be supplied as cast, as
wrought, or from powders.
The properties of cast and wrought
metals any be substantially and
identifiably different. Cast metals are
produced from molten metal solidifying in
a mold cavity.
Properties of Engineering
Materials
Mechanical Properties
Physical Properties
Thermal Properties
Electrical Properties
Chemical Properties
Magnetic Properties
Optical Properties
Mechanical Properties
Malleability
Ductility
Hardness
Brittleness
Fatigue
Toughness
Elasticity
Plasticity
Stiffness
Mechanical Properties
Malleability ability of a material to be
plastically deformed by hammering or filling
into sheet form. Eg. Gold.
Ductility ability of a material to be plastically
(permanently) deformed by tension before
fracture occurs. Eg. Wire drawing. Eg. Copper
wire.
Hardness ability of a material to resist
scratching or penetration. Eg. Glass.
Importance of Mechanical
Properties of Materials in
Engineering
The need to acquire knowledge of the properties
of materials is ultimately for one main reason:
The correct selection of a material for a given
application. In the case of mechanical
properties, these are data used to predict the
response of materials under mechanical loads.
They are expressed in terms of forces which
may deform materials or even cause them to fail
completely.
Mechanical Properties
of Metals
Stress(MPa)
500
CONTINUED
400
300
200
100
0
0.000 0.002 0.004 0.006 0.008 0.010
Strain
Mechanical Properties
Stiffness - Elastic Modulus or Youngs Modulus (MPa)
Strength - Yield, Ultimate, Fracture, Proof, Offset Yield.
Measured as stress (MPa)
Ductility - Measure of ability to deform plastically without
fracture - Elongation, Area Reduction, Fracture Strain - (no
units or mm/mm)
Toughness, Resilience - Measure of ability to absorb energy
(J/m3).
Hardness - Resistance to indentation/abrasion (Various
scales, e.g.; Rockwell, Brinell, Vickers.)
Lo
Area
Ao
L/2
DirectStressTension
EngineeringStress
P
S
Ao
Load, P
L/2
Lo
L
e
Lo
Area
Ao
L/2
EngineeringStrain
DirectStressCompression
Tension Test
MeasuresP
Extensometer
MeasuresL
TypicalUniversal
TestingMachine
Extensometer
Specimen
0.505"Dia
2GaugeLength
Lo
Total
Elongation
UniformDeformation
X
Maximum
Load,Pmax
Elastic
Deformation
Elongation, L (mm)
Load,Pf
Elongation
Sy
0.2%offset
yieldstress
(Ultimate)
Su
E
ProportionalLimit
EngineeringStrain,e=L/Lo)
Hookes Law
Elastic Deformation
Elastic deformation is not permanent; it means that when
the load is removed, the part returns to its original shape
and dimensions.
For most metals, the elastic region is linear. For some
materials, including metals such as cast iron, polymers,
and concrete, the elastic region is non-linear.
If the behavior is linear elastic, or nearly linear-elastic,
Hookes Law may be applied:
S Ee
Stre ss(M Pa )
400
300
200
S (300 0)MPa
E
2x10 5 MPa
e (0.015 0.0)
100
0
0.000
0.002
0.004
0.006
Strain
0.008
0.010
dF
E
dr ro
Strongly Bonded
Weakly Bonded
InteratomicDistance
Shear
Strain,
Shear Stress,
ShearStress
ShearStrain
shearstress,=ShearLoad/Area
shearstrain,=angleofdeformation(radians)
shearmodulus,G = /(elasticregion)
Poissons Ratio,
ey
ex
ez
ez
Formostmetals,
0.25<<0.35
intheelasticrange
Furthermore:
E 2G(1 )
Plastic Deformation
ElasticPlastic
ElasticPlastic
Sy
Sy
ElasticPlastic
Stress
Sy
0.002
MostMetalsAl,Cu
0.002
Strain
CladAlAlloys
0.002
LowcarbonSteel
Microstructural Origins of
Plasticity
Slip, Climb and Slide of atoms in the crystal
structure.
Slip and Climb occur at Dislocations and Slide
occurs at Grain Boundaries.
e ee e p
Stress
S
ee
E
e p e ee
TotalStrain
Plastic
ep
Strain
ee
Elastic
The0.2%offsetyieldstress
isthestressthatgivesaplastic
(permanent)strainof0.002.
