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Learning Objectives
After completing this topic, students should be
able to:
Explain the basis of solvent extraction
Give examples on applications of solvent
extractions
Able to use formulas in solving calculations
Distribution coefficient
Zaq
Zorg
KD = distribution coefficient/
partition coefficient
Distribution ratio
It is more meaningful to describe a different term, the
distribution ratio, which is the ratio of the concentrations of all
the species of the solute in each phase.
In this example, it is given by
(org)
(aq)
Distribution ratio
KD = distribution coefficient
Ka = acidity constant
Dc = distribution ratio
(org)
(aq)
KD
C0Vaq
n solute in org = CorgVorg
n solute in aquoues = CaqVaq
(org)
(aq)
(org)
(aq)
Corg
Caq
Percentage of extraction
Percentage of extraction:
Single extraction
Vorg
Vaq
-4
norg = 75/100 x 1.00 x 10-3 mol [X]org = 7.5 x 10 mol/0.1 L
= 7.5 x 10-3 M
= 7.5 x 10-4 mol
Another Example
Twenty milliliters of an aqueous
solution of 0.10M butyric acid is
shaken with 10mL ether. After the
layers are separated, it is determined
by titration that 0.5 mmol butyric
acid remains in the aqueous layer.
What is the distribution ratio, and
what is the percent extracted?
Therefore,
Tutorial:
For a solute with a distribution
ratio of 25.0, show by
calculation which is more
effective, extraction of 10 mL of
an aqueous solution with 10 mL
organic solvent or extraction
with two separate 5.0 mL
portions of organic solvent.
Single extraction
(i) ether
60 mL
collected
Multiple
extraction
2 portions (30 mL each)
original
ether
ether
first
30 mL
collected 1
second
30 mL
aqueous
collected 2
(ii) ether
original
ether
collected 1
collected 2
collected 3
second
third
20 mL
20 mL
aqueous
Multiple extraction
remaining concentration/
remaining mass
E = 1-qn
Initial concentration/
Initial mass
numbers of extraction
amount remaining
%E = 100 (1-qn)
Example:
Note the increased extraction efficiencies that result from dividing the
original 50 mL of solvent into two 25 mL or five 10 mL portions
SOLVENT EXTRACTION
TECHNIQUE IN THE EXTRACTION
OF METAL CHELATES, ION
ASSOCIATION COMPLEXES AN
ORGANIC SAMPLE.
Technique of solvent
extraction.
Technique based on fact :
Uncharged organic
molecule-tend to
dissolve in organic layer.
Charge anion- remains
in polar aqueous layer.
Metal ion:
Do not tend to dissolve
appreciably in organic layer.
To solubilize it, charge must be
neutralized with adding
something make organic like.
Two principle ways of doing this:
Extraction of ion-association
complexes.
Extraction of metal chelates.
Extraction of ion-association
complexes
Metal ion incorporated into bulky
molecule.
Associate with another ion of
opposite charge forming ion pair.
OR
Metal ion associate with another
ion of great size (organiclike).