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LJ
2S+1
L=0 is S,
L=1 is P,
L=2 is D,
L=3 is F,
L=4 is G,
L=5 is H...
J is the vector sum of L and S:
J = (L+S), (L+S-1), (L+S-2), ....|L-S|
Summary Examples
H (1s1)
ground state term symbol is 2S1/2
He (1s2)
Ground state term symbol is 1S0
He (1s12s1)
S0
nor a
S-1
Term }
B (1s22s22p1)
{ground state}
P1/2
2 2 2
C (1s 2s 2p ) {lowest electron configuration}
Calculate the number of possible electron arrangements
in the given configuration:
There are 6!/4!2! = 15 microstates expected
3
N (1s 2s 2p ) {lowest energy configuration}
Assign Terms
Reality: