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Ilmu Material
Topic
Definition
Dental cements : materials made from
two components, powder and liquid,
mixed together.
Powder + Liquid
Pastelike or flowable material
Hardens to a rigid solid
Luting agent
Temporary cement
Permanent cement
Cavity varnish
Liner
Base
Filling
Temporary filling
Permanent filling
Others
Luting agent
Luting : the use of moldable
substance to seal a space between
two component.
Most dental treatment necessitate
attachment of prostheses to the
teeth by means of luting agent.
Biocompatibility
Retention
High tensile strength, fracture
toughness, fatique strength
Good marginal seal
Film thickness
Cement base
Classification of dental
cements
Conventional cement
Resin-base cement
Resin cement
Resin modified glass ionomer cement
Conventional cement
Liquid
Zinc oxide
Phosphoric acid
Magnesium
oxide
Water
Alumenium
phosphate
ZnO
ZnO
Zn+
ZnO
Zn+
Zinc
aluminophosphate
gel
Unreacted
ZnO
Unreacted
ZnO
Unreacted
ZnO
Unreacted
ZnO
Setting reaction
Exothermic reaction
Adding of water can accerlate the
reaction.
Loss of water can lengthen the
setting reaction.
{not
recommended}
{no
moisture}
Mixing procedure
There are three steps:
Mixing procedure
Mixing procedure
4
2
1
5
3
7
8
4
2
1
5
3
7
8
Characteristic properties
Setting time at 37O
Minimum
compressive
strength
5 9 minutes
75 MPa
Maximum film
thickness
Maximum Solubility
25 m (for luting
the prostheses)
0.2% by weight
Effects of manipulation on
some properties.
Manipulative
variables
Decreased
powder/liquid ratio
Increase rate of
powder
incorporation
Increase mixing
temperature
Water
contamination
Properties
Copressiv Film
e
thicknes
strength s
Solubilit Initial
y
acidity
Setting
time
Biocompatibility
Liquid = 2.0
3 minutes after mixing = 4.2
1 hour = 6
48 hours = 7
Fluoride cement
Zinc silicophosphate
Clinical applications
Luting agent
Base and temporary filling
Luting prostheses
Luting the orthodontics band
Zinc oxide-eugenol
cements
Zinc oxide-eugenol
cement
Simple ZOE
Reinforced ZOE
EBA cement
Compositions of simple
ZOE
Powder
Zinc oxide
Rosin : reduce the brittleness of the
set cement
Zinc stearate : plastcizer
Zinc acetate : improve strength
Liquid
Setting reaction
First
ZnO + Eugenol --
water
Zn(OH)2
Second
Zn(OH)2+2HE ZnE2+H2O
Setting reaction
Manipulation
Paste/paste
Powder/liquid
Classification
Type I
Type II
Permanent cementation
Type III
Type IV
Cavity liner
Specification requirements
Type
Type I
4-10
35 maximum 2.5
25
Type II
4-10
35 maximum 1.5
25
35 maximum 1.5
Reinforced ZOE
EBA cement
Powder
Liquid
Clinical applications
Base
Temporary cementation
Permanent cementation
Zinc polycarboxylate
cement
Composition
Zinc oxide
Magnesium oxide
Stannous fluoride
Liquid
Manipulation
Setting reaction
Specification requirements
Applications
Composition
Powder
Liquid
Polyacid
Setting reaction
There are three stages:
Dissolution
Gelation
Hardening.
Water hardening or water setting
Polyacid liquid
Hydrogen
ions
Ca2+
Glass core
Al3+
F-
Silica gel
Polyacid liquid
Ca2+
Al3+
F-
-COOH
Cross-linked
polyacid
Gelation
Polyacid liquid
Al3+
-COOH
Cross-linked
polyacid
Hardening
Glas
s
core
Cross-linked polyacid
Silica gel
Properties
Strength
Bonding
Modified GI
Cermet
Resin-modified GI
Resin-modified glass
ionomer cement
Setting reaction
Polymerization
Acid-base reaction
initial setting
Properties
GIC
RMGIC
Working time
2 min
3 min 45 sec
Setting time
4 min
20 sec
Compressive
strength
202 MPa
242 Mpa
37 Mpa
Applications
GI filling material
Composite :
Resin matrix + inorganic filler
Silane
coated
Composition
Filler
Silica
Matrix
Bis-GMA (polymer)
Setting reaction
Polymerization
Chemical activation
Light activation
Dual activation [chemical and light]
Preparations
Powder / liquid
Chemical, light, or dual cure
2 paste system [base / catalyst]
Chemical, light, or dual cure
Single paste
Light cure
Bonding system
Properties
Applications
Composition
2 Pastes system
Base
Salicylate reaction
Calcium tungstate and barium sulfate
radiopacity
Catalyst
Calcium hydroxide
Properties
Properties
Comparable properties of
cements
Compressive strength
[MPa]
Bond strength
Separation forces [MPa]
Others
Solubility
References
Textbooks
Kenneth J. Anusavice
Phillips science of dental materials
11th edition
W.B. Saunders company 2003
References
Textbook
Robert G. Craig
Restorative dental materials
9th edition
Mosby company 1993
References
Textbook
References
Journals