Professional Documents
Culture Documents
Outlines
1.
1.Hydroconversion
Hydroconversion
2.
2.Hydrotreating
Hydrotreating
3.
3. Hydrocracking
Hydrocracking
Catalytic reforming
Hydroconversion
Introduction
Hydrotreating
Hydrocracking
Hydrogenation
Hydrotreating
Objectives of Hydrotreating
1. Removing impurities, such as sulphur, nitrogen and
oxygen for the control of a final product specification
or for the preparation of feed for further processing.
2. Removal of metals, usually in a separate guard
catalytic reactor when the organo-metallic compounds
are hydrogenated and decomposed, resulting in metal
deposition on the catalyst pores.
3. Saturation of olefins and their unstable compounds.
Hydrotreating
HT are located before
the reformer,
hydrocracker and FCC
They are also
needed to adjust the
final product
specification for
various streams,
such as light
naphtha, kerosene
and low sulphur
fuel oils (LSFOs).
Hydrotreating
Hydrotreating
Hydrotreating
Hydrotreating
Hydrotreating
Hydrotreating
Operating Conditions
The operating conditions of the hydrotreating
processes
pressure
temperature
catalyst loading
feed flow rate
hydrogen partial pressure
Hydrotreating
Operating Conditions
Increasing hydrogen partial pressure improves the
removal of sulphur and nitrogen compounds and
reduces coke formation.
Higher temperatures will increase the reaction rate
constant and improve the kinetics. However, excessive
temperatures will lead to thermal cracking and coke
formation.
The space velocity is the reverse of reactor residence
time (y). High space velocity results in low
conversion, low hydrogen consumption and low coke
formation.
Hydrotreating
Operating Conditions
Hydrocracking
Hydrocracking is a catalytic hydrogenation process in which
high molecular weight feedstocks are converted and
hydrogenated to lower molecular weight products.
Hydrocracking
It is mainly used to produce
middle distillates of low
sulphur content such as
kerosene and diesel.
If mild hydrocracking is used,
a LSFO can be produced.
It has been used to remove
wax by catalytic dewaxing and
for aromatic removal by
hydrogen saturation.
This has been applied to the
lube oil plants and is gradually
replacing the old solvent
dewaxing and aromatic solvent
extraction.
Hydrocracking
Hydrocracking
Hydrocracking Catalysts
Hydrocracking
The following factors can
affect operation (product quality),
Hydrocracking
Process
yield (quantity), and the total economics of the process:
1. Process configuration: one stage (once-through or recycle) or
two stages
2. Catalyst type
3. Operating condition (depends on process objective)
- Conversion level
- Maximization of certain product
- Product quality
- Catalyst cycle
- Partial hydrogen pressure
- Liquid hourly space velocity
- Feed/hydrogen recycle ratio
Process Configuration
Hydrocracking
Simplified flow
diagram of one-stage
hydrocracking
process with and
without recycle
In commercial hydrocrackers, a conversion of 4080% of the feed can
be achieved.
However if high conversion is required the product from the bottom of
the distillation tower is recycled back to the reactor for complete
conversion.
This configuration can be used to maximize a diesel product, and it
employs an amorphous catalyst.
Hydrocracking
Process Configuration