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Non-electrolytes
Substances that
can conduct
electricity when they
are in molten state
or aqueous solution
and undergo
chemical changes.
Substances that
cannot conduct
electricity either in
molten state or
aqueous solution.
Non-electrolytes
Example:
Sodium chloride,
NaCl solution
Molten Lead (II)
bromide, PbBr2
Example:
Naphthalene
Glucose solution
All covalent
compounds
Non-electrolytes
Contain freely
moving ions.
Contain neutral
molecules
Do not contain freely
moving ions.
6.2 ELECTROLYSIS OF
MOLTEN COMPOUND
What is electrolysis?
BATTERY
Electrodes
CATHODE
Electrode which
is connected
to the negative
terminal
ANODE
ELECTROLYTE
Electrode which
is connected to
the positive
terminal
Molten PbBr2
Pb2+ ions, Br- ions
Passing
electric
ANODE
Release electrons
2Br- Br2 + 2e-
Pb2+
Ion move to..
CATHODE
Accept electrons
Pb2+ + 2e- Pb
PbBr2
Pb 2+
Br-
ANODE
Release electron
2Br- Br2 + 2eHalf equation
Overall ionic equation
CATHODE
Accept electron
Pb2+ + 2e- Pb
Pb2+ + 2e-
Pb
Anode
Cathode
The anions, OH
and SO42- move
to the anode.
OH- ions are
selectively
discharged.
Bubbles of
colourless gas is
released.
Copper(II)
sulphate The cations,
solution
Cu2+.and H+
move to the
cathode.
Cu2+ ions accept
two electrons.
Brown solid is
formed at the
cathode.
Cu2+ (aq) + 2e- Cu (s)
Anode
The anions,OHand Cl- move to
the anode.
Cl- ions are
selectively
discharged
because
concentration of
Cl- is higher than
OH Bubbles of
yellowish gas is
produced.
2Cl- Cl2+ 2e
Cathode
The cations,
H+ ions move
to the
cathode.
H+ ions
accept
electron.
Bubbles of
Colourless
gas is
produced.
2H+ + 2e H2
The overall ionic equation :
2H+ (aq) + 2Cl-(aq) Cl2 (g) + H2 (g)
Anode
OH- and SO42move to the
anode.
OH- ions are
selectively
discharged due
to the lower
position in ECS.
Bubbles of
colourless gas is
released at the
anode.
4OH- 2H2O + O2 + 4e-
Carbon
Carbon
Observation :
The blue copper(II)
sulphate solution becomes
faded/paler because the
concentration of
copper(II)ions decreases.
Cathode
Cu2+.and H+
move to the
cathode.
Cu2+ ions
selectively
discharged
because Cu2+is
lower than H+
in ECS
Brown
deposit/solid is
produced
Cu2+ + 2e Cu
Anode
Cathode
Copper : active
electrode.
Copper
electrode
dissolved and
release
electrons to
form copper(II)
ion.
Copper
electrode
becomes
thinner// Size
of anode
decreaces
Cu Cu
2+
+ 2e
Observation :
Copper
move to the
cathode.
Cu2+ ions
selectively
discharged
because Cu2+ is
lower than H+
in ECS
Copper electrode
become
thicker//Size of
cathode
increases
Cu2+ + 2e- Cu
A. Extraction of Aluminium
Cathode : Al3+ + 3e Al
B. Purification of Copper
The impure copper plate is connected to the +ve terminal anode.
The pure copper plate is connected to the ve terminal cathode.
The electrolyte : copper(II) sulphate solution.
Anode : Cu Cu2+ + 2e
Deposit at
the bottom
of the
beaker
Cathode : Cu2+ + 2e Cu
Pure
cooper
C. Electroplating
Coating with a Thin Protective Layer of Metal.
Anode : Cu Cu2+ + 2e
Cathode : Cu2+ + 2e Cu
Blue
solution
remains
unchanged
Copper
Dissolves/
becomes
thinner
Coated/
deposit layer of
brown solid
VOLTAIC CELLS
[GALVANIC CELL]
A simple voltaic cell is a cell with two different
metals being immersed into an electrolyte and
connected by wire
It converts chemical energy to electrical energy.
Cathode(+ve)
Accept electrons
FUNCTIONS OF
SALT BRIDGE OR POROUS
POT :
(a)
(b)
MECHANISM OF DANIELL
Cathode
CELL Anode
Electrode becomes thinner
Various types
of
voltaic cell
Lead acid
Accumulator
Dry cell
Mercury cell
Alkaline cell
Nickel-cadmium
cell
Advantages
Rechargeable
Can be made
to have
higher voltage
Portable
Cheap
Stable voltage
of 1.5 v
Portable
Portable
Voltage of
1.5 V
More long
lasting
Disadvantages
Heavy
Expensive
Spilled easily
Not
rechargeable
Not rechargeable
Produces voltage
of 1.3 V only
Poisonous
Not
rechargeable
May leak
Portable
Rechargeable
up to hundreds
of times
Produce low
voltage of 1.25 V
Expensive
Heavy
SIMILARITIES BETWEEN AN
ELECTROLYTIC CELL AND A VOLTAIC
CELL
DIFFERENCES
AN ELECTROLYTIC
CELL AND A VOLTAIC
Electrolytic
cell BETWEEN
Type
of cell
Voltaic
cell
CELL:
Electrical energy
Chemical energy
From positive terminal
to negative terminal
Cathode:
Accepts electrons
Anode :
Releases electrons
Two similar
(usually carbon) or
different metals
Conversion of
energy
Flow of
Chemical energy
electrical energy
electrons
Negative
terminal
Anode:
Release of electrons
Positive
Cathode:
terminal
Types of
electrodes
Accepts electrons
Metals
Cations
K K e
Na Na e
Ca Ca2 2e
Mg Mg2 2e
Al Al 3 3e
Zn Zn2 2e
Fe Fe 2 2e
Sn Sn2 2e
Pb Pb2 2e
H H e
Cu Cu2 2e
Ag Ag e
Ability of
metal
atoms to
release
electrons
to form
ions
decreases
Ability of
cations to
accept
electrons to
form
metals
increases
Voltmeter
Electron flow
Copper strip
Magnesium strip
Mg Mg
2+
Cu2+ + 2e Cu
+ 2e
Copper(II) sulphate,
CuSO4 solution
EXAMPLE :
Figure below shows the cell voltages of a few voltaic cells using
different metals as electrodes.
Predict the negative terminal, positive terminal and cell voltage of the
following voltaic cells.
Voltaic cells
Cell voltage/V
Mg/Ag
Mg/Zn
Zn/Pb
Magnesium
Magnesium
Silver
Zinc
Zinc
Lead