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Coal Research Group, Unit for Energy Systems, School of Chemical and Minerals Engineering, North-West
University, Potchefstroom Campus, Private Bag X6001, Potchefstroom 2520, South Africa.
b
CSIRO Energy Technology, P. O Box 52, North Ryde NSW 1670, Australia
Background Information
Metz et al., (2005). IPCC Special report on carbon dioxide capture and storage
Background Information
[9]
Background Information
Of the 440 Million tonnes of CO2
emitted per annum in South Africa:
91.8
4.3
6.6
44.9
70
Eskom (50.5%)
Sasol (15.9%)
Refineries (1.0%)
Others (20.9%)
Others (about 92 Mton (21%)) are from moving source: transportation, agriculture waste
sector etc.
Figure 3: Distribution of large-scale industrial CO 2 emissions in South Africa2009 (Mton CO2 per annum)[10]
Viljoen et al., (2010). Technical report on the geological storage of carbon dioxide in South Africa
[10]
Background Information
Table 1: Estimated CO2 storage capacity of South Africas unmineable coal fields[10]
Basins/
Area
Amersfoort/
Utrecht
Ellisras
Welkom/
Hennenman
Kroonstad
Springbok Flats
Somkele
Pafuri
Kangwane
Newcastle/
Ladysmith
Edenville
Tuli
Heilbron
Frankfort
Nongoma
Depth
Interval (m)
CO2 Adsorption
Capacity/Tonne
of coal (m3)
CO2 Storage
Capacity
(MtCO2)
Gas Content
(wt %, adb)
300-550
2227
331.8
NA
800
10
300-800
1722
293.4
23-26
1440
300-550
1721
154.4
NA
936
300-550
1721
100.3
NA
2300
300-550
1722
84.4
28-35
360
420
195
5
3
6
300-800
300-800
300-800
2227
2226
2226
82.9
56.9
52.8
6-8
22-27
7-24
936
300-550
2227
43.1
NA
360
150
288
216
75
2
3
1
1
1.5
300-550
300-550
300-550
300-550
300-550
1721
2227
1721
2227
2227
25.7
20.7
10.3
10
5.2
32-36
NA
NA
7-24
Area
(km2)
Seam
Thickness
(m)
3600
1271.9
Viljoen et al., (2010). Technical report on the geological storage of carbon dioxide in South Africa
[10]
Research Methods
Physicalstructural
properties:
LPGA (CO2 and N2);
MIP;
Helium pycnometry;
SAXS.
Correlate
HPGA results
with sample
properties
Figure 4: Research methods
8
225 5 g
55 0.2 C
Ambient 16.2 MPa
PAGE: 9
PAGE: 9
PAGE: 4
Coal OGS
Coal TKD
Inherent moisture
3.3
4.0
2.7
0.7
Ash content
22.0
25.9
24.5
16.8
Volatile Matter
26.6
21.5
22.4
22.0
Fixed carbon
48.1
48.6
50.4
60.5
23.3
29.6
Carbon
78.5
78.7
81.3
86.9
Hydrogen
4.9
4.4
4.7
5.1
Nitrogen
2.0
2.2
2.0
2.1
Oxygen
13.2
13.0
10.6
4.8
1.4
1.7
1.3
1.0
0.0
0.0
0.5
8.5
11
PAGE: 4
Coal FOZ
Coal DEN
Coal OGS
Coal TKD
36
20
21
68
Liptinite
Inertinite
45
59
57
23
Visible minerals
14
18
17
54
41
Reflectance properties (%)
42
72
0.63
0.65
0.69
1.2
1.05
1.24
1.19
1.5
Medium
Rank C
Medium
Rank C
Medium
Rank C
Medium
Rank B
Rank (Bituminous)
12
Method used Coal FOZ Coal DEN Coal OGS Coal TKD
CO2 Adsorption Results
D-R
D-R
H-K
CO2 Ads data
N2 Adsorption Results
127.9
5.1
3.87
129.3
5.2
3.85
117.8
4.7
3.89
107.3
4.3
4.1
5.36
5.27
4.58
2.91
BET
BET
BJH
N2 Ads data
MIP Measurements
3.6