Elastic Recovery
Loading
Reloading
Stress
Loading
Unloading
Unloading
Strain
elasticstrain
Strain
EL%
L f Lo
Lo
x100
Lo
Lf
Area Reduction
AR%
Ao A f
Ao
x100
Ao
Af
EngineeringStress
Brittle
Ductile
A&B
C&D
EngineeringStrain
EngineeringStress,S=P/Ao
Toughness, Ut
Su
Sy
X
ef
Ut S de
o
(S y Su ) EL%
100
2
EngineeringStrain,e=L/Lo)
EngineeringStress,S=P/Ao
Resilience, Ur
Su
Sy
ey
Ur S de
o
ey
Sy e y
2
Sy 2
2E
EngineeringStrain,e=L/Lo)
Yield Stress
(MPa)
350
380
100
210
75
942
285
Ultimate
Stress (MPa)
520
615
200
550
300
1000
340
Ductility
EL%
30
25
18
60
70
14
11
Elastic Modulus
(MPa)
207000
207000
72000
195000
110000
107000
45000
Poissons
Ratio
0.30
0.30
0.33
0.30
0.35
0.36
0.29
Mode patahan
Hardness test
where
BHN = the Brinell hardness number
F = the imposed load in kg
D = the diameter of the spherical indenter in mm
Di = diameter of the resulting indenter impression in mm
Uji impak
Mekanisme
Perpatahan
Bend tests
Are often used as a means of judging the
suitability of a metal for similar treatment
during a production process.
Crystal structures
Structure-property
relationships
Heat treatment
Nucleation;
Homogeneous nucleation: very pure metal, substantial
undercooling (0.2Tm)
Heterogeneous nucleation: nucleation agents (5C
undercooling)
Grain growth
Planar: pure metal
Dendritic: solid solution
Grain size
depends on number of nuclei and cooling rate.
Slip Systems
Deformation (dislocation) occurs on preferential
crystallographic planes and directions, called slip systems.
The slip plane/direction is the plane/direction with the most
closely packed atoms.
6x2=12
4x3=12
1x3=3
Slip Systems
BCC has 6 slip planes and 2 slip directions per plane (12 slip
systems), but distance between slip planes is small, therefore the
required stress is high. Good Strength and moderate ductility, e.g.
Steel, Titanium, Molybdenum, Tungsten.
FCC has 4 slip planes and 3 slip directions per plane (12 Slip
Systems), but distance between slip planes is larger than BCC.
Therefore, probability of slip is moderate, shear stress to cause slip
is low. Moderate Strength and Good Ductility, e.g., Aluminum,
Copper, Gold, Silver
HCP has 1 slip plane and 3 slip directions on that plane (3 systems).
Low probability of slip. Generally brittle materials, e.g., Beryllium,
Magnesium, and Zinc
G b
Theoretical
maxor ideal tensile strength
betweenof material
G / 10 ~ G
30 tensile stress
is/the
2 the
a atomic bonds between two neighboring
required to break
atomic planes.
Solid Solutions
Most metals are not pure but contain a number of other metallic
or non-metallic elements, either alloying elements or
contaminants. Alloying elements are uniformly distributed in the
base metal, forming a solid solution.
Substitutional solid solution
Interstitial solid solution
Effect of Imperfections
Phase Diagrams
A phase diagram, also called equilibrium diagram or a constitutional
diagram, graphically illustrates the relationships among temperature,
composition, and the phases present in a particular alloy system.
Lever Rule
C CL
S
0
S L Cs C L
or
C C0
L
s
S L Cs CL
Example: Calculate the relative proportions of the phases in a CuAg alloy of eutectic composition just below the eutectic temperature.
C E C 71.9 91.2
23.2%
C C 7.9 91.2
Nonequilibrium Solidification
Microsegregation or coring
Heat Treatment
Most parts will require heat treatment either after or
during the processing for proper in-service properties
Annealing
Heat to elevated temp, hold, cool
Softens the material and removes stress
Precipitation Hardening
Diffusion of alloys to produce two phase structure that
promote good strength and ductility
(Aging Aluminum for example)
Heat Treatment of Steel
Summary
Solidification process affects crystal structures which in
turn affect material properties.
Single crystal materials behave very differently than
metal alloys.
The effect of imperfections and grain size in solid
solutions.
Heat treatment can modify material properties by
changing the crystal structure.
Samples
AISI-SAE 1018 0.18 % C
AISI-SAE 1045 0.45 % C
AISI-SAE 1095 0.95 % C
Austenitized at 870C for 2 hours
Heat Treatments
Jominy Test
Generally, the faster steel cools, the harder it will
be. The Jominy bar measures the hardenbility of
a steel
Softest
Hardest
Pearlite Formation
Austenite precipitates
Fe3C at Eutectoid
Transformation
Temperature (727C).
When slow cooled, this
is Pearlite (looks like
Mother of Pearl)
Morphology of Pearlite
(a)
(b)
(b) fine
Bainite
Upper (550-350C)
Rods of Fe3C
Lower (350-250C)
Fe3C Precipitates in
Plates of Ferrite
It is still Ferrite and
Cementite! Its just
acicular.
Martensite
Diffusionless
transformation
of FCC to BCT (more
volume!)
Lenticular structure
Very hard & very
brittle.
TTT Diagrams
Slow Cooling
Time in region
indicates amount of
microconstituent!
