Professional Documents
Culture Documents
WATER
FOR HIGH PRESSURE BOILERS
Dilip Kumar
NTPC Ltd.
DEMINERALIZATION
TECHNIQUES
DISTILATION
ELECTRODIALYSIS
REVERSE OSMOSIS
ION EXCHANGE
DISTILLATION
Distillation is one of the oldest
methods of water treatment and is
still in use today though not
commonly as a home treatment
method. It can effectively remove
many contaminants from drinking
water,
including
bacteria,
inorganic and many organic
compounds.
ELECTRODIALYSIS
Electro dialysis is a membrane process in which ions are
transported through ion permeable membranes from one
solution to another under the influence of an electrical
potential gradient.
REVERSE OSMOSIS
Osmosis occurs when two solutions of different
concentrations are separated from one another by a
membrane which is permeable to solvent but
impermeable to solute. Solvents flows from dilute to the
concentrated solution, until, at equilibrium, the chemical
potential of the solvent is equal on both sides of the
membrane.
REVERSE OSMOSIS
CONTI...
REVERSE OSMOSIS
CONTI...
REVERSE OSMOSIS
A typical reverse osmosis
plant consists of
CONTI...
the following items:
LOW
PRESSURE
PUMPS
PARTICULAT
E FILTERS
HIGH
PRESSURE
PUMPS
RO
plant
Stage-1
7 modules
PRODUCT
WATER
Stage-2
4 modules
Stage-3
2 modules
STORAGE
PRODUCT
WATER
PUMPS
DEGASSING
TOWER
CONCETRATE
TO WASTE
LOW
PRESSURE
PUMPS
PARTICULAT
E FILTERS
HIGH
PRESSURE
PUMPS
RO
plant
Stage-1
7 modules
PRODUCT
WATER
Stage-2
4 modules
Stage-3
2 modules
STORAGE
PRODUCT
WATER
PUMPS
DEGASSING
TOWER
CONCETRATE
TO WASTE
LOW
PRESSURE
PUMPS
PARTICULAT
E FILTERS
HIGH
PRESSURE
PUMPS
RO
plant
Stage-1
7 modules
PRODUCT
WATER
Stage-2
4 modules
Stage-3
2 modules
STORAGE
PRODUCT
WATER
PUMPS
DEGASSING
TOWER
CONCETRATE
TO WASTE
REVERSE OSMOSIS
CONTI...
Water analyses from the reverse osmosis
plant at Hartlepool power station
Analyses
Pretreated
water
Product
water
Reject
water
Conductivit
y S/cm
1560
145
6050
Total
hardness
560
30
2700
100
15
600
455
15
2300
180
23
800
mg/kg
CaCO3
Sodium
mg/kg Na
Sulphate
mg/kg SO4
Chloride
DEMINERALIZATION BY
ION- EXCHANGE PROCESS
DEMINERALISATION
SREAM
ACTIVATED CARBON
FILTER (ACF)
Sl.N
o
3.2.1
Characteristics
Unit
NTPC Specification
m2/g
850
3.2.2
g/cc
1.3 1.4
mm
0.6 0.8
mm
1.5 2.0
mg/g
1000
% by mass
95
mm
7.0
3.2.3
3.2.4
In case of needle /
cylindrical
type
3.2.6
(ii)
3.2.7
3.2.5
3.2.8
mesh
Kg/m3
2.
2.4
4 16
400
In case of needle /
cylindrical type
(iv)
ACTIVATED
CARBON
ACTIVATED CARBON
FILTER (ACF)
Acts on principle of adsorption
which is a surface active
phenomenon .
It removes residual turbidity (<2
NTU) of water to its 1/10 level.
It removes organic molecules to
control color and odor.
It removes free residual chlorine
present in filtered water(0.5 ppm
Nil)
ACTIVATED
CARBON
PREPARATION OF RESINS
TYPES OF
RESIN
(R)
R-SO3H
Sulphonic Acid
(SAC
)
R-CH2CHCH3
|
COOH
Carboxylic Acid
(WAC
)
CH3
|
R-CH2-NH+
|
CH3
OH
Tertiary Ammonium
(WB
A)
CH3
|
R-CH2-N-CH3 OH
|
CH3
Quarternary Ammonium
(SBA
)
VESSEL
DESIGN
CATION EXCHANGE
MECHANISM
Ca
Mg
Na
Ca
Mg
Na
Ca
Mg
Na
Na leakage
Un-exchanged
Resin
START OF RUN
END OF RUN
Thoroughfare Counter-flow
Regeneration
DEGASIFIER DESIGN
In water demineralization, a degasifier, or degasser, is
often used to remove dissolved carbon dioxide after
cation exchange. The most common degassers are of
the so-called forced draft or atmospheric type.
THEORY OF
DEGASIFICATION
DEGASIFIER DESIGN
After cation
exchange, the bicarbonate
and carbonate (if any) ions
are converted to carbonic
acid, or carbon dioxide. CO2
is soluble in water, but it
tends to escape into the air,
much as it does in a glass of
Cold drink when you stir it.
Using a degasser to remove
CO2 reduces the ionic load
on the strong base anion
resin, and the consumption
of caustic soda is thus
DEGASIFIER
To be effective, the degasifier must
be placed after the cation exchange
column. Before cation exchange, the
water is containing bicarbonate. After it,
the cations in water (Ca++, Mg++ and Na+
principally) are converted to H+ ions,
which
combine
with
the
HCO3
bicarbonate anions to produce carbonic
acid.
Oxidation
When a strong base anion resin experiences
chemical attack, the polymer chain usually
remains intact, but the quaternary ammonium
strong functional group (trimethylamine for
type 1 anion resins) splits off. Alternately, the
strong base functional groups are converted to
weak base tertiary amine groups, and the resin
becomes bifunctional, meaning it has both
strong base and weak base capacity. The
decline in strong base (salt splitting) capacity
may not be noted until more than 25% of the
capacity has been converted.
2. BACKWASH
3. SIMULTANEOUS
REGENERATION
4. DRAIN DOWN
5. MIXING WITH AIR
6. FINAL RINSE