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Before we start....
Conservation of....
All three types of radioactive decays
(Alfa, beta and gamma) hold classical
conservation laws.
Energy, linear momentum, angular
momentum, electric charge are all
conserved
Conservation of...
The law of conservation of nucleon
number states that the total number of
nucleons (A) remains constant in any
process, although one particle can
change into another ( protons into
neutrons or vica versa). This is accepted
to be true for all the three radioactive
decays.
Radioactive
and its
Decay Law
Proof
Exponentional Decay
A quantity is said to be subject to
exponentional decay if it decreases at a
rate proportional to its value.
Exponentional Decay
Symbolically, this can be expressed as
the fallowing differential equation where
N is the quantity and is a positive
number called the decay constant:
N = - N
t
Relating it to radioactive
decay law:
The number of decays are represented
by N
The short time interval that N occurs is
represented by t
N is the number of nuclei present
is the decay constant
10
Relating it to radioactive
decay law:
Here comes our first equation AGAIN, try
to look it with the new perspective:
N = - N
t
11
Confused Minds...
With each decay that occurs (N) in a
short time period (t),a decrease in the
number N of the nuclei present is
observed.
So; the minus sign indicates that N is
decreasing.
14
Got it!!!!
Now, here is our little old equation:
N = - N
POF!!!
t
16
So what?
Thus, the number of parent nuclei in a
sample decreases exponentionally in
time
If reaction is first order with respect to
[N], integration with respect to time, t,
gives this equation.
17
HALF-LIFE
The amount of time required for one-half
or 50% of the radioactive atoms to
undergo a radioactive decay.
Every radioactive element has a specific
half-life associated with it.
Is a spontaneous process.
HALF-LIFE
Ooops!!!
Remember the first few slides? We
stated that we can not predict when
particular atom of an element will decay.
However half-life is defined for the time
at which 50% of the atoms have
decayed. Why cant we make a ratio and
predict when all will decay???
Answer
The concept of half-life relies on a lot of
radioactive atoms being present. As an example,
imagine you could see inside a bag of popcorn as
you heat it inside your microwave oven. While
you could not predict when (or if) a particular
kernel would "pop," you would observe that after
2-3 minutes, all the kernels that were going to
pop had in fact done so. In a similar way, we
know that, when dealing with a lot of radioactive
atoms, we can accurately predict when one-half
of them have decayed, even if we do not know
the exact time that a particular atom will do so.
HALF-LIFE
Range fractions of a second to billions of
years.
Is a measure of how stable the nuclei is.
No operation or process of any kind (i.e.,
chemical or physical) has ever been
shown to change the rate at which a
radionuclide decays.
Bye!
26
Calculating Half-Life
R (original amount)
n (number of half-lifes)
R . (1/2)
Try it!!!
Now lets try to solve a half-life calculation
problem
64 grams of Serenium-87, is left 4 grams
after 20 days by radioactive decay. How
long is its half life?
Solution
Initially, Sr is 64 grams, and after 20
days, it becomes 4 grams.The arrows
represent the half-life.
64 g 1/2
64 . 1/2
64 . .
It goes like this till it reaches 4 grams, in 20
days.
30
Solution
We have to find after how many
multiplications by does 64 becomes 4.
We can simply state that,
64 . (1/2)
Solution
64 . (1/2)n = 4
26-n = 22
n = 4 half-lifes
And as we are given the information that this
process happened in 20 days ;
4 half-lifes = 20 days
1 half life = 5 days
Tataa!!! We have found it really easily!
Questions
Explain the reason for why cant we predict
when/if a nucleus of a radioactive isotope with
a known- half life would decay?
Define half-life briefly.
Questions
Explain the law of conservation of
nucleon number.
Does nuclei decay all at once/ how does
it decay?
A quantity is said to be subject to
exponentional decay if?
THE END!!!
Resources:
http://cathylaw.com/images/halflifebar.jpg
http://burro.astr.cwru.edu/Academics/Astr221/HW/H
W3/noft.gif
http://www.chem.ox.ac.uk/vrchemistry/Conservation/
page35.htm
www.gcse.com/ radio/halflife3.htm
www.nucmed.buffalo.edu/.../ sld003.htm
http://www.iem-inc.com/prhlfr.html
http://www.math.duke.edu/education/ccp/materials/d
iffcalc/raddec/raddec1.html
http://www.mrgale.com/onlhlp/nucpart/halflife.htm