Medium Cooling
Cooling Rate, R, is
Change in Temp /
Time C/s
Fast Cooling
What is Tempering?
Martensite needs to be tempered to get better
ductility. This happens when Fe3C is allowed to
precipitate from the supercooled Martensite.
Spheroidite
If tempered for a long
time, Fe3C forms
spheres and grows
inside Ferrite.
Very soft, easy to
machine
So What is Hardenability?
Jominy Bar used to
show how cooling rate
affects hardness
Alloyed steels (Cr, Mo,
Ni, etc.) have higher
hardenbility at same
cooling rates than
carbon steels
Joining Processes
Joining Processes
Mechanical Joining
Rivetin
g
Selfpiercing
rivets
threade
d
fastener
s
Welding
Speed of operation
Slow
Fast
Slow
Fast
Ease of automation
Mediu
m
Good
Poor
Good
Pre-drilled holes
Yes
No
Yes
No
Dissimilar metals
Suitabl
e
suitable
Suitable
unsuitable
Pre-painted/plastic coated
metals
Suitabl
e
Suitable
Suitable
unsuitable
Consumable part
Rivet
Rivet
Bolts,
screws,
plus
nuts
None
Tool life
Long
Long
Long
Short/mediu
m
Tool cost
High
High
medium
Low
Energy demand
Low
Low
Low
Medium/hig
Cold
pressure
welding
Diffusion welding
Gas pressure
welding etc.
0.5Tm
Pressure welding
Tm
Fusion welding
Temperature
Cold Welding
Lap welding
Butt welding
Explosion welding
Roll bonding
Ultrasonic welding
Diffusion Bonding
Surface structure
Diffusion Bonding/Superplastic
Forming (DB/SPF)
Hot Welding
Fusion Welding
Resistance Welding
Spot Welding
(a)
Seam Welding
(b)
Projection Welding
(c)
Fusion Welding
Electric Arc Welding
Nonconsumable-electrode, Consumableelectrode
Moltenmetal
Solid
Adhesive Bonding
Mechanical pretreatment
(grit blasting, grinding, wire
brushing)
Remove dirt, oxides, paint
Surface ionization pretreatment
(changes the polarity of the
surfaces and their energy)
Flame treatment
Corona process
Low-pressure plasma
Degreasing
(uses solvents that evaporate
without residues)
Building up new, active surface by
coating with primers
(for bonding plastics like PP, PE,
PTFE, silicones and many
thermoplastic elastomers)
Joint Design
Summary
Difference between mechanical joining
and welding
Working temperatures of different
welding processes, in terms of Tm
Difference between soldering and
brazing
Property variation in welding zone
Cause of welding distortions
Light
LASER
Cold worked base material will show recrystallization in HAZ, with coarse
grain sizes.
Welding Defects
1. Fusion welding defects due wrong heat input, insufficient
rate of weld metal deposition, and cooling.
2. Lack of bonding or gas porosity due to surface
contaminants, including oxides, oils, etc.
3. Undesirable reactions with surface contaminants
4. Solidification cracks in the weld.
5. Solidification shrinkage coupled with solid shrinkage
imposes internal tensile stresses on the structure, may
lead to distortion.
6. Gases released or formed during welding (eg CO) can
lead to porosity which weakens the joint and acts as a
stress raiser.
Metal Treatment
1. Preheating the weld zone reduces energy input, cooling
rates in the weld and HAZ, reduces differential shrinkage,
residual stresses, and distortion.
2. Postwelding heat treatment of the entire welded structure
a. Stress-relief anneal reduces residual stresses to
acceptable level.
b. Normalizing a steel wipes out most undesirable effects of
welding.
c. Full heat treatment (quenching and tempering of steels)
3. Peening (hammering or rolling) of weld bead improves the
strength of welds.
Oxyacetylene Torch
The acetylene valve is opened first; the
gas is lit with a spark lighter or a pilot
light; then the oxygen valve is opened
and the flame adjusted.
Heat input H EI
v
Non-Consumable-Electrode Welding:
Gas Tungsten-Arc Welding (GTAW)
Nonconsumable gas tungsten
Inert gas welding (TIG)
Weld zone is protected by inert
gas
DC with straight polarity is used
with steel, cast iron, and
stainless
AC with Al, Mg alloys where ac
helps in stripping the oxide
Both hand and automatic
operations are possible
The process demands
considerable skill but produces
very high-quality welds on almost
any material
No weld spatter or slag formation
Consumable-Electrode Welding:
Gas Metal-Arc Welding (GMAW) - MIG
Consumable gas metal-arc welding
(MIG)
Consumable electrode is metal which
melts to become part of the weld seam.
Weld zone is protected by a gas or a
flux
No slag is formed
Several layers could be build with little
or no intermediate cleaning
It is suitable for most metals
Wire electrode can be supplied in long,
coiled lengths which allow uninterrupted
welds in any welding position.