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8
Polymeric Materials
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Introduction to Polymers
Polymers
many types
Polymers
Plastics
Thermoplastics
Can be
reheated and
formed
into new
materials
2
Elastomers
Thermosetting Plastics
Cannot be reformed
by reheating.
Set by chemical reaction.
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Plastics - Advantages
Remote
Control
3
Good insulation.
Light weight.
Noise Reduction.
Wafer bands
Air intake manifold
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Polymerization
H
Heat
Pressure
Catalyst
H n
DP =
n=degree of
Polymerization (DP).
(range: 3500-25000
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Initiation:
A Radical is needed.
Example H2O2
In General
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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CH2 + CH2
CH2
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
CH2)n R
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Mm
fi M i
fi
Example:
Mm
= 19,550
1
= 19,550 g/mol
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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10
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Stepwise Polymerization:
Monomers chemically
react with each other to
produce linear polymers
and a small molecule of
byproduct.
Network polymerization:
Chemical reaction takes
place in more than two
reaction sites
(3D network).
11
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Industrial Polymerization
Raw Materials:
Natural gas, Petroleum
and coal
Granules, pellets,
Polymerization powders or liquids.
Bulk polymerization :
Monomer and activator
mixed in a reactor and
heated and cooled as desired
Solution polymerization: Monomer
dissolved in non-reactive solvent
and catalyst.
Suspension polymerization: monomer
and catalyst suspended in water.
Emulsion polymerization: Monomer
and catalyst suspended in water along with emulsifier.
12
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Solidification of Thermoplastics.
below
Tg
above
Rubbery
13
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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14
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Stereoisomerism in Thermoplastics
15
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16
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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18
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Transfer Molding
19
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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20
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Polyethylene
21
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22
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Polypropylene
H
H CH3 n
23
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Polystyrene
H
24
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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H
C
Does not
Melt.
H C N n
High strength.
Good resistance to
moisture and solvents.
Applications: sweaters
and blankets. Commoner
for SAN and ABS resins.
25
SAN
Random amorphous
copolymer of styrene and
acrylonitrile.
Better chemical
resistance, high heat
deflection temperature,
toughness and load
bearing characteristics
than polyester alone.
Applications: Automotive
instrument lenses, dash
components, knobs,
blender and mixer bowls.
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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ABS
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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C
O
27
CH3 n
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Fluoroplastics
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Polychlorotrifluroethylene (PCTFE)
F
Cl n
Melting
Point
2180C
29
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Engineering Thermoplastics
30
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Polyamides (Nylons)
31
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Properties of Nylon
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Polycarbonate
High strength, toughness and
dimensional stability.
Very high impact strength.
high heat deflection
temperature.
Resistance to corrosion.
33
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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34
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Acetals
35
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Thermoplastic Polyesters
Phenylene ring provides rigidity.
Good strength and resistant to most chemicals.
Good insulator: independent of temperature and humidity.
Applications: Switches, relays, TV tuner components,
circuit boards, impellers, housing and handles.
36
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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37
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Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Thermosetting Plastics
39
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Phenolics
40
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Epoxy Resins
41
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Unsaturated Polyesters
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Elastomers (Rubbers)
CH3
C
H
C
H
C
H
44
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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45
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Synthetic Rubbers
46
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2ZnCl2 + MgO
OH
H2O
2Zn
+ MgCl
Cl
Silicone Rubbers:
Wide temperature
range.
Used in gaskets,
electric insulation etc.
47
X
Si
X
CH3
Example
Si
n
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
CH3
O
n
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Deformation of Thermoplastics
Below Tg
deformation.
Plastic
Elastic deformation
Plastic deformation
48
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Strengthening of Thermoplastics
Increasing average molecular mass increases strength
upto a certain critical mass.
Degree of crystallinity increases strength, modulus
of elasticity and density.
Chain slippage during permanent deformation can
be hindered by introduction of pendant atomic
groups to main carbon chain.
Strength can be increased by bonding highly polar
atoms on the main carbon chain.
49
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
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1
Ce
52
Q
RT
= relaxation time.
T= temperature, R= molar gas constant.
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display
Fracture of Polymers
Thermosetting plastics
Primarily brittle mode.
Thermoplastics
ductile or brittle depending on the
temperature.
53
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display
Exercise
1.
2.
3.
4.
5.
6.
7.
8.
54
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi
Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display
Exercise
7.
8.
9.
10.
11.
12.
13.
55
What are the two most important engineering thermoplastic polyesters? What
are their repeating chemical structural units?
What is the repeating chemical structural unit for polysulfone?
What are elastomers? What are some elastomeric materials?
What are chemical structural isomers?
(a) What are SAN resins? (b) What desirable properties do SAN thermoplastics
have? (c) What are some of the applications for SAN thermoplastics?
(a) What do the letters A, B, and S stand for in the ABS thermoplastic? (b) Why
is ABS sometimes referred to as a terpolymer? (c) What important property
advantages does each of the components in ABS contribute? (d) Describe the
structure of ABS.
(a) What is the repeating chemical structural unit for polymethyl methacrylate?
(b) By what trade names is PMMA commonly known? (c) What are some of the
important properties of PMMA that make it an important industrial plastic?
Foundations of Materials Science and Engineering, 5th Edn. Smith and Hashemi