1.32
187
5.7
1.47
125
2.9
1.01
196
2.6
1.02
261
2.23
1.6
1.32
2.63
MIP
MIP
MIP
MIP
MIP
SAXS measurements
13.9
4.4
127
6.2
1295
14.1
3.9
111
6.1
1455
12.5
5.2
168
7.1
1367
10.9
5.7
208
7.6
1206
162.6
10.3
8.6
11
171.7
10.1
7.7
9.9
158.2
9.5
8.6
10.5
147.4
8.7
6.6
11.1
SAXS
SAXS
SAXS
SAXS
13
SiO2
18.5
36.0
21.3
26.7
CaMg(CO3)2
7.7
8.2
3.9
6.0
CaCO3
7.5
5.3
5.6
2.0
KAlSi3O8
5.9
4.6
3.6
2.4
FeS2
4.0
4.8
2.9
2.3
KAll2AlSi3O10(OH)2
3.5
3.8
4.6
8.6
TiO2
0.4
0.4
0.1
0.9
FeCO3
0.2
0.0
0.6
2.6
14
PAGE: 9
(b)
(c)
(d)
Figure 7: CO2, CH4 and N2 isotherms of coals: (a) FOZ; (b) DEN; (c) OGS, and (d)
TKD
15
PAGE: 9
PAGE: 9
[1,7,9-12]
Figure 9: Fitting of D-R and MD-R model data to the experimental CO2 HP adsorption data
of the samples
17
PAGE: 9
[1,7,9-12]
Figure 10: Fitting of D-R and MD-R model data to the experimental CH4 HP adsorption
data of the samples
18
PAGE: 9
[1,7,9-12]
Figure 11: Fitting of D-R and MD-R model data to the experimental N2 HP adsorption data
of the samples
19
Sorption Capacity, W0
Affinity constant, D
Heat of sorption, Es
Proportionality constant, k
ESS
RMS Residuals
QOF (%)
Sorption Capacity, W0
Affinity constant, D
Heat of sorption, Es
Proportionality constant, k
ESS
RMS Residuals
QOF (%)
FOZ
D-R
MD-R
86.9
60.6
0.076
0.049
9.9
12.3
0.035
454.3
4.6
7.13
0.54
81.4
97.4
18.1
0.090
9.1
1.97
0.47
92.6
13.3
0.070
10.3
0.034
0.18
0.12
94.4
21.7
0.130
7.6
1.88
0.38
87.1
13.2
0.099
8.7
0.032
0.11
0.09
94.9
PAGE: 9
TKD
D-R
MD-R
57.7
40.7
0.070
0.046
10.3
12.7
0.024
454.3
4.6
5.01
0.86
81.4
97.4
12.9
0.092
9.0
2.87
0.39
90.8
10.1
0.077
9.9
0.020
0.19
0.29
94.9
15.0
0.118
7.9
0.94
0.27
87.6
10.4
0.096
8.8
0.018
0.31
0.15
95.3
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Conclusion
For the adsorbate gases, the affirnity constant of the samples increased in the order: CO 2 <
CH4 < N2.
The adsorption energy of the samples for the three adsorbate gases was low (<13 kJ/mol),
indicating that physical adsorption was the dominating sorption mechanism.
The sorption capacities of the samples increased with increasing microporosity and
micropore volume; but decreased with increasing vitrinite reflectance of the coals.
The excess sorption capacity of the samples fitted the Modified Dubinin-Radushkevich
(MD-R) model satisfactorily.
Sorption capacity of the samples increased in the order: TKD < OGS < DEN < FOZ
MD-R fitted the experimental data better than D-R with higher QOF.
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Acknowledgement
This work is based on the research supported by
the South African Research Chairs Initiative of
the Department of Science and Technology
(DST) and National Research Foundation
(NRF) of South Africa.
Any opinion, finding, conclusion or recommendation expressed in this material is that of the author(s) and the NRF does not accept any liability in this regard.